Determination of Electrical and Photoelectrical Properties of Schottky Diodes Made Using New Chitin Derivatives Synthesized as Interface Layer

Silicon - 5-(2,4-dichlorophenyl)-2-furoic acid and anthraquinone-2-carboxylic acid were reacted separately with chitin. The synthesized products were characterized by various spectroscopic methods...     

FPGA implementations of fast Fourier transforms for real-time signal and image processing

Applications based on the fast Fourier transform (FFT), such as signal and image processing, require high computational power, plus the ability to experiment with algorithms. Reconfigurable hardware devices in the form of field programmable gate arrays (FPGAs) have been proposed as a way of obtaining high performance at an economical price. However, users must program FPGAs at a very low level and have a detailed knowledge of the architecture of the device being used. They do not therefore facilitate easy development of, or experimentation with, signal/image processing algorithms. To try to reconcile the dual requirements of high performance and ease of development, the paper reports on the design and realisation of a high level framework for the implementation of 1D and 2D FFTs for real-time applications. A wide range of FFT algorithms, including radix-2, radix-4, split-radix and fast Hartley transform (FHT) have been implemented under a common framework in order to enable system designers to meet different system requirements. Results show that the parallel implementation of 2D FFT achieves linear speed-up and real-time performance for large matrix sizes. Finally, an FPGA-based parametrisable environment based on 2D FFT is presented as a solution for frequency-domain image filtering application.     

Assessing internationality of scholarly journals through foreign authorship patterns: the case of major journals in information science,and scientometrics

This article reports findings from a study of patterns of foreign authorship of articles, and international composition of journal editorial boards in five leading journals in the field of information science, and scientometrics. The study covers an American journal and four European journals. Bibliographic data about foreign authors and their national affiliation from five selected years of publication were analyzed for all journals. The foreign input of articles were extremely high in Information Processing & Management, and Scientometrics, and were relatively low in the other three journals. The number of foreign countries contributing in all journals have increased rapidly since 1996. Canada, England, Belgium, Netherlands, China, and Spain were the countries with high contributions in JASIST. The authors from the USA have dominated the foreign-authored articles in all European journals. A simple linear regression analysis showed that 60% of variation in the proportion of foreign-authored articles in the set of five journals over the selected years could be explained by the percentage of foreign members on the editorial boards of the journals. This revised version was published online in June 2006 with corrections to the Cover Date.     

Specific heavy metal ion recovery with ion‐imprinted cryogels

In this study, the functional monomers, N‐methacryloyl‐l ‐aspartic acid and N‐methacryloyl‐l ‐cysteine were synthesized through a reaction between appropriate amino acids and methacryloyl chloride. Then, Pb(II) or Cd(II) ion‐imprinted 2‐hydroxyethyl methacrylate based cryogels were prepared by free radical polymerization method under partially frozen conditions. Following the characterization of matrices, adsorption of heavy metal ions was examined in batch mode from aqueous solution considering several parameters affecting the adsorption performance. The actual adsorption capacities were 44.5, 65.3, and 86.7 mg/g for Cd‐1, Cd‐2, and Cd‐3 cryogels meanwhile those were 41.9, 86.3, and 122.7 mg/g for Pb‐1, Pb‐2, and Pb‐3 cryogels, respectively at optimum pH: 5.5. By increasing temperature, adsorption capabilities of both cryogels were inhibited because of the electrostatic nature of coordinated covalent bonds and collapsing of coordination spheres. The adsorption process was very fast, the equilibrium adsorption was achieved in about 60 min, which was directly related to macroporous structure and interconnected flow‐channels of cryogels. Kinetics and adsorption isotherms were also studied. Langmuir isotherms and pseudo‐second order kinetic model were well suited to adsorption data, which also indicated that the process occurred without any diffusion restrictions or steric hindrances. Finally, the competitive adsorption studies were performed using multi‐ion containing synthetic wastewater to show whether the cryogels developed are suitable for specific heavy metal recycling or not. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43095.     

Coprecipitation of Cefuroxime Axetil-PVP composite microparticles by batch supercritical antisolvent process

Batch supercritical antisolvent precipitation (SAS) process was used to coprecipitate Cefuroxime Axetil amorphous (CFA, antibiotic) and Polyvinylpyrrolidone (PVP-K30) for preparing drug-polymer composite particles. Solutions of CFA and PVP-K30 in methanol with overall concentrations of 50-150 mg/ml and polymer/drug ratios of 1/1-4/1 were sprayed into the CO₂ at 70-200 bar and 35-50 °C with drug + polymer solution injection rates of 0.85 and 2.5 ml/min. Spherical particles having mean diameters of 1.88-3.97 μm, distribution ranges of 0.82-9.7 μm (the narrowest distribution) and 0.91-46.64 μm (the broadest distribution) were obtained. Mean particle size was not affected significantly with the change of process parameters. It was only affected by pressure change. On the other hand particle size distribution was affected by pressure, temperature, drug + polymer solution injection rate and concentration. It was observed that temperature and polymer/drug ratio affected the particle morphology most. The drug release rate of SAS-coprecipitated CFA-PVP (1/1) particles was almost 10 times slower than the drug alone. As the ratio of the polymer increased drug release rate also increased due to the wetting effect of PVP.     

Productivity ratings of institutions based on publication in Scientometrics,Informetrics, and Bibliometrics, 1981–2000

The author surveyed a set of ten scholarly journals that publish the mainstream of papers in the field of Scientometrics, Informetrics, and Bibliometrics (SIB). The survey is limited only to the research articles published in the field for the two decades period 1981–2000. Each journal was examined issue by issue for the institutional affiliations of contributing authors. Institutional rankings for the total period and the two decade periods; 1981–1990 and 1991–2000 were determined by awarding credit to the authors" institutions based on authorship. In the composite of ten journals, the University Sheffield (England), the University of North Carolina (USA), the University of Leiden (Netherlands), the City University of London (England), the National Institute of Science, Technology and Development Studies (India), the University of Sussex (England), the University of Illinois (USA), the University of Michigan (USA), the Hungarian Academy of Sciences Library (Hungary), and Indiana University (USA) emerged as the ten most productive institutions for the period 1981–2000. This revised version was published online in June 2006 with corrections to the Cover Date.     

Effect of growth rate and lamellar spacing on microhardness in the directionally solidified Pb-Cd, Sn-Zn and Bi-Cd eutectic alloys

Lead-cadmium, Zinc-tin and Bismuth-cadmium of (99.99%) high purity eutectic alloys were melted in a graphite crucible under vacuum atmosphere. These eutectic alloys were directionally solidified upward with a constant temperature gradient G and different growth rates V in the Bridgman type directional solidification furnace. The lamellar spacings and microhardness H _V were measured from both transverse section and longitudinal section of the specimen. The variations of H _V with respect to V and have been determined by using the linear regression analysis method. H _V values increase with the increasing values of V and decrease with the increasing values. The Hall-petch type relationships obtained in this work have been compared with the previous works.     

Combining molecular imprinted nanoparticles with surface plasmon resonance nanosensor for chloramphenicol detection in honey

The focus of this article is to develop a surface plasmon resonance (SPR) nanosensor to determine chloramphenicol (CAP) using the molecularly imprinted nanoparticles. The CAP imprinted nanoparticles were prepared by miniemulsion polymerization method. Then, the nanoparticles were attached onto the SPR nanosensor surface via temperature‐controlled evaporation. Surface characterization studies were performed with atomic force microscopy and contact angle measurements. Kinetic studies were performed with CAP solutions in the concentration range of 0.155–6.192 nM. Florphenicol (FLP) and thiamphenicol (TAP) having similar chemical structures to the template (i.e., CAP) were chosen as competitors to determine selectivity of the nanoparticles. Selectivity constants were observed as 8.86 for CAP/TAP and 8.36 for CAP/FLP. The detection limit was calculated as 40 ng/kg honey sample. In the light of these results, it was emphasized that the SPR nanosensor is able to recognize CAP selectively and has a potential for real‐time CAP detection in honey sample. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013