Thermo economic evaluation of oxy fuel combustion cycle in Kazeroon power plant considering enhanced oil recovery revenues简

Oxy fuel combustion and conventional cycle （currently working cycle） in Kazeroon plant are modeled using commercial thermodynamic modeling software. Economic evaluation of the two models regarding the resources of transport and injection of carbon dioxide into oil fields at Gachsaran for enhanced oil recovery in the various oil price indices is conducted and indices net present value （NPV） and internal rate of return on investment （IRR） are calculated. The results of the two models reveal that gross efficiency of the oxy fuel cycle is more than reference cycle （62% compared to 49.03%）, but the net efficiency is less （41.85% compared to 47.92%） because of the high-energy consumption of the components, particularly air separation unit （ASU） in the oxy fuel cycle. In this model, pure carbon dioxide with pressure of 20~ 105 Pa and purity of 96.84% was captured. NOx emissions also decrease by 4289.7 tons per year due to separation of nitrogen in ASU. In this model, none of the components of oxy fuel cycle is a major engineering challenge. With increasing oil price, economic justification of oxy fuel combustion model increases. With the price of oil at $ 80 per barrel in mind and $ 31 per ton fines for emissions of carbon dioxide in the atmosphere, IRR is the same for both models.     

Robust design optimization of electro-thermal microactuator using probabilistic methods

Micromachining of microelectromechanical systems which is similar to other fabrication processes has inherent variation that leads to uncertain dimensional and material properties. Methods for optimization under uncertainty analysis can be used to reduce microdevice sensitivity to these uncertainties in order to create a more robust design, thereby increasing reliability and yield. In this paper, approaches for uncertainty and sensitivity analysis, and robust optimization of an electro-thermal microactuator are applied to take into account the influence of dimensional and material property uncertainties on microactuator tip deflection. These uncertainties include variation of thickness, length and width of cold and hot arms, gap, Young modulus and thermal expansion coefficient. A simple and efficient uncertainty analysis method is performed by creating second-order metamodel through Box-Behnken design and Monte Carlo simulation. Also, the influence of uncertainties has been examined using direct Monte Carlo Simulation method. The results show that the standard deviations of tip deflection generated by these uncertainty analysis methods are very close to each other. Simulation results of tip deflection have been validated by a comparison with experimental results in literature. The analysis is performed at multiple input voltages to estimate uncertainty bands around the deflection curve. Experimental data fall within 95 % confidence boundary obtained by simulation results. Also, the sensitivity analysis results demonstrate that microactuator performance has been affected more by thermal expansion coefficient and microactuator gap uncertainties. Finally, approaches for robust optimization to achieve the optimal designs for microactuator are used. The proposed robust microactuators are less sensitive to uncertainties. For this goal, two methods including Genetic Algorithm and Non-dominated Sorting Genetic Algorithm are employed to find the robust designs for microactuator.     

Geometric Patterns,Light and Shade: Quantifying Aperture Ratio and Pattern Resolution in the Performance of Shading Screens

This research focuses on the application and performance assessment of geometric patterns as shading screens and shows how the geometric patterns can function as a design agency, an environmental control system, and a cultural element. We begin with a brief review of the underlying rules of creating two-dimensional geometric patterns, and then look at how these patterns evolve as three-dimensional shading screens in buildings. We next discuss a predictive model for translating complex patterns to simple patterns concerning their perforation ratio, granularity, and morphology. This is followed by an experimental and simulation study for measuring the daylighting performance of some simple shading screens. The result of this phase assesses the agreement among experimental and numerical studies. Finally, we evaluate the performance of a screen inspired by a Persian pattern.     

The Effect of Ti on Mechanical Properties of Extruded In-Situ Al-15 pct Mg2Si Composite

This work was carried out to investigate the effect of different Ti concentrations as a modifying agent on the microstructure and tensile properties of an in-situ Al-15 pctMg₂Si composite. Cast, modified, and homogenized small ingots were extruded at 753 K (480 °C) at the extrusion ratio of 18:1 and ram speed of 1 mm/s. Various techniques including metallography, tensile testing, and scanning electron microscopy were used to characterize the mechanical behavior, microstructural observations, and fracture mechanisms of this composite. The results showed that 0.5 pctTi addition and homogenizing treatment were highly effective in modifying Mg₂Si particles. The results also exhibited that the addition of Ti up to 0.5 pct increases both ultimate tensile strength (UTS) and tensile elongation values. The highest UTS and elongation values were found to be 245 MPa and 9.5 pct for homogenized and extruded Al-15 pctMg₂Si-0.5 pctTi composite, respectively. Fracture surface examinations revealed a transition from brittle fracture mode in the as-cast composite to ductile fracture in homogenized and extruded specimens. This can be attributed to the changes in size and morphology of Mg₂Si intermetallic and porosity content.     

Resistive switching memory using biomaterials

Resistive switching memory (ReRAM) is emerging as a developed technology for a new generation of non-volatile memory devices. Natural organic biomaterials are potential elements of environmentally-benign, biocompatible, and biodegradable electronic devices for information storage and resorbable medical implants. Here, we highlight progress in exploiting biomaterials to fabricate a special category of bio-nanoelectronic memories called biodegradable resistive random access memory (bio-ReRAM). Bio-ReRAMs are beneficial because they are non-toxic and environmentally benign. Various types of biomaterials with their chemical compound, bio-ReRAM device design and structure, their relevance resistive switching (RS) behavior, and conduction mechanism are considered in detail. Particularly, we report physically-transient devices, their corresponding switching mechanism, and their dissolution by immersion in water. Finally, we review recent progress in the development of various types of flexible bio-ReRAMs, focusing on their flexibility and reliability as bendable nanoelectronics. Because most of these devices are candidates to become wearable, skin-compatible, and even digestible smart electronics, we discuss the future improvement of natural materials and the perspective of novel bio-ReRAMs.     

Low Temperature Hall Effect Investigation of Conducting Polymer-Carbon Nanotubes Composite Network

Polypyrrole (PPy) and polypyrrole-carboxylic functionalized multi wall carbon nanotube composites (PPy/f-MWCNT) were synthesized by in situ chemical oxidative polymerization of pyrrole on the carbon nanotubes (CNTs). The structure of the resulting complex nanotubes was characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The effects of f-MWCNT concentration on the electrical properties of the resulting composites were studied at temperatures between 100 K and 300 K. The Hall mobility and Hall coefficient of PPy and PPy/f-MWCNT composite samples with different concentrations of f-MWCNT were measured using the van der Pauw technique. The mobility decreased slightly with increasing temperature, while the conductivity was dominated by the gradually increasing carrier density.     

Removal of ciprofloxacin from aqueous solution by a continuous flow electro-coagulation process

This study deals with the performance and modeling of the electro-coagulation process for ciprofloxacin (CIP) removal by using aluminum electrode as anode in a continuous electrochemical reactor. The initial pH, temperature, current density, time and flow rate were selected as independent variables in response surface methodology (RSM) involving a five-level central composite design (CCD), while CIP removal efficiency was considered as the response function. The result of optimization showed that the maximum amount of CIP removal efficiency (88%) presented at the optimal condition of pH=5.6, t=100min, T=25.5 °C, I=5.6mA/cm² and V=25.9 mL/min. In addition, the mineralization of the CIP was investigated by chemical oxygen demand (COD) and total organic carbon (TOC) measurements that showed 77% COD removal and 49%TOC removal.     

Feldspar/titanium dioxide/chitosan as a biophotocatalyst hybrid for the removal of organic dyes from aquatic phases

Feldspar/titanium dioxide/chitosan hybrid, a photoactive biocompatible adsorbent for anionic dyes, was synthesized, characterized, and successfully tested. The adsorbent characterization, pH role, adsorbent dose effect, equilibrium data, kinetic plats, and thermodynamic parameters are reported. The point of zero charge for the hybrid was measured to be 8.3, and the most favorable pH range for the adsorption process was found to be below this pH value. The adsorption equilibrium study demonstrated that the Freundlich model was best fitted to the experimental data. Without UV light exposure, the prepared adsorbent adsorbed 72 mg of Acid Black 1 (AB1)/g of sorbent (86% removal) from a 100‐mL solution with an initial dye concentration of 50 mg/L, whereas UV irradiation resulted in an increase in the elimination of AB1 dye (97% removal). The kinetic data was depicted well by the pseudo‐second‐order model. The thermodynamic parameters indicated that the reaction between the hybrid and the dye was exothermic and also spontaneous at lower temperatures. In the batch desorption process, several aqueous solutions adjusted to different pH values were tested, and the best desorption performance (90% desorption) was achieved at pH 11. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40247.     

Study of the anticorrosive properties of polypyrrole/polyaniline bilayer via electrochemical techniques

In this work, using electrochemical techniques the authors investigated the protective properties of a polypyrrole/polyaniline bilayer as a conductive polymer. A polypyrrole/polyaniline bilayer was deposited on carbon steel substrate by potentiostatic method. The electric capacitance and resistance of the films were monitored with the immersion time in a corrosive solution to investigate the water permeability of the films. Polypyrrole/polyaniline bilayer has a relatively low permeability and good catalytic behavior in passivation of carbon steel in longer periods. The results show that the bilayer has a better anticorrosive behavior compared to homopolymers (polypyrrole and polyaniline).