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排序方式: 共有79条查询结果,搜索用时 31 毫秒
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Murat Özen Myrjam MertensJan Luyten Frans SnijkersHans D’Hondt Pegie Cool 《Ceramics International》2012,38(1):619-625
In this paper, the amorphous barium titanate precursor was prepared by the peroxo-hydroxide method and post-treated by various drying procedures, such as: room temperature drying, room temperature vacuum drying and vacuum drying at 50 °C. The objective in the latter two treatments was to increase the Ti-O-Ba bonds of the precursor. The post-treated precursors were compared with the untreated (i.e., ‘wet’) precursor. Also, a barium titanate precursor was prepared by an alkoxide route. Afterwards, the precursors were hydrothermally treated at 200 °C in a 10 M NaOH solution. Vacuum drying of the precursor seemingly promoted the formation of Ti-O-Ti bonds in the hydrothermal end-product. The low Ba:Ti ratio (0.66) of the alkoxide-route prepared precursor lead to a multi-phase hydrothermal product with BaTiO3 as the main phase. In contrast, phase pure BaTiO3, i.e. without BaCO3 contamination, was obtained for the precursor which was dried at room temperature. Cube-shaped and highly crystalline BaTiO3 particles were observed by electron microscopy for the hydrothermally treated peroxo-hydroxide-route prepared precursor. 相似文献
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J. Kärger J. Caro P. Cool M.‐O. Coppens D. Jones F. Kapteijn F. Rodríguez‐Reinoso M. Stöcker D. Theodorou E. F. Vansant J. Weitkamp 《化学工程与技术》2009,32(10):1494-1511
Detailed knowledge of the transport properties of nanoporous materials is a prerequisite for their complete characterization and optimum technological exploitation. One of the best ways to attain this information is provided by the “microscopic” techniques of diffusion measurement, in particular by the pulsed field gradient technique of NMR and by interference microscopy and IR microscopy. Starting with the measuring principles, the various types of evidence as accessible by these techniques are illustrated. A large variety of host‐guest systems with both ordered and random pore networks have been studied, from microporous up to macroporous materials. The information obtained concerns diffusivities in the various pore domains, extra resistances at the interfaces between them and the associated exchange rates. 相似文献
5.
Tested the influence of ability, time, quality of instruction, motivation, and academic coursework on students' achievement, controlling for relevant background variables. Structural equation models were analyzed with longitudinal data from a national sample of 25,875 high school students. Intellectual ability and academic coursework had direct effects on achievement, and homework had a smaller direct effect. The indirect effects of quality of instruction and motivation were stronger than their direct effects; quality affected motivation, which affected coursework. Supplemental analyses were consistent with the initial findings. Results support these variables as influences on school learning, and support the theories from which the variables were derived. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
6.
Seftel EM Popovici E Beyers E Mertens M Zhu HY Vansant EF Cool P 《Journal of nanoscience and nanotechnology》2010,10(12):8227-8233
In this study we report the synthesis of a series of composite nanostructures comprising LDH and TiO2 phases. The materials characterization showed that the LDH crystallites are encapsulated inside the TiO2 matrix after the anatase seeds are deposited on MgxAl-LDHs. The structure in which LDH phase is embedded into anatase matrix is unique bringing important advantages to the photocatalytic performances of the nanocomposites. The photocatalytic activity of the prepared nanocomposites was tested on the degradation of the methylene blue (MB) in aqueous solution. The photocatalytic activities of the nanocomposites were compared with commercial TiO2 nanoparticles Degussa P25. The nanocomposites exhibited superior photocatalytic activity in basic environment because the negatively charged surface of TiO2 nanoparticles at high pH attracts the positively charged methylene blue species. 相似文献
7.
Cuticular hydrocarbons (CHC) and soldier defense secretions (SDS) were characterized for collections of Reticulitermes from six counties (Los Angeles, Orange, Riverside, San Bernardino, San Diego, and Santa Barbara) in southern California.
Collection sites included the type locality for R. hesperus, Lake Arrowhead (formerly known as Little Bear Lake) in the San Bernardino Mountains. In southern California, there are two
CHC phenotypes, SC-A and SC-B, which are easily distinguished by the presence or absence of 5-methyl pentacosane, 5-methyl
heptacosane, 5,17-dimethyl pentacosane, and 5,17-dimethyl heptacosane. These phenotypes are similar, but not identical, to
previously designated phenotypes of Reticulitermes from northern California. The SDS of termites collected from southern California were characterized; (—)-germacrene A was
abundant in all but the four samples from Lake Arrowhead. Soldiers of phenotype SC-A produced >79% germacrene A. The four
samples from Lake Arrowhead produced no germacrene A, but contained >78% γ-cadinene. The SDS from the Lake Arrowhead samples
were more similar to those of CA-A/CA-A′ from northern California than to any of the CHC phenotypes from southern California.
Soldiers of CHC phenotype SC-B produced germacrene A, with the proportion varying from 16.2 to 98.7%. The SDS of SC-B were
more similar to those of SC-A than to any of the phenotypes from northern California. The CHC phenotype SC-A found in southern
California likely represents R. hesperus and SC-B appears to be a new, as yet undescribed species. We discuss the state of current taxonomic research on Reticulitermes.
相似文献
Lori J. NelsonEmail: |
8.
Jarian Vernimmen Vera Meynen Myrjam Mertens Oleg I. Lebedev Gustaaf Van Tendeloo Pegie Cool 《Journal of Porous Materials》2012,19(2):153-160
Based on a facile one-pot templating synthesis, using a TS-1 zeolite recipe whereby part of the zeolite structure directing
agent is replaced by a mesopore templating agent, a trimodal material is formed. The resulting meso-TSM material combines
mesoporosity (Ti-MCM-41) with zeolitic features (TS-1) and a unique sheet-like morphology with uniform macroporous voids (macroholes).
Moreover, the macrohole formation, mesoporosity and zeolitic properties of the meso-TSM material can be controlled in a straightforward
way by adjusting the length of the hydrothermal treatment. This newly developed material may imply great potential for catalytic
redox applications and diffusion limitated processes because of its highly tunable character in all three dimensions (micro-,
meso- and macroporous scale). 相似文献
9.
Lucjan Chmielarz Piotr Kuśtrowski Marek Drozdek Małgorzata Rutkowska Roman Dziembaj Marek Michalik Pegie Cool Etienne F. Vansant 《Journal of Porous Materials》2011,18(4):483-491
SBA-15 mesoporous silicas modified with rhodium were studied as catalysts for the N2O decomposition reaction. Rhodium was deposited on SBA-15 by the Molecular Designed Dispersion (MDD) method using Rh(acac)3 as a precursor of active phase. The same method was used for the deposition of Cu, Fe, Al and Ti. The SBA-15 support modified
with metals were characterized with respect to metal loading (EPMA), structure (XRD), texture (BET), morphology (SEM), Rh
dispersion (oxygen chemisorption), surface acidity (pyridine adsorption) and chemical nature of introduced copper and iron
species (UV–vis-DRS). The rhodium-containing SBA-15 samples were found to be active catalysts for the N2O decomposition reaction. Deposition of Al on the Rh-loaded catalyst increased its activity. An opposite effect was observed
for the samples modified with Cu and Fe. 相似文献
10.
The paper describes an analytical method whereby the chemical composition of the polysaccharide fraction of woody materials, including the uronic acids and carbohydrate acid degradation products, can be completely determined. Sealed vessels, termed bombs, are used during the high temperature acid hydrolysis of the materials to retain volatile constituents that would otherwise be lost. High-Performance Liquid Chromatography (HPLC) is used for all of the analyses. The sample preparation procedures are simple and easily adopted into a routine. To demonstrate the reproducibility of the method, triplicate samples of Quaking aspen ( Populus tremuloides ) and White fir ( Abies concolor ) were analyzed. No significant peaks in the chromatograms were left unidentified. 相似文献