Potentiometric studies of oxidation–reduction reactions with redox copolymers

Polymeric oxidants in the bead form that were macroporous styrene/divinylbenzene copolymers containing N‐chlorosulfonamide functional groups (in sodium or hydrogen form) or N‐bromosulfonamide groups (in sodium form) were synthesized and investigated to determine their oxidizing powers. The redox potentials of the N‐chlorosulfonamide/sulfonamide and N‐bromosulfonamide/sulfonamide systems were determined by potentiometric studies at different pH values with aqueous solutions of Na₂SO₃, KCN, and KSCN as reducers. The formal redox potentials of the N‐chlorosulfonamide copolymers were 0.79, 0.44, and ?0.12 V at pH's of 1.8, 8.45, and 13.6, respectively. The formal redox potential of the N‐bromosulfonamide copolymer was about 100 mV higher in comparable conditions and in solutions over pH = 5 (e.g., 0.56 V at pH = 8.56). The comparatively higher oxidizing power of the N‐bromosulfonamide copolymer was particularly evident in a strong alkaline medium (in which the N‐chlorosulfonamide copolymer was not reactive). In contrast, the N‐chlorosulfonamide copolymer showed strong oxidative properties in acidic media (in which the N‐bromosulfonamide copolymer decomposed itself). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Classification of honeys by principal component analysis on the basis of chemical and physical parameters

Summary Eighteen chemical and physical parameters of nectar and honeydew honeys were determined and the results were analysed statistically by the method of principal component analysis. On the plots of principal component loadings, the honeys were divided into the following groups: (1) acacia honey; (2) rape honey; (3) linden, floral (nectar coming from various plants) and heather honeys; (4) honeydew honey. The samples which were a blend of nectar and honeydew honeys may be considered as a separate group between 3 and 4. The most important first principal component was strongly associated with the value of electrical conductivity, the contents of ash, free acids and proline, as well as with the pH and the diastase number. The principal component loadings and linear correlation suggested that these parameters contributed much more to the classification of honeys than apparent reducing sugars, apparent sucrose, mono-, di-, and trisaccharides, glucose and fructose. The classification of honeys by the method of principal component analysis may serve as an additional tool in specifying samples on the basis of their chemical composition.

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Klassifizierung von Honigen durch chemische und physikalische Parameter mit Hilfe der Hauptkomponentenanalyse

Zusammenfassung 18 chemische und physikalische Parameter der Nektar- und Honigtauhonige wurden bestimmt und die Ergebnisse statistisch mit Hilfe der Hauptkomponentenanalyse ausgewertet. Danach konnten die Honige in folgende Gruppen unterteilt werden: 1) Akazienhonige, 2) Rapshonige, 3) Linden-, Blüten-und Heidehonige, 4) Honigtauhonige. Zwischen dem Nektarhonig und Honigtauhonig lagen wahrscheinlich die Proben von Mischhonigen aus Blüten- und Waldtracht. Die bedeutendste erste Hauptkomponente war mit folgenden Parametern verbunden: elektrischer Leitfähigkeitswert und Aschegehalt, Gehalt an freien Säuren und Prolin sowie der pH-Wert und Diastasezahl. Aufgrund der Hauptkomponentenladungen und der linearen Korrelation kann angenommen werden, daß diese Parameter für die Honigklassifizierung von größerer Bedeutung sind als der Gehalt an reduzierenden Zuckern, scheinbarer Saccharose, Mono-, Di- und Trisaccharide, Glucose und Fructose. Die Klassifizierung der Honige mit Hilfe der Hauptkomponentenanalyse kann bei der Spezifikation einer Honigprobe aufgrund ihrer chemischen Zusammensetzung von Nutzen sein.

     

Efficient algorithms for singleton arc consistency

In this paper, we propose two original and efficient approaches for enforcing singleton arc consistency. In the first one, the data structures used to enforce arc consistency are shared between all subproblems where a domain is reduced to a singleton. This new algorithm is not optimal but it requires far less space and is often more efficient in practice than the optimal algorithm SAC-Opt. In the second approach, we perform several runs of a greedy search (where at each step, arc consistency is maintained), possibly detecting the singleton arc consistency of several values in one run. It is an original illustration of applying inference (i.e., establishing singleton arc consistency) by search. Using a greedy search allows benefiting from the incrementality of arc consistency, learning relevant information from conflicts and, potentially finding solution(s) during the inference process. We present extensive experiments that show the benefit of our two approaches.     

Traumatic Acid Reduces Oxidative Stress and Enhances Collagen Biosynthesis in Cultured Human Skin Fibroblasts

Traumatic acid (TA) is a plant hormone (cytokinin) that in terms of chemical structure belongs to the group of fatty acids derivatives. It was isolated from Phaseolus vulgaris. TA activity and its influence on human cells and organism has not previously been the subject of research. The aim of this study was to examine the effects of TA on collagen content and basic oxidative stress parameters, such as antioxidative enzyme activity, reduced glutathione, thiol group content, and lipid peroxidation in physiological conditions. The results show a stimulatory effect of TA on tested parameters. TA caused a decrease in membrane phospholipid peroxidation and exhibited protective properties against ROS production. It also increases protein and collagen biosynthesis and its secretion into the culture medium. The present findings reveal that TA exhibits multiple and complex activity in fibroblast cells in vitro. TA, with its activity similar to unsaturated fatty acids, shows antioxidant and stimulatory effects on collagen biosynthesis. It is a potentially powerful agent with applications in the treatment of many skin diseases connected with oxidative stress and collagen biosynthesis disorders.     

Coupled aeroelastic oscillations of a turbine blade row in 3D transonic flow

heodctionThe trend of imPrved gas ndine engine designwith higher Hntalc blade loadin and sInallerPhysical size attraCtS much Mon to the aeroelasticbehayour of blades not Ouly in comPI'essors, bu also intuIbines. Flow-induced triine and comPressor bladesoscillations can lead to fatigUe failures of a constrUctionand so rePrsent imPorIant Problems of reliability, safety,and operatin cost.The hahonal aPProach in flutter calculations ofblW disks is based on twency doInain analysis"ro,in whi…     

Exponential and Logarithmic Functions Using Standard CMOS 0.8 μm Technology

The integration of various mathematical functions in ananalogue mode is a growing concern, e.g., for image processingapplications. Specific cells using CMOS technology which performarithmetical operations [1,2] have already been designed. This paperdescribes an extension of the previous cells performing the two mostfundamental transcendental functions: logarithm and exponential. Thedesign of this extension and technological issues are detailed in thispaper. The exponential function is based on MOS transistors operatingin the weak inversion region, in order to behave like bipolar transistors while remaining in a standard CMOS technology.     

白化菌对TMP和溶解桨厂运行的影响

生物技术与术材化学、真菌学、生物化学和遗传学结合为制浆造纸工业开发出一种白化真菌产品．在制浆前用其预处理木片，能够降低水材中的树脂含量并提高术片的整体白度，减轻树脂障碍．降低纸浆的漂白要求。有人提出白化菌预处理还能起到纤维改性的作用。     

Nuclear microscopy in biomedical analysis with special emphasis on clinical metal biology

Nuclear microscopy based upon developments in high energy ion beam techniques is by now an accepted technique in many fields of research. The advancements into the biomedical field have, however, been slower than expected. A major factor explaining this tendency is the availability of nuclear microscopy. This paper reviews briefly the biomedical work using nuclear microscopy that has been carried out since the 4^th International Conference on Nuclear Microprobe Technology and Applications held in Shanghai. Nuclear microscopy of isolated individual blood cells from patients adversely affected by metal exposure from dental amalgam has been performed both before and after removal of the metallic fillings. The elemental profile of blood cells was more or less normalised after treatment. Some of these results will be presented to illustrate a medical application. Results from bulk analysis by ICP-MS of erythrocytes and plasma before and after treatment will also be presented to illustrate the difference in information content between these two approaches as well as the need for complementary information in solving biomedical problems. As part of a larger study of acute porphyria, nuclear microscopy of blood cells was included among the 78 laboratory tests. The approach in this study was unbiased in the sense that no hypothesis was formulated as to which laboratory parameters would be the most explanatory for health or disease. Multivariate discriminant analysis was applied to the large amounts of data acquired. This approach led to the hypothesis that oxidative stress increased the synthesis of manganese-dependent superoxide dismutase in the mitochondria of polymorphonuclear leukocytes, explaining the increase of manganese in these cells. Antioxidant therapy was therefore applied to a couple of patients with porphyria, however, without clinical success.