Atomic layer deposition of GDC cathodic functional thin films for oxide ion incorporation enhancement

In this paper, we report successful fabrication of a gadolinia-doped ceria (GDC) thin film using atomic layer deposition (ALD) for improving the performance of solid oxide fuel cells (SOFCs). By varying the deposition conditions and adjusting the configuration of the ALD supercycle, the doping ratio of ALD GDC was controlled. The morphology, crystallinity, and chemical composition of ALD GDC thin films were analyzed. ALD GDC showed different surface chemistry, including oxidation states, at different doping ratios. The application of ALD GDC in a SOFC led to an output power density enhancement greater than 2.5 times. With an anodic aluminum oxide (AAO) porous support structure, an ALD GDC thin film SOFC (TF-SOFC) showed a high power density of 288.24 mW/cm² at an operating temperature of 450°C.     

Comparison of mechanical properties of ground corn stover,switchgrass, and willow and their pellet qualities

Mechanical and physical properties of ground corn stover, switchgrass, and willow were measured and compared in addition to the quality of pellets. Biomass was size-reduced with two different screen sizes (3.175 and 6.35?mm) and conditioned to obtain samples at two different moisture contents (17.5 and 20% on wet basis). Ground switchgrass had the smallest and willow had the highest D₅₀ when size-reduced with the same screen size. Hydrostatic triaxial compression tests were performed using the cubical triaxial tester to determine the bulk modulus, compression index, and spring-back index at specific unloading pressures (20, 45, 70, and 95?kPa). The trends of pressure vs. volumetric strain and void ratio vs. natural log of pressure were similar for all three materials; however, the magnitudes were different. Willow, size-reduced with 3.175?mm screen size at 17.5% wet basis, had the highest bulk modulus among different conditions of all the three biomass. Pellet durability values for all the three materials were higher than 80%. Corn stover pellets formed with 3.175?mm screen size at 20% wet basis had the highest diametral tensile and axial compressive strengths among different conditions for all the three biomass, however the values were not significantly different (p?>?0.05).     

Microfluidic Spinning of Cell‐Responsive Grooved Microfibers

Engineering living tissues that simulate their natural counterparts is a dynamic area of research. Among the various models of biological tissues being developed, fiber‐shaped cellular architectures, which can be used as artificial blood vessels or muscle fibers, have drawn particular attention. However, the fabrication of continuous microfiber substrates for culturing cells is still limited to a restricted number of polymers (e.g., alginate) having easy processability but poor cell–material interaction properties. Moreover, the typical smooth surface of a synthetic fiber does not replicate the micro‐ and nanofeatures observed in vivo, which guide and regulate cell behavior. In this study, a method to fabricate photocrosslinkable cell‐responsive methacrylamide‐modified gelatin (GelMA) fibers with exquisite microstructured surfaces by using a microfluidic device is developed. These hydrogel fibers with microgrooved surfaces efficiently promote cell encapsulation and adhesion. GelMA fibers significantly promote the viability of cells encapsulated in/or grown on the fibers compared with similar grooved alginate fibers used as controls. Importantly, the grooves engraved on the GelMA fibers induce cell alignment. Furthermore, the GelMA fibers exhibit excellent processability and could be wound into various shapes. These microstructured GelMA fibers have great potential as templates for the creation of fiber‐shaped tissues or tissue microstructures.     

Synthesis of LiNiO2 cathode by the combustion method

To determine optimum conditions for the synthesis of LiNiO₂ by the combustion method, syntheses were carried out in air and under oxygen at various calcination temperatures and for different times. The electrochemical properties of the prepared samples were then investigated. The optimum conditions are preheating at 400 °C for 30 min in air in the mole ratio of urea to nitrate 3.6 and calcination at 750 °C for 36 h under O₂. The LiNiO₂ synthesized under these conditions had a first discharge capacity of 189 mAh g⁻¹ at 0.1 C-rate and relatively good cycling performance. This sample has a larger value of I ₀₀₃/I ₁₀₄ (smaller cation mixing) and a smaller R-factor (larger hexagonal ordering). Cycling performance was investigated in various voltage ranges. The first discharge capacity increased as the upper limit of the voltage range rose. The first discharge capacity was small but cycling performance was good when the sample was cycled in the voltage range with the lowest upper limit.     

GENERATING OPTIMAL CONFIGURATIONS IN STRUCTURAL DESIGN USING SIMULATED ANNEALING

This paper presents a combinatorial optimization procedure based on the simulated annealing approach for generation of optimal configuration of structural members. The work is based on altering the finite element model of structure by removing or restoring elements to minimize the material use subject to constraints on maximum stress value and maintenance of connectivity between elements. Such an optimization problem is categorized as a large-scale, non-convex and non-linear problem. Thus, the problem can have multi-minima and it is important to find the global optimum solution as opposed to a local minimization. To improve the computational efficiency, the non-linear shape optimization problem has been linearized and to account for the difference between the non-linear and the linearized values a correction factor is implemented. To illustrate the approach, several design examples are presented and the effect of the parameter of the simulated annealing on the final configuration design is examined. © 1997 by John Wiley & Sons, Ltd.     

Microfabricated Biomaterials for Engineering 3D Tissues

Mimicking natural tissue structure is crucial for engineered tissues with intended applications ranging from regenerative medicine to biorobotics. Native tissues are highly organized at the microscale, thus making these natural characteristics an integral part of creating effective biomimetic tissue structures. There exists a growing appreciation that the incorporation of similar highly organized microscale structures in tissue engineering may yield a remedy for problems ranging from vascularization to cell function control/determination. In this review, we highlight the recent progress in the field of microscale tissue engineering and discuss the use of various biomaterials for generating engineered tissue structures with microscale features. In particular, we will discuss the use of microscale approaches to engineer the architecture of scaffolds, generate artificial vasculature, and control cellular orientation and differentiation. In addition, the emergence of microfabricated tissue units and the modular assembly to emulate hierarchical tissues will be discussed.     

Systematic generation of alternative production schedules

We propose a systematic approach for generating alternative production schedules to address two challenges in implementing optimization-based scheduling techniques in industrial settings: (a) the limited scope of the scheduling models due to modeling simplifications, and (b) the consideration of shop-floor nervousness. We first introduce metrics to quantify specific characteristics of a schedule (e.g., number of batches and degree of nervousness). Next, we favor, at different degrees, such characteristics in each alternative schedule, by penalizing the metrics in the objective function. Through illustrative instances, we show that multiple alternative schedules, including schedules with desired properties can readily be generated.     

Admittance Spectroscopy of Polycrystalline ZnO-Bi2O3 and ZnO-BaO Systems

Admittance spectroscopy was used to characterize the bulk electron traps in polycrystalline ZnO-Bi²O³ and ZnO-BaO systems. Temperatures from 30 to 350 K and a frequency range from 1.0 to 33.3 kHz were used. Admittance spectra for the ZnO-Bi²O³ system showed large variations with sintering atmosphere and heat treatment. A trap is observed at 0.33 eV below the conduction band edge in both systems. This trap is likely to be associated with an ionized oxygen vacancy. A possible explanation of primitive varistor characteristics in terms of the roles of the electronic defects is presented.