Time temperature equivalence in plasticized PVC

The viscoelastic response of plasticized PVC was determined from stress-relaxation data over a wide range of time at different temperatures. The relaxation modulus as a function of time was determined from these data. The relaxation curves were then shifted horizontally to obtain a master curve at a reference temperature. The amount of shift was evaluated using the WLF equation. The coefficients C and C used in the equation for the PVC were determined according to the method of reduced variables.     

Preparation and characterization of low-halogen and nonhalgoen fire-resistant low-smoke (FRLS) cable sheathing compound from blends of functionalized polyolefins and PVC

An attempt is made to develop a novel series of cable sheathing compounds with variation in chlorine content and sufficient fire retardance and unique low-smoke characteristics. These are prepared by blending PVC and functionalized polyolefins in different compositions. PE and EPDM have been functionalized by grafting dibutyl maleate (DBM) using DCP as initiator. FRLS compounds made from PVC-functionalized polyolefin blends possess the special characteristics of low-smoke, low-acid-gas generation, increased fire retardance, and improved volume resistivity, which are much better in comparison with a typical PVC sheathing compound. Thermoplastic elastomer (TPE) based nonhalogen FRLS compounds are also reported. The mechanisms for grafting, polymer-polymer and polymer-filler interactions have been presented.     

NodeWiz: Fault-tolerant grid information service

Large scale grid computing systems may provide multitudinous services, from different providers, whose quality of service will vary. Moreover, services are deployed and undeployed in the grid with no central coordination. Thus, to find out the most suitable service to fulfill their needs, or to find the most suitable set of resources on which to deploy their services, grid users must resort to a Grid Information Service (GIS). This service allows users to submit rich queries that are normally composed of multiple attributes and range operations. The ability to efficiently execute complex searches in a scalable and reliable way is a key challenge for current GIS designs. Scalability issues are normally dealt with by using peer-to-peer technologies. However, the more reliable peer-to-peer approaches do not cater for rich queries in a natural way. On the other hand, approaches that can easily support these rich queries are less robust in the presence of failures. In this paper we present the design of NodeWiz, a GIS that allows multi-attribute range queries to be performed efficiently in a distributed manner, while maintaining load balance and resilience to failures.     

An Instant,Green, Microwave Irradiated Process for the Preparation of Advanced,Hybrid, Nanoflower of Thorium Oxide and Thorium Oxalate Hydrate Useful for Broad Application Spectrum

Protection of Metals and Physical Chemistry of Surfaces - We report a facile and reproducible method to synthesize advanced, homogenized, hybrid, nanoflower of thorium oxide and thorium oxalate...     

Poly(acrylamide) functionalized chitosan: An efficient adsorbent for azo dyes from aqueous solutions

In the present communication we report on the optimization of persulfate/ascorbic acid initiated synthesis of chitosan-graft-poly(acrylamide) (Ch-g-PAM) and its application in the removal of azo dyes. The optimum yield of the copolymer was obtained using 16 × 10⁻² M acrylamide, 3.0 × 10⁻² M ascorbic acid, 2.4 × 10⁻³ M K₂S₂O₈ and 0.1 g chitosan in 25 mL of 5% aqueous formic acid at 45 ± 0.2 °C. Ch-g-PAM remained water insoluble even under highly acidic conditions and could efficiently remove Remazol violet and Procion yellow dyes from the aqueous solutions over a pH range of 3–8 in contrast to chitosan (Ch) which showed pH dependent adsorption. The adsorption data of the Ch-g-PAM and Ch for both the dyes were modeled by Langmuir and Freundlich isotherms where the data fitted better to Langmuir isotherms. To understand the adsorption behavior of Ch-g-PAM, adsorption of Remazol violet on to the copolymer was optimized and the kinetic and thermodynamic studies were carried out taking Ch as reference. Both Ch-g-PAM and Ch followed pseudo-second-order adsorption kinetics. The thermodynamic study revealed a positive heat of adsorption (ΔH°), a positive ΔS° and a negative ΔG°, indicating spontaneous and endothermic nature of the adsorption of RV dye on to the Ch-g-PAM. The Ch-g-PAM was found to be very efficient in removing color from real industrial wastewater as well, though the interfering ions present in the wastewater slightly hindered its adsorption capacity. The data from regeneration efficiencies for ten cycles evidenced the high reusability of the copolymer in the treatment of waste water laden with even high concentrations of dye.     

Study of crystal structure,dielectric, magnetic and magnetoelecrtic properties of xCoFe2O4-(1-x)Na0.5Bi0.5TiO3 composites

Multiferroic composites of spinel ferrite and ferroelectric xCoFe₂O₄ – (1-x)Na_0.5Bi_0.5TiO₃ (with x = 0.10,0.30,0.50) were efficiently prepared by standard solid state reaction mechanism. X-ray diffractometer was used to analyze crystal structure of the prepared composites. The observed XRD patterns of the composites comprise peaks of both the phases i.e. ferrite and ferroelectric, with no sign of secondary peaks. Rietveld refinement of XRD data further confirms the coexistence of these two phases with cubic (Fd3m) and rhombohedral (R3c) symmetry corresponding to ferrite and ferroelectric phase respectively. The 3-dimensional overview of crystal structure of pure CoFe₂O₄ and Na_0.5Bi_0.5TiO₃ and of composite 0.50CoFe₂O₄?0.50Na_0.5Bi_0.5TiO₃ is generated by using refined parameters. The dielectric constant (ε´) and dielectric loss (tanδ) values were recorded as a function of frequency ranging from 100?Hz to 7?MHz and at different temperatures. Both ε´ and tanδ follow dispersion pattern at lower frequencies while show frequency independent behavior at higher frequencies. The magnetic evaluation carried by analyzing M-H hysteresis loop reveals the ferrimagnetic characteristics of these composites. The highest value of magnetic moment is 1.12μ_B observed for composite 0.50CoFe₂O₄ – 0.50Na_0.5Bi_0.5TiO_3. Magnetoelectric (ME) voltage coefficient (α) was also demonstrated to observe the interaction between ferrite and ferroelectric phases. The highest value of α (72.72μV/Oe cm) is obtained for low ferrite composition 0.10CoFe₂O₄ – 0.90Na_0.5Bi_0.5TiO₃, which suggests the dependence of magnetoelectric response on the resistivity of the composites.     

Measurement of 40k as an indicator of body potassium: implication for diabetes and other disease conditions

Potassium (K) content in 408 male workers of a rare earths processing plant was estimated using a shadow shield whole body counter. The average K content in the non-vegetarian and vegetarian group was found to be 1.5 g kg(-1) and 2.1 g kg(-1) respectively. The absorbed dose due to 40K is determined as 0.18 +/- 0.02 mGy. While the K content was found to be proportional to body build index, it is inversely proportional to slenderness. Body K was maximum in the middle aged group (35-45 y) and a minimum in younger and older persons. The correlation of potassium content with some disease patterns was also studied. Diabetes mellitus patients were observed to have low K content of 0.9 +/- 0.2 g kg(-1) and those who suffer from cardiovascular disorders were found to have high K content 2.7 +/- 0.3 g kg(-1). The studies showed that the depletion of body K content takes place a few years prior to the clinical detection of diabetes and it builds up a few years before the clinical detection of cardiovascular disorders. It is stressed that the medical information is preliminary as the number of subjects studied was not very large. Wider and in depth study by various groups can hopefully strengthen the observation.     

Increase in the yield of silicon carbide whiskers from rice husk

Favourable conditions for the growth of good quality silicon carbide (SiC) whiskers from rice husk have been discussed in the light of available evidence on the probable growth mechanism and the theoretical understanding of the same. Preliminary results indicate an increase in whisker yield at lower temperatures and coarsening of whiskers with longer duration of conversion.