Mechanical,electrical, and thermal expansion properties of carbon nanotube-based silver and silver-palladium alloy composites

The mechanical, electrical, and thermal expansion properties of carbon nanotube（CNT）-based silver and silver–palladium（10：1, w/w） alloy nanocomposites are reported. To tailor the properties of silver, CNTs were incorporated into a silver matrix by a modified molecular level-mixing process. CNTs interact weakly with silver because of their non-reactive nature and lack of mutual solubility. Therefore, palladium was utilized as an alloying element to improve interfacial adhesion. Comparative microstructural characterizations and property evaluations of the nanocomposites were performed. The structural characterizations revealed that decorated type-CNTs were dispersed, embedded, and anchored into the silver matrix. The experimental results indicated that the modification of the silver and silver–palladium nanocomposite with CNT resulted in increases in the hardness and Young＇s modulus along with concomitant decreases in the electrical conductivity and the coefficient of thermal expansion（CTE）. The hardness and Young＇s modulus of the nanocomposites were increased by 30%？40% whereas the CTE was decreased to 50%-60% of the CTE of silver. The significantly improved CTE and the mechanical properties of the CNT-reinforced silver and silver–palladium nanocomposites are correlated with the intriguing properties of CNTs and with good interfacial adhesion between the CNTs and silver as a result of the fabrication process and the contact action of palladium as an alloying element.     

Stability analysis of a class of digital filters utilizing single saturation nonlinearity

A novel criterion for the global asymptotic stability of a class of digital filters utilizing single saturation nonlinearity is presented. An example showing the effectiveness of the present criterion is given.     

Modified criterion for global asymptotic stability of fixed-point state-space digital filters using two’s complement arithmetic

A criterion for the global asymptotic stability of fixed-point state-space digital filters using two’s complement arithmetic is presented. The criterion is a modified form of a well-known criterion due to Mills, Mullis, and Roberts. The criterion is in the form of linear matrix inequality and, hence, computationally tractable. An example shows the effectiveness of the modified criterion.     

Securing communication using function extraction technology for malicious code behavior analysis

Since computer hardware and Internet is growing so fast today, security threats of malicious executable code are getting more serious. Basically, malicious executable codes are categorized into three kinds – virus, Trojan Horse, and worm. Current anti-virus products cannot detect all the malicious codes, especially for those unseen, polymorphism malicious executable codes. The newly developed virus will create the damages before it has been found and updated in database. The basic idea of the proposed system is, it will analyze the behavior of the malicious codes and based on the behavior signature of the malicious code content filtering mechanism will be used to filter out contents, so that, the system will be secured from the future communication processes. The behavior of the code is analyzed using the function extraction technology. The function extraction technology will replace the function codes into algebraic expressions. Based on the behavior of the malicious codes, it will be categorized into different kinds of malicious codes. The detected malicious code will be prevented from execution. Based on the type of malicious code, appropriate security mechanism will be used for further communication.     

Optimization of a plate-fin heat exchanger design through an improved multi-objective teaching-learning based optimization (MO-ITLBO) algorithm

Teaching-learning-based optimization (TLBO) is a recently developed heuristic algorithm based on the natural phenomenon of teaching-learning process. In the present work, multi-objective improved teaching-learning-based optimization (MO-ITLBO) algorithm is introduced and applied for the multi-objective optimization of plate-fin heat exchangers. The basic TLBO algorithm is improved to enhance its exploration and exploitation capacities by introducing the concept of number of teachers, adaptive teaching factor, tutorial training and self-motivated learning. The MO-ITLBO algorithm uses a grid-based approach to adaptively assess the non-dominated solutions maintained in an external archive. Minimizing total annual cost and the total weight of heat exchanger as well as minimization of total pressure drop and maximization of heat exchanger effectiveness for specific heat duty requirement are considered as objective functions. Two application examples are presented to demonstrate the effectiveness and accuracy of the proposed algorithm.     

Alkaline hydrolysis of the cyclic nitramine explosives RDX,HMX, and CL-20: new insights into degradation pathways obtained by the observation of novel intermediates

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX, I) and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) hydrolyze at pH > 10 to form end products including NO2-, HCHO, HCOOH, NH3, and N2O, but little information is available on intermediates, apart from the tentatively identified pentahydro-3,5-dinitro-1,3,5-triazacyclohex-1-ene (II). Despite suggestions that RDX and HMX contaminated groundwater could be economically treated via alkaline hydrolysis, the optimization of such a process requires more detailed knowledge of intermediates and degradation pathways. In this study, we hydrolyzed the monocyclic nitramines RDX, MNX (hexahydro-1-nitroso-3,5-dinitro-1,3,5-triazine), and HMX in aqueous solution (pH 10-12.3) and found that nitramine removal was accompanied by formation of 1 molar equiv of nitrite and the accumulation of the key ring cleavage product 4-nitro-2,4-diazabutanal (4-NDAB, O2NNHCH2NHCHO). Most of the remaining C and N content of RDX, MNX, and HMX was found in HCHO, N2O, HCOOH, and NH3. Consequently, we selected RDX as a model compound and hydrolyzed it in aqueous acetonitrile solutions (pH 12.3) in the presence and absence of hydroxypropyl-beta-cyclodextrin (HP-beta-CD) to explore other early intermediates in more detail. We observed a transient LC-MS peak with a [M-H] at 192 Da that was tentatively identified as 4,6-dinitro-2,4,6-triaza-hexanal (O2NNHCH2NNO2CH2NHCHO, III) considered as the hydrolyzed product of II. In addition, we detected another novel intermediate with a [M-H] at 148 Da that was tentatively identified as a hydrolyzed product of III, namely, 5-hydroxy-4-nitro-2,4-diaza-pentanal (HOCH2NNO2CH2NHCHO, IV). Both III and IV can act as precursors to 4-NDAB. In the case of the polycyclic nitramine 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20), denitration (two NO2-) also led to the formation of HCOOH, NH3, and N2O, but neither HCHO nor 4-NDAB were detected. The results provide strong evidence that initial denitration of cyclic nitramines in water is sufficient to cause ring cleavage followed by spontaneous decomposition to form the final products.     

PLA/functionalized‐gum arabic based bionanocomposite films for high gas barrier applications

The present work focuses on the microwave synthesis of lactic acid‐grafted‐gum arabic (LA‐g‐GA) by polycondensation reaction and its influence as an additive to improve the gas barrier properties of poly(lactic acid) (PLA) films, prepared by solution casting method. It is observed that during the synthesis of LA‐g‐GA, hydrophilic gum is converted into hydrophobic due to grafting of in situ grown hydrophobic oligo‐(lactic acid). Subsequently, PLA/LA‐g‐GA bionanocomposite films are fabricated and characterized for structural, thermal, mechanical and gas barrier properties. Path breaking reduction in oxygen permeability (OP) of ～10 folds is achieved in case of PLA films containing LA‐g‐GA as filler. However, water vapor transmission rate (WVTR) is reduced up to 27% after 5 wt % addition of filler. Reduction in OP of this order of magnitude enables the PLA to compete with PET in term of enhancing shelf life and maintaining the food quality. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43458.     

Green biomass active electronic diode

For the first time, a biomass electronic junction functioning as a conventional electronic diode inside green leaves of Vinka-rosa and Plumeria rubra mass structure has been experimentally predicted and studied. The experimental diode demonstrated appropriate conventional electronic diode characteristics. The predicted diode junctions were operated for forward and reverse dc voltage biases in the range of ±1 to 10 and 1 to 30?V respectively. The studies revealed a strong functional dependence on the water content of the green leaf. These studies are sequential to the very recently reported research work of Kosta et al. on bioelectronics and soilelectronics. The study speculatively forecasts the beginning of a new revolutionary era of green biomass electronic circuitry.     

Spatial-frequency-tuned mechanisms of the red-green channel estimated by oblique masking

The sustained spatial-frequency-tuned (SF-tuned) mechanisms of nonoriented units were examined by means of orthogonal masking for the Red-Green (R-G) color channel, and those of oriented units by oblique masking for the achromatic channel but not for the color channels. An oblique-masking technique minimizes the artifacts that are due to spatial phase effects, local cues, spatial beats, spatial probability summation, and changing criteria. Therefore the spatial characteristics of the R-G color channel are now investigated by an oblique-masking technique and linked with my paper on orthogonal masking [J. Opt. Soc. Am. A 15, 1 (1998)]. The R-G channel was defined by the minimum-flicker and hue-cancellation techniques. A color monitor system was used to generate spatially localized (D6) vertical color test patterns [0.063-8 cycles per degree (cpd)] and sinusoidal oblique color masks (0.031-16 cpd, 1.2-60% contrasts). Color contrast sensitivity functions (CSFs), threshold elevation (TE) versus mask SF (TvSF) curves, and TE versus mask contrast (TvC) curves were measured by the method of constant stimuli with a two-interval forced-choice technique by using Powell's achromatizing lens under sustained (Gaussian, 2-s-duration) conditions. Results show the following: (1) The color CSF is a low-pass function of SF with average half-height SF of 0.7 cpd and cutoff SF of 14 cpd with the use of a color-detection criterion. (2) TvSF curves are broadly bandpass and fall into five groups, peaking at approximately 0.13, 0.5, 2, 4, and 8 cpd. The root-mean-square cone-color CSF is 3.8-5.4 times the stimulus-color CSF. (3) A "crowding effect" similar to that of the TvSF curves of the achromatic channel was also found, but the TvSF curves of the R-G channel are not sharply peaked, similar to the result for orthogonal masking. Data analysis led to the following conclusions: (1) A simple multiple-mechanism model yields one low-pass color mechanism (with average half-height SF of 0.54 cpd) and five bandpass SF-tuned color mechanisms; these six mechanisms are necessary to explain the CSF, TvSF, and TvC data simultaneously. (2) The bandpass mechanisms peaked at approximately 0.13, 0.5, 2, 4, and 8 cpd with average full bandwidths at half-heights of 3.6, 3.2, 2.1, 1.2, and 1.3 octaves, respectively. (3) Since oblique-masking color mechanisms (unlike achromatic oriented mechanisms) have broad orientation tuning under sustained conditions and there is a significant orthogonal masking, the oblique-masking color mechanisms may have contributions from both oriented and nonoriented units. (4) The high degree of similarity between the SF-tuned filters of mechanisms derived from oblique- and orthogonal-masking data suggests that most of the chromatic SF tuning is already accomplished by nonoriented units. (5) The quality of the fit to oblique- and orthogonal-masking data combined dropped enough to reject the hypothesis that the former taps the performance of only the same nonoriented mechanisms as those by the latter. Adding gain parameters that reduce the TEs for orthogonal masking gave a better fit, suggesting that orientation gains are one of the factors involved in the transformation of information from nonoriented to oriented mechanisms. However, the fit was still worse than that for oblique-(6) Since masking-alone or orthogonal-masking-alone data, suggesting that more factors may be involved. primate parvo lateral geniculate nucleus (pLGN) units behave in a fairly linear manner, the color contrast nonlinearity (which follows the linear filter) of a mechanism may be post-pLGN.     

Color-luminance interaction: data produced by oblique cross masking

Threshold-elevation (TE-) versus-mask-spatial-frequency (SF) curves and TE-versus-mask-contrast curves, produced by the oblique-masking technique, were reported for uncrossed stimuli (color-test-on-color-mask and luminance-test-on-luminance-mask) [Invest. Ophthalmol. Visual Sci. Suppl. 34, 751 (1993) and Vision. Res. 23, 873 (1983)]. The technique minimizes the artifacts that are due to spatial phase effects, spatial beats, spatial probability summation, and local cues. My goal was to measure these curves for crossed stimuli (color-test-on-luminance-mask and luminance-test-on-color-mask) by this oblique-masking technique and to compare the curves with those reported in previous studies. For this purpose threshold contrasts were measured by a yes-no procedure with randomized double staircases. Test targets were vertical spatially localized (D6) patterns, and masks were oblique sinusoidal patterns; both the test and the mask were presented simultaneously, for 2 s (Gaussian window), on a color monitor interfaced with an ATVista system and a Powell achromatizing lens. The test SF's were 0.125, 0.5, 2, 4, and 8 cycles per degree (cpd); mask SF's were 0.031-16 cpd; and mask contrasts were 6.25%-50%. Furthermore, the Red-Green channel was defined by the minimum flicker and the hue cancellation techniques. Results show mostly masking effect (TE > 1) at contrasts above threshold; sometimes, separability (TE = 1) and above-threshold facilitation (TE < 1) effects were also observed, depending on the test SF, the mask SF, the mask contrast, and the subject. In general, the magnitudes of TE's are smaller and the TE-versus-mask-SF curves are slightly narrower for the oblique-cross-masking conditions than those for the respective oblique uncross masking. In addition, the TE-versus-mask-contrast curves for the crossed conditions are mostly shallower than those for the respective uncrossed conditions. Furthermore, mostly the color-luminance asymmetry (color masks luminance more than luminance masks color) is found, in mild form, for SF's > or = 0.5 cpd. For the lower SF of 0.125 cpd, there is either a lack of asymmetry or a very mild asymmetry of the opposite kind (luminance masks color slightly more than color masks luminance) seems to prevail. In general, the oblique-masking data shows mild asymmetry and reduced facilitation; both are consistent with reduced local cues, similar to those shown by randomized phase data, thus making the data suitable for SF analysis; moreover, at high contrast, the masking data are consistent with those reported in previous studies.