Novel Bi-Doped Amorphous SnOx Nanoshells for Efficient Electrochemical CO2 Reduction into Formate at Low Overpotentials

Engineering novel Sn-based bimetallic materials could provide intriguing catalytic properties to boost the electrochemical CO₂ reduction. Herein, the first synthesis of homogeneous Sn_1−xBi_x alloy nanoparticles (x up to 0.20) with native Bi-doped amorphous SnO_x shells for efficient CO₂ reduction is reported. The Bi-SnO_x nanoshells boost the production of formate with high Faradaic efficiencies (>90%) over a wide potential window (−0.67 to −0.92 V vs RHE) with low overpotentials, outperforming current tin oxide catalysts. The state-of-the-art Bi-SnO_x nanoshells derived from Sn_0.80Bi_0.20 alloy nanoparticles exhibit a great partial current density of 74.6 mA cm⁻² and high Faradaic efficiency of 95.8%. The detailed electrocatalytic analyses and corresponding density functional theory calculations simultaneously reveal that the incorporation of Bi atoms into Sn species facilitates formate production by suppressing the formation of H₂ and CO.     

Enhanced relative permittivity in niobium and europium co-doped TiO2 ceramics

The appearance of colossal permittivity materials broadened the choice of materials for energy-storage applications. In this work, colossal permittivity in ceramics of TiO₂ co-doped with niobium and europium ions ((Eu_0.5Nb_0.5)_xTi_1-xO₂ ceramics) was reported. A large permittivity (ε_r ～ 2.01?×?10⁵) and a low dielectric loss (tanδ ～ 0.095) were observed for (Eu_0.5Nb_0.5)_xTi_1-xO₂ (x?=?1%) ceramics at 1?kHz. Moreover, two significant relaxations were observed in the temperature dependence of dielectric properties for (Eu, Nb) co-doped TiO₂ ceramics, which originated from defect dipoles and electron hopping, respectively. The low dielectric loss and high relative permittivity were ascribed to the electron-pinned defect-dipoles and electrons hopping. The (Eu_0.5Nb_0.5)_xTi_1-xO₂ ceramic with great colossal permittivity is one of the most promising candidates for high-energy density storage applications.     

自动捕捉平衡系数试验电流工具设计

在电梯平衡系数传统测量方法中,存在电梯轿厢和对重平衡点难以判断、人为因素导致测量误差偏大、测量不准导致效率低等问题,为解决这些问题,设计出一款基于光电传感器和霍尔传感器的电流自动捕捉工具,除能够高效准确识别电梯轿厢和对重平衡点的位置外,还能通过无线信号传输处理,利用钳形电流表精确捕捉平衡点位置的电流值。经测试使用,该工具系统消除了在平衡系数测量过程中捕捉电流值的人为因素影响,并解决了无机房不能准确判断平衡点问题,有效的提高了检验工作的准确性和效率。     

浅谈“水源空调“在丹东市的推广使用

本文通过对“水源空调”的介绍,结合丹东市的地质情况,分析论证其在我市推广使用的可行性。     

刮板输送机接链用千斤拉的研究

针对刮板输送机的掐链、接链问题,研制出新型掐、接链用千斤拉,介绍了该装置的结构特点和工作原理,并对使用效果进行了分析。     

电气扰动引起的弯曲振动

分析了电气扰动引起机组弯曲振动的原因.认为电气扰动可以影响联轴器的同心度和转子的弯曲.本文还分析了这种振动的特点和处理措施.     

小型压裂技术的应用

在加砂压裂施工前进行小规模压裂，能使加砂压裂更加有效。通过对近两年来胜利油田应用小型压裂指导压裂设计的4口井实例的总结，说明了为确保加砂压裂施工的成功，尤其对端部脱砂压裂设计，小型压裂必不可少。同时介绍了Nolte方法和步骤，及小型压裂为加砂压裂设计提供的必要参数，讨论了参数解释的影响因素。为配合小型压裂工作，全面提高压裂技术水平，应选部分井进行岩石力学参数解释工作、适当延长压降测量时间，并测出瞬时停泵压力等。     

塔格糖制备方法研究进展

塔格糖是一种天然的低能量填充型甜味剂，并具有抑制高血糖、改善肠道菌群和不致龋齿等多种生理功效。目前主要通过生物和化学两种方法合成。