Imaging biofilm in porous media using X-ray computed microtomography

In this study, a new technique for three-dimensional imaging of biofilm within porous media using X-ray computed microtomography is presented. Due to the similarity in X-ray absorption coefficients for the porous media (plastic), biofilm and aqueous phase, an X-ray contrast agent is required to image biofilm within the experimental matrix using X-ray computed tomography. The presented technique utilizes a medical suspension of barium sulphate to differentiate between the aqueous phase and the biofilm. Potassium iodide is added to the suspension to aid in delineation between the biofilm and the experimental porous medium. The iodide readily diffuses into the biofilm while the barium sulphate suspension remains in the aqueous phase. This allows for effective differentiation of the three phases within the experimental systems utilized in this study. The behaviour of the two contrast agents, in particular of the barium sulphate, is addressed by comparing two-dimensional images of biofilm within a pore network obtained by (1) optical visualization and (2) X-ray absorption radiography. We show that the contrast mixture provides contrast between the biofilm, the aqueous-phase and the solid-phase (beads). The imaging method is then applied to two three-dimensional packed-bead columns within which biofilm was grown. Examples of reconstructed images are provided to illustrate the effectiveness of the method. Limitations and applications of the technique are discussed. A key benefit, associated with the presented method, is that it captures a substantial amount of information regarding the topology of the pore-scale transport processes. For example, the quantification of changes in porous media effective parameters, such as dispersion or permeability, induced by biofilm growth, is possible using specific upscaling techniques and numerical analysis. We emphasize that the results presented here serve as a first test of this novel approach; issues with accurate segmentation of the images, optimal concentrations of contrast agents and the potential need for use of synchrotron radiation sources need to be addressed before the method can be used for precise quantitative analysis of biofilm geometry in porous media.     

高合金化Al-Zn-Mg-Cu系7049A合金的连续冷却析出图

研究了所有有技术价值的冷却速率范围内7049A铝合金的析出行为。冷却速率从接近平衡冷却时的慢速条件变化到形成完全超饱和固溶体的高速率,跨越了7个数量级（0．0005到5000K／s）。7049A铝合金连续冷却析出行为采用差热分析（DSC）、扫描电镜（SEM）和维氏硬度测量相结合的方法记录。冷却速率在0．0005到4K／s时,对高合金化、高强度和高淬火敏感性的变形铝合金7049A从固溶温度下的淬火析出行为采用传统的DSC方法研究。在此冷却速率范围内,至少观察到了两个放热反应：一个是在很窄的温度区间430～450℃内的高温反应;另外一个是最低到200℃且范围很宽的低温反应。这两个反应的强度随着冷却速率的增高而降低。采用快速差热分析（DFSC）和差分再加热方法（DRM）对合金淬火冷却速率从慢速到数千K／s时的析出行为进行了研究。该合金不析出沉淀相时的临界淬火速率为100～300K／s。     

Asymptotic confidence intervals for variograms of stationary time series

Industrial processes are often monitored via data sampled at a high frequency and hence are likely to be autocorrelated time series that may or may not be stationary. To determine if a time series is stationary or not the standard approach is to check whether sample autocorrelation function fades out relatively quickly. An alternative and somewhat sounder approach is to use the variogram. In this article we review the basic properties of the variogram and then derive a general expression for asymptotic confidence intervals for variogram based on the Delta method. We illustrate the computations with an industrial process example. Copyright © 2009 John Wiley & Sons, Ltd.     

Microwave-assisted preparation and characterization of nanoscale rhenium diboride

A simple and efficient microwave-assisted preparation of ReB₂-based material is reported utilizing ammonium perrhenate (NH₄ReO₄), magnesium boride (MgB₁₂) reactants and carbon as an absorber of microwave irradiation. The investigation of microwave irradiated NH₄ReO₄ +MgB₁₂ +C mixtures, thermal analysis results and electron microscopy examination reveals that NH₄ReO₄ decomposition produces ReO₃ at early stages of the process. The ReO₃ then exothermically reacts with MgB₁₂ forming the nanoscale Re₃B phase, which converts into ReB₂ upon further irradiation. The coupling of microwave energy with exothermic reactions significantly accelerates the formation of ReB₂. The product primarily consists of ReB₂ as well as B₄C and minor carbon phases. Structural characterization reveals that the average particle size of ReB₂ is ~ 50?nm.     

A natural tomato slurry as a photosensitizer for dye-sensitized solar cells with TiO2/CuO composite thin films

We have studied the performance of dye-sensitized solar cells by employing natural dye “anthocyanins” extracted from the tomato slurry as a sensitizer for the TiO₂/CuO photoanode. The extracts were anchored on TiO₂/CuO films deposited on an ITO substrate which was used as a photoanode. The dye adsorbed TiO₂/CuO films electrode, the copper plate as a counter electrode, and iodolyte as an electrolyte were assembled into DSSCs. The conversion efficiency of the DSSCs was found to be 2.96% with a V_OC of 0.615 V, J_SC of 6.6 mA/cm², and an FF of 0.73. This work highlights the use of contribution of the tomato slurry as a natural sensitizer to enhance the efficiency of DSSCs.     

CU placement over a reconfigurable wireless fronthaul in 5G networks with functional splits

Mobile network operators are currently facing a tremendous increase in the level of data traffic. Although cell size reduction is one of the most common ways used to accommodate such traffic demand, densely deployed small cells also dramatically increase the level of intercell interference. By centralizing baseband signal processing at powerful computing infrastructures, called centralized unit (CU) pools, cloud radio access network (C‐RAN) enables advanced coordination algorithms to be employed in dense small cell networks. In C‐RAN, due to stringent bandwidth and latency requirements at the fronthaul links, the optical fiber, thanks to its bandwidth and latency characteristics, continues to be the most prevalent fronthaul medium option. Nevertheless, the optical fiber is one of the fronthaul options, while C‐RAN (physical layer radio frequency [PHY‐RF] split) is one of the functional splits that can be defined each coming with different fronthaul requirements. In this paper, we formulate and solve a dynamic CU placement problem for mobile networks as an integer linear programming (ILP) problem. In the considered network, CU pools are placed at the edges of the network, and a reconfigurable millimeter wave (MMW) wireless fronthaul links are used in order to provide decentralized units (DUs) with connectivity. We study the impact of different functional splits on the placement cost and on the acceptance ratio using different substrate networks. Lastly, we propose and evaluate a CU placement heuristic algorithm using a numerical simulator. The results reveal that the optimal functional split selection can lead to significant resource utilization benefits in the RAN.     

Synthesis of Heterocyclic Ylids as Candidates for Energetic Materials

Concise syntheses of nitrogen-rich pyridinium and 1,2,4-triazolium N-imides are reported. Substrate scope and various imide-stabilizing electron withdrawing groups are examined. Energetic properties of the target molecules were studied by heats of combustion.     

Submicrometer‐Sized ZIF‐71 Filled Organophilic Membranes for Improved Bioethanol Recovery: Mechanistic Insights by Monte Carlo Simulation and FTIR Spectroscopy

Template‐free self‐assembly synthesis of nano‐sized metal‐organic frameworks (MOFs) is of particular interest in MOF research since organized nanostructures possessing distinctive properties are useful for many advanced applications. In this work, the facile room temperature synthesis of robust submicrometer‐sized ZIF‐71 crystals with different particle sizes (140, 290, or 430 nm), having a high permanent microporosity (S_BET = 827 cm² g^?1) and synthesis yield up to 80% based on Zn on a gram‐scale, is reported. These small ZIF‐71 particles are ideal filler for the fabrication of thinner and homogeneous polydimethylsiloxane (PDMS) based mixed matrix membranes (MMMs) with excellent filler dispersion and filler‐polymer adhesion at high loading up to 40 wt%, as confirmed by scanning electron microscopy. Pervaporation tests using these submicrometer‐sized ZIF‐71 filled MMMs show significant improvement for bioethanol recovery. Interesting phenomena of i) reversible ethanol‐ethanol hydrogen interaction in the ethanol liquid‐phase and ii) irreversible hydrogen interaction of ethanol and –Cl functional group in the α‐cages and octagonal prismatic cages of ZIF‐71 in ethanol vapor‐phase are discovered for the first time by a Fourier transform infrared spectroscopy (FTIR) study. In full agreement with molecular simulation results, these explain fundamentally the ZIF‐71 filled MMMs pervaporation performance.