Grafting of poly(ethylene terephthalate) fibers with methacrylic acid using benzoyl peroxide

The graft copolymerization of methacrylic acid onto poly(ethylene terephthalate) fibers, by the aid of benzoyl peroxide, have been investigated. The graft yield increased up to 85°C, and then decreased with the further increase in temperature. The maximum graft yield was obtained at benzoyl peroxide concentration of 4.0 × 10^?3 mol/L. The increase in the concentration of monomer was found to increase the graft yield. The change in the graft yield was followed by the experiments carried out using different water/solvent mixtures. Also, the change in the properties of polye (thylene terephthalate) fibers grafted with methacrylic acid such as moisture regain, density, and diameter were investigated.     

Exergetic performance analysis of ohmic cooking process

This paper deals with the performance evaluation of ohmic cooking process by applying exergy analysis. Cylindrically shaped ground beef samples with different fat contents (2%, 9% and 15%) were used as the test material being cooked. The cooking process was conducted at three different voltage gradients (20, 30 or 40 V/cm) up to 80 °C. The effects of voltage gradient applied and the initial fat content of sample on the energy efficiency, exergy efficiency, exergy loss and improvement potential were investigated. The energy and exergy efficiency values for ohmic cooking process at the voltage gradients between 20 and 40 V/cm were found to be in the range of 0.69–0.91% and 63.2–89.2%, respectively. It was determined that the system should have been improved energetically especially for samples having high initial fat contents cooked at the low voltage gradients, since improvement potential values predicted were highest at this conditions.     

Artificial neural networks in their simplest forms for analysis and synthesis of RF/microwave planar transmission lines

In this work, the multiplayer perceptron (MLP) and radial basis function (RBF) neural networks in their simplest forms are employed in function approximation for highly nonlinear and complex analysis and synthesis of the most commonly used planar RF/microwave transmission lines, that is, microstrip lines, coupled microstrip lines, and basic and shielded coplanar‐waveguides. Since the analysis and synthesis processes for these systems have “one‐to‐one mapping” relations with each other, a forward model is defined for the analysis process for all these types of the planar transmission lines; on the other hand, a reverse model is also considered for the synthesis of the same lines. This reverse model is realized by swapping some of the inputs/outputs in the analysis model, and training the neural networks accordingly. Both MLP and RBF types of neural models are applied to the four widely used anisotropic and isotropic dielectric materials: PTFE/microstrip glass, RT/Duroid 6006, alumina and gallium arsenide. The results are shown to agree very well with the targets. A low‐pass filter with 30‐dB attenuation frequency at 3.5 GHz on an alumina substrate is designed by the use of a neural‐network synthesis and its resulting performance agrees well with the one using analytical formulas for the synthesis. © 2005 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2005.     

A review of gas engine driven heat pumps (GEHPs) for residential and industrial applications

This study reviews gas engine-driven heat pump (GEHP) systems for residential and industrial applications in terms of energetic and exergetic aspects for the first time to the best of the authors’ knowledge. These systems are novel heat pump systems (one of today's promising new technologies). Although the first investigations had been performed at late 1970s, the first merchandized GEHP was produced and introduced in the market in 1985. Gradually, it has become widespread all over the world for various purposes. Main application of GEHPs are for space and water heating/cooling purposes. However, they can be integrated to industrial applications, especially to drying processes.In this study, historical development of GEHP systems was briefly given first. Next, the operation of these systems was described, while studies conducted on them were reviewed and presented in tabulated forms. GEHPs were then modeled for performance evaluation purposes by using energy and exergy analysis methods. Finally, an illustrative example was given, while the results obtained were discussed. In addition, a new project on integration of GEHP systems to food drying processes in Turkey initiated by the authors was introduced. It is expected that this comprehensive study will be very beneficial to everyone involved or interested in the energetic and exergetic design, simulation, analysis and performance of assessment of GEHP systems.     

Poly(ether sulfonamide)s with glycidyl pendant units

SUMMARY High molecular weight poly (ether sulfonamide) has been prepared by condensation of 4,4'-dichlorosulfonyldiphenylether with ethylenediamine. The reaction of potassium salt of poly (ether sulfonamide) with epichlorohydrin gives the corresponding N-glycidiyl derivative in yield as high as 98%. The resulting polymer offers many functionalization possibilities through ring opening of the oxirane units. Also the glycidiyl bearing polymer may act as multifunctional post-crosslinking agent for polymers carrying hydroxy, amino or carboxyl groups. Received: 16 February 1998/Revised version: 4 May 1998/Accepted: 7 May 1998     

Electrical characterization of the boron trifluoride doped poly(3‐aminoacetophenone)/p‐Si junction

Electrical and interface state properties of the borontrifluoride doped poly(3‐aminoacetophenone)/p‐Si junction have been investigated by current‐voltage and impedance spectroscopy methods. Al/p‐Si/P₃APBF₃/Aldiode indicates a nonideal behavior with electrical parameters (n = 3.53, ?_B = 0.82 eV, and R_s = 1.48 kΩ), which result from the interfacial layer, series resistance, and resistance of the organic semiconductor. The obtained barrier height value of the Al/p‐Si/P₃APBF₃/Aldiode is higher than that of the conventional Al/p‐Si (?_B = 0.58 eV) Schottky diode. The interface state density of the diode was of the order of 1.05× 10¹² eV^?1 cm^?2. It is evaluated that the barrier height and interface state density values of the diode are modified using the boron trifluoride doped poly (3‐aminoacetophenone) organic semiconductor. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers     

Microstructure and densification of ZrB2–SiC composites prepared by spark plasma sintering

ZrB₂–SiC composites were prepared by spark plasma sintering (SPS) at temperatures of 1800–2100 °C for 180–300 s under a pressure of 20 MPa and at higher temperatures of above 2100 °C without a holding time under 10 MPa. Densification, microstructure and mechanical properties of ZrB₂–SiC composites were investigated. Fully dense ZrB₂–SiC composites containing 20–60 mass% SiC with a relative density of more than 99% were obtained at 2000 and 2100 °C for 180 s. Below 2120 °C, microstructures consisted of equiaxed ZrB₂ grains with a size of 2–5 μm and α-SiC grains with a size of 2–4 μm. Morphological change from equiaxed to elongated α-SiC grains was observed at higher temperatures. Vickers hardness of ZrB₂–SiC composites increased with increasing sintering temperature and SiC content up to 60 mass%, and ZrB₂–SiC composite containing 60 mass% SiC sintered at 2100 °C for 180 s had the highest value of 26.8 GPa. The highest fracture toughness was observed for ZrB₂–SiC composites containing 50 mass% SiC independent of sintering temperatures.