Diporphyrin tweezer for multichannel spectroscopic analysis of enantiomeric excess

Chiral 1,1’-binaphthyl-linked diporphyrin ‘tweezers’ (R)-1/(S)-1 and the corresponding zinc(II) complexes (R)-2/(S)-2 were prepared as chiral host molecules, and their utility for chiral analyses (especially enantiomeric excess (ee) determinations) were evaluated. Tris(1-n-dodecyl)porphyrins were used for the first time as the interacting units. Host capabilities of the diporphyrin tweezers were investigated by titrations with (R,R)- and (S,S)-cyclohexane-1,2-diamine (CHDA). The host molecules could be used as multichannel probes of ee by using UV-vis, circular dichroism (CD), fluorescence emission and ¹H nuclear magnetic resonance (¹H-NMR) methods. Chiral configurations could also be differentiated using CD or ¹H-NMR spectroscopy. All three optical techniques give good resolution of ee with reasonable sensitivity considering the low concentrations used (ca. 10⁻⁶ mol·L⁻¹). The ee determination of CHDA enantiomers using NMR spectroscopy is also possible because of the reasonably well separated resonances in the case of (R,R)- and (S,S)-CHDA. Non-metallated (R)-1/(S)-1 hosts could not be used to detect chiral information in a strongly acidic chiral guest. This work demonstrates the utility of 1,1’-binapthyl-linked chiral hosts for chiral analysis of ditopically interacting enantiomers.     

Covalent triazine framework with efficient photocatalytic activity in aqueous and solid media

Covalent triazine frameworks (CTFs) have been recently employed for visible light-driven photocatalysis due to their unique optical and electronic properties. However, the usually highly hydrophobic nature of CTFs, which originates from their overall aromatic backbone, leads to limitations of CTFs for applications in aqueous media. In this study, we aim to extend the range of the application media of CTFs and design hybrid material of a CTF and mesoporous silica (SBA-15) for efficient photocatalysis in aqueous medium. A thiophene-containing CTF was directly synthesized in mesopores of SBA-15. Due to the high surface area and the added hydrophilic properties by silica, the hybrid material demonstrated excellent adsorption of organic molecules in water. This leads not only to high photocatalytic performance of the hybrid material for the degradation of organic dyes in water, but also for efficient photocatalysis in solvent-free and solid state. Furthermore, the reusability, stability and easy recovery of the hybrid material offers promising metal-free heterogeneous photocatalyst for broader applications in different reaction media.     

Erratum to: Suspended superconducting weak links from aerosol-synthesized single-walled carbon nanotubes

Erratum to Nano Research 2020,13(12):3433-3438 https://doi.org/101007/s12274-020-3032-1 The article“Suspended superconducting weak links from aerosol-synthesized single-walled carbon nanotubes"written by Jukka-Pekka Kaikkonen1(■),Abhilash Thanniyil Sebastian3,Patrik Laiho3,Nan Wei3,Marco Will-2,Yongping Liao3,Esko I.Kauppinen3,and Pertti J.Hakonen1,2(■),was originally published Online First without Open Access.     

不锈钢塔器在硫酸装置中的应用

摘 要:主要介绍Sasol Agri公司硫酸四系统的技术改造,分两步进行,第一步更换转化器、热换热器及主省煤器,生产能力由1600t/d提高到1750 t/d,且鼓风机出口压力很低。第二步更换干燥塔、二吸塔及冷换热器,连续生产能力在1950 t/d以上。使用不锈钢材质及克瓦纳·凯密迪公司专有的换热器,使装置的改造相当成功,维护及操作费用较低,并具有较大的灵活性和可操作性。     

全面升级 2006上半年PC技术关键字解读

随着PC平台架构的转变,在2005年到2006年间出现了若干新技术,对PC平台的架构变革产生了深远的影响。随着这些技术被广泛地应用,用户在选购电脑产品时,了解一下这些新技术,显得尤其重要。为此,《电脑迷》杂志搜集了2006年上半年的一些技术关键字进行分析,希望对广大用户的选购有所帮助。     

论道英特尔无线通信发展策略——对话Kevin C.Kahn博士

2006年6月7日,以"创新科技,超越未来"为主题的"2006英特尔中国研究论坛"在北京召开.来自国内一流高校的600多位博士及硕士研究生,与英特尔公司的多位院士、高级科学家以及国内著名专家济济一堂,在浓郁的学术氛围中,共同交流IT业界前沿核心技术的研究进展.英特尔资深院士兼通信技术实验室总监Kevin Kahn博士展示了公司在无线通信领域的最新研发进展,包括英特尔在单一平台上支持更多无线通信数量所进行的技术和行业标准开发.     

硫酸厂主鼓风机的主要设计准则

论述现代硫酸厂主鼓风机设计时必须考虑的关键因素，通过实例讨论操作费用与投资之间的平衡关系以及对装置竞争力的影响。建议在硫酸厂严酷的操作条件下改进风机特性，提高耐磨性并采用维修友好的设计。     

抗衰老生物活性物ARGIRELINE

肉毒杆菌神经毒素(BoNTs)是一种非常有效的抗皱去皱生物活性物，它通常通过对人体的局部注射来实现其抗衰老性能，它的发明代表着化妆品的一次技术性革命，但由于它的剧毒性限制了其应用。所以有必要开发一种无毒、又有BoNTs功能的生物活性物，Lipotee、S.A公司开发的ARGIRELINE正符合了这种需求。ARGIRELINE是一种乙酰己肽物，通过志愿者人体实验，使用10％ARGIRELINE O／W乳液30天后，眼部皱纹减浅了30％，它的作用机理类似于BoNTs，即通过抑制钙依赖性接受体SNARE的形成，阻止神经递质素起作用，虽然ARGIRELINE不及BoNTs强，但实验证明，ARGIRELINE是一种无毒、无任何刺激性，甚至大剂量用量，且有很好的抗衰老效果，可以说，ARGIRELINE是BoNTs一种生物安全性的替代品。     

实时GPS定位中的自适应故障检测

给出了一种GPS卡尔曼滤波的自适应方案,该方案能根据GPS导航中变化的动态来估计协方差.当增强卡尔曼滤波器时,方案可得到更精确的定位修正.此外,也可将此估计方法用于完整监测,以增强故障检测的阈值选择.采用模拟数据验证了提出方法的正确性.     

澳大利亚蒂汶海奥利弗气田古油藏潜力定量评价

砂岩岩心和钻屑中的含油流体包裹体代表了隐蔽的石油显示。含有此类包裹体的石英颗粒的数目(GOI数)反映了砂岩储层中曾经历过最大的古含油饱和度，而与现今流体相无关。含油饱和度高的样品比含油饱和度低的样品的GOI数至少高一个数量级。因此，在原始油被后期填充气取代的井中，可根据这些流体包裹体的资料确定古油柱并划分原始油一水界面。此外，若能利用详细的GOI图精确确定原始油一水界面的位置，那么就可以确定古油柱的高度并估算原始石油地质储量。奥利弗(Oliver)油气田位于澳大利亚蒂汶海(Timor)，现在含有一个178．5m的油气柱，其中气柱高164m，位于14．5m油柱之上。该油气田已填充至溢出点。奥利弗-1井的GOI图显示，在现在的气柱内古油柱的总高度曾在99-132m之间，原始石油地质储量高达2亿bbl，明显高于现在4500万bbl的储量。高达1．55亿bbl的油从奥利弗构造转移到其上倾方向的倾斜断块，从而大大改善了该断块构造的勘探远景。GOI制图法是一种储层描述新方法。它能可靠探测现在被气充填的圈闭中的古油储。在新井钻探之前，利用这些资料可以定量描述气藏及其附近未测试构造的油藏潜力。