Copper-titanium diboride coatings obtained by plasma spraying reactive micropellets

Electrotribological applications require materials with both high electrical conductivity and wear resisance. For this purpose, a copper- base plasma sprayed coating containing titanium diboride particles was developed. The process for fabricating this CU- TiB₂ coating consists of plasma spraying reactive powders that contain a Cu- Ti alloy and boron. The reaction between the copper alloy and boron proceeds in different steps going from solid- state diffusion of titanium and copper to the synthesis of TiB₂ in a liquid below 1083 ‡C. Plasma sprayed copper coatings contain finer TiB₂ crystals than Cu- TiB₂ materials synthesized in a furnace at 1200 ‡C. Coatings with 25 vol% TiB2 have hardnesses that are comparable to Cu- Co- Be and Cu- Ni- Be alloys and to Cu- W and Cu- Mo alloys used in spot welding. Their low electrical resistivity of 52 ΜΩ cm could be increased by lowering the oxygen content with coatings and controlling the formation of TiB₂ clusters, the titanium content in solution in copper remaining low after the synthesis reaction.     

Abstraction of levels of abstraction

The notion of level of abstraction (LoA) is one of the foundations of the Floridi's Philosophy of Information. It also serves for many practical purposes as in information ethics. But the notion of abstraction is not new; it has been given many different meanings in various fields, especially in scientific disciplines and, in particular, in computer science. Our purpose here is to examine the use of abstraction in Floridi's works in conjunction with some of the meanings of abstraction in computer science. The article is divided into five sections. After a general introduction to the Floridi's method of abstraction (MoA) in Section 1, Section 2 revisits Floridi's definition of abstraction and Section 3 gives the different senses of abstraction in computer science. The Section 4 compares them with the Floridi's LoAs and proposes to generalise the Floridi's approach to abstraction using an abstraction of the LoAs, while Section 5 concludes on what we think to be some new arguments in favour of MoA and LoA.     

Computing the Duquenne–Guigues basis: an algorithm for choosing the order

This paper presents an algorithm for choosing the order in which pseudo-intents are enumerated when computing the Duquenne–Guigues basis of a formal context. Sets are constructed through the use of a spanning tree to ensure they are all found once. The time and space complexities of the algorithm are empirically evaluated using, respectively, the number of logical closures and the number of sets in memory as measures. It is found that only the space complexity depends on the enumeration order.     

The geometry of flex tangents to a cubic curve and its parameterizations

We show how the study of the geometry of the nine flex tangents to a cubic produces pseudo-parameterizations, including the ones given by Icart, Kammerer, Lercier, Renault and Farashahi, and infinitely many new ones.     

Performance Analysis and Modeling of Thermally Sprayed Resistive Heaters

Many processes and systems require hot surfaces. These are usually heated using electrical elements located in their vicinity. However, this solution is subject to intrinsic limitations associated with heating element geometry and physical location. Thermally spraying electrical elements directly on surfaces can overcome these limitations by tailoring the geometry of the heating element to the application. Moreover, the element heat transfer is maximized by minimizing the distance between the heater and the surface to be heated. This article is aimed at modeling and characterizing resistive heaters sprayed on metallic substrates. Heaters were fabricated by using a plasma-sprayed alumina dielectric insulator and a wire flame-sprayed iron-based alloy resistive element. Samples were energized and kept at a constant temperature of 425 °C for up to 4 months. SEM cross-sectional observations revealed the formation of cracks at very specific locations in the alumina layer after thermal use. Finite-element modeling shows that these cracks originate from high local thermal stresses and can be predicted according to the considered geometry. The simulation model was refined using experimental parameters obtained by several techniques such as emissivity and time-dependent temperature profile (infra-red camera), resistivity (four-probe technique), thermal diffusivity (laser flash method), and mechanical properties (micro and nanoindentation). The influence of the alumina thickness and the substrate material on crack formation was evaluated.     

Approximation of functions by perceptrons: a new approach

We provide a constructive proof of the theorem of function approximation by perceptrons (cf Leshno et al. [1], Hornik [2]) when the activation function ψ isC∞ with all its derivatives non 0 at 0. We deal with uniform approximation on compact sets of continuous functions on ℜ ^d ,d≥1. This approach is elementary and provides some approximation results for the derivatives along with some bounds for the hidden layer.     

Vertical distribution of fauna in the bed sediment of three running water sites: Influence of physical and trophic factors

Relationships between invertebrates, substrate characteristics and trophic factors were investigated, with special emphasis on the hyporheic habitat, in order to characterize the functioning of different running waters ecosystems. Three contrasting study sites were chosen in catchments exhibiting different features: (1) a meandering reach of the Loire River in its alluvial floodplain, upstream of the ‘Bec d'Allier’; (2) a reach of the Galaure with a fairly developed riparian corridor, a small sinuous foothill river; and (3) a braided reach of the Drac, an alpine torrential stream. Each site was sampled once using the freezing-core technique with previous electro-positioning of the invertebrates. In each site, four 60 cm cores were extracted, each one from different morphodynamic units. In the Loire and Galaure rivers, most invertebrates are found in the first 15 cm of the sediment, with the exception of some particular taxa or morphodynamic units (riffle head). Conversely, in the Drac lotic units, maximum density of invertebrates occurs between 15 and 30 cm and more than 75 per cent of all organisms are found at a depth > 15 cm. The vertical distribution of organisms does not follow a uniform pattern in different streams. In the substrate, the vertical distribution of macroinvertebrates is very closely related to porosity in contrast with trophic parameters that always decrease with depth. The porosity is negatively correlated with the percentage of sand in the sediment and seems to be important in determining the vertical distribution of fauna, and should be integrated in a functional typology of running waters. The trophic parameters and the structure of invertebrate community with its dominant feeding groups allow discrimination of the different sites.     

Life cycle assessment of using powder and liquid precursors in plasma spraying: The case of yttria-stabilized zirconia

Plasma spraying using liquid precursors makes possible the production of finely-structured coatings and thin coatings. This technology has been investigated for nearly ten years in many laboratories and applications are now emerging, using conventional plasma equipment except for the feedstock injection system. While superior quality is expected from the nano-structured coatings, the question remains as to the impacts of using liquid precursors on the environment. In this study, we used the life cycle assessment (LCA) methodology to compare the conventional plasma spray process using powder feedstock, with injection of the precursor in the form of a liquid solution or suspension. The LCA methodology consists of identifying and comparing the environmental impacts of feedstock, energy inputs, products and emissions (solid, liquid and gaseous) of these two alternatives. The LCA study was carried out using the SimaPro program developed in the Netherlands and a peer-reviewed database of upstream materials and energy (EcoInvent v.2). The specific application studied was the plasma spraying of yttria-stabilized zirconia.     

Engineering HVOF-Sprayed Cr3C2-NiCr Coatings: The Effect of Particle Morphology and Spraying Parameters on the Microstructure, Properties, and High Temperature Wear Performance

Chromium carbide-based thermally sprayed coatings are widely used for high temperature wear applications (typical temperature range from 540 to 900 °C). In these extreme environments at those temperatures, several phenomena will degrade, oxidize, and change the microstructure of the coatings, thereby affecting their wear behavior. Although it can be easily conceived that the Cr₃C₂-NiCr coating microstructure evolution after high temperature exposure will depend on the as-sprayed microstructure and spraying parameters, very little has been done in this regard. This study intends to develop a better understanding of the effect of spraying parameters on the resulting chromium carbide coating microstructure after high temperature operation and high temperature sliding wear properties. The microstructures of different coatings produced from two morphologies of Cr₃C₂-NiCr powders and under a window of in-flight particle temperature and velocity values were characterized through x-ray diffraction and scanning electron microscopy. Sliding wear at 800 °C was performed and the wear behavior correlated with the spraying parameters and coating microstructure. Vickers microhardness (300 gf) of the coatings before and after sliding wear was also measured.     

Gas-Substrate Heat Exchange During Cold-Gas Dynamic Spraying

In this study, the temperature distribution of the surfaces of several substrates under an impinging gas jet from a cold spray nozzle was determined. A low-pressure cold-gas dynamic spraying unit was used to generate a jet of hot compressed nitrogen that impinged upon flat substrates. Computer codes based on a finite differences method were used to solve a simplified 2D temperature distribution equation for the substrate to produce nondimensional relationships between the surface temperature and the radius of the impinging fluid jet, the axial velocity of the cold spray nozzle, the substrate thickness, and the heating time. It was found that a single profile of the transient nondimensional maximum surface temperature could be used to estimate the dimensional maximum surface temperature, regardless of the value of the compressed gas temperature. It was found further that, as the thermal conductance of the substrate increased, the maximum surface temperature of the substrate beneath the gas jet decreased. Heat exchange between the substrate and the compressed gas jet during motion of the nozzle to produce heat conduction within the substrate was characterized by the nondimensional Peclét number. It was found that lower Peclét numbers produced higher temperatures within the substrate. The close agreement of the numerical results with the experimental results suggests that the nondimensionalized results may be applied to a wide range of conditions and materials.