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1.
M. Kangas J. Villegas N. Kumar T. Salmi D.Yu. Murzin F. Sandelin E. Harlin 《Catalysis Today》2005,100(3-4):363-366
An investigation of the effect of reaction conditions on product distribution in the skeletal isomerisation reaction of linear butenes has been carried out. The main reaction routes over ferrierite have been identified. Beside the main product isobutene, major by-product formation occurs. The unwanted reactions include dimerisation of butene to form octenes, hydrogen transfer yielding small amounts of saturated C3 and C4 hydrocarbons and disproportionation producing propene and pentenes. The most abundant by-products were pentene and propene, though these were not formed in equimolar amounts as could be expected. Oligomerisation experiments of propene over ferrierite produced large amounts of butene and pentene, revealing the presence of adsorbed nonene. The cracking of this surface species to hexene and propene is the most likely reaction route for the excess propene formation. This additional path to propene formation operates mainly at temperatures above 623 K. 相似文献
2.
Kayo Suzuki Author Vitae Author Vitae Hiroaki Ikeda Author Vitae Author Vitae Fumio Adachi Author Vitae 《Computers & Electrical Engineering》2008,34(1):21-37
This paper focuses on a practical design for an efficient scalable image database and retrieval system over broadband networks. It describes a concrete solution for the implementation of HD/SHD (high-definition/super-high-definition) still image retrieval services which can be used in different applications. The structure of the complete system, consisting of a directory server, an image server, and MMI (man-machine interface) devices, has been presented, detailing each element and their corresponding functions. The desired HD/SHD image is displayed on the HD-PDP (plasma display panel) with the aid of image matching. The proposed system generates image index automatically, eliminating special skills in preparing index images and crucially reducing the processing time (from 35 min to 110 s), and does not use keywords. It has been also shown that these indices can be used for quite accurate image retrieval, i.e., the system provides high precision rates (currently up to 98%) to the user, eliminating troubles encountered in the image retrieval operations due to limitation on the user’s age, culture, knowledge, and languages.The broadband IP networks currently have a number of issues from the viewpoint of practical system operations, and so the requirements and issues needed for the networks are discussed from the viewpoint of in-service performance, differentiation among different types of services, secure connections, and so on, focusing on handling of HD/SHD still images. 相似文献
3.
4.
Periodic flooding alters riverine vegetation community composition; moderate flood disturbance maintains communities at an early seral stage, whereas severe floods may remove entire communities. After disturbance, plants may recolonize riverbeds from refugia.Here, we investigated the morphological characteristics of refugia where riverine plants survived large floods. At three sites, plant communities growing on cobble-bars were surveyed, and the hydraulic characteristics of each site were analyzed. The populations of an indicator plant, Anaphalis margaritacea sub-species yedoensis (Franch. et Savat.) were assessed after major floods in 2004 and 2009. At each survey, the particle size and bed composition were measured, and the critical shear-stress required to move particles at each site was calculated. A one-dimensional flow and the average and local shear-stress at ten different discharges, including that of the largest flood were calculated. The results demonstrate that the A. margaritacea community is maintained at locations where the local shear-stress at peak discharge in large-floods does not exceed a critical value. These conditions were achieved in locations with particular morphological characteristics, where the river is not constrained by levees and is restricted by a downstream narrow-pass; in this reach river width increases with discharge thus limiting the increase in water depth with increasing discharge and allowing the establishment of refugia where plant species may survive large floods.Flooding and reestablishment from refugia maintain a characteristic riverbed community in equilibrium. 相似文献
5.
Xiaoyi Wang Scott Kangas Divyachapan Padur Lei Liu James A. Swanson Arthur J. Helmicki Victor J. Hunt 《Canadian Metallurgical Quarterly》2005,10(4):460-467
Condition assessment is a term that is used to describe the process of characterizing the physical condition of constructed systems. This paper summarizes a condition assessment (CA) procedure based on a complete system of field-testing, finite element (FE) modeling, and load rating. Experimental techniques, including both modal testing and truckload testing, are used to collect measurements of the constructed systems. The basic mechanism and procedure of the FE modeling and calibration are presented. Different physical parameters of FE models are adjusted during the calibration process using both static and dynamic responses as criteria to achieve convergence between experimental measurements and analytical results using carefully developed objective functions. Finally, a bridge load rating is completed on the basis of the calibrated model. These developments are described and illustrated using a representative bridge as an example. 相似文献
6.
Dr. Johann Dion Fumi Minoshima Sayoko Saito Kayo Kiyoi Kayo Hasehira Dr. Hiroaki Tateno 《Chembiochem : a European journal of chemical biology》2019,20(12):1606-1611
Human pluripotent stem cells (hPSCs) are attractive resources for regenerative medicine, but medical applications are hindered by their tumorigenic potential. Previously, a hPSC-specific lectin probe, rBC2LCN, was identified through comprehensive glycome analysis by using high-density lectin microarrays. Herein, a lectin–doxorubicin (DOX) prodrug conjugate, with controllable photolysis activation for the elimination of tumorigenic human induced pluripotent stem cells, has been developed. rBC2LCN was fused with a biotin-binding protein, tamavidin (BC2Tama), and the fusion protein was expressed in Escherichia coli and purified by means of affinity chromatography. BC2Tama was then conjugated with doxorubicin-photocleavable biotin (DOXPCB). The BC2Tama–DOXPCB conjugates were observed to bind to hPSCs followed by internalization. Upon exposure to ultraviolet light, DOX was released inside the cells, which allowed specific killing of the hPSCs. Thus, BC2Tama–DOXPCB should be useful for the targeted elimination of hPSCs contained in hPSC-derived cell therapy products. This is the first report of the generation of lectin–prodrug conjugates. BC2Tama should be applicable for the targeted delivery of various types of biotinylated compounds into hPSCs. 相似文献
7.
Characterization of alternative plasticizers in poly(vinyl chloride) sheets for blood containers 下载免费PDF全文
Yuji Haishima Tsuyoshi Kawakami Chie Fukui Akito Tanoue Toshiyasu Yuba Satoru Ozono Hidehumi Kumada Kaoru Inoue Tomomi Morikawa Miwa Takahashi Ayano Fujisawa Kayo Yamasaki Yusuke Nomura Kazuo Isama Ung‐il Chung Kumiko Ogawa Shingo Niimi Midori Yoshida 《乙烯基与添加剂工艺杂志》2016,22(4):520-528
This study aimed to optimize the ratio of dioctyl 4‐cyclohexene‐1,2‐dicarboxylate (DOTH) and di‐isononyl‐cyclohexane‐1,2‐dicarboxylate (DINCH®) for use as plasticizers in poly(vinyl chloride) (PVC) sheets. We also evaluated the biological safety of DOTH for its potential to be part of a safe PVC‐based blood container. The suppression of hemolysis in mannitol‐adenine‐phosphate / red cell concentrates (MAP/RCC) with DOTH/(DINCH®‐PVC) sheets and the elution of plasticizers from the sheets increased with higher DOTH compositions. The properties of the PVC sheet containing DOTH and DINCH® in the ratio of 25:33 parts against PVC 100 parts as a weight were almost identical to the PVC sheet made of di(2‐ethylhexyl) phthalate. From a subchronic toxicity test, DOTH did not show any adverse effects on all organs, including the testes, epididymis, liver, and kidneys. The no‐observed‐adverse‐effect level was 300 mg/kg body weight/day in a rat. These results suggest that DOTH/DINCH® (25:33) is a promising candidate for the replacement of di(2‐ethylhexyl) phthalate in blood containers. J. VINYL ADDIT. TECHNOL., 22:520–528, 2016. © 2015 Society of Plastics Engineers 相似文献
8.
Amr Ahmed Andrew Arnold Luis Pedro Coelho Joshua Kangas Abdul-Saboor Sheikh Eric Xing William Cohen Robert F. Murphy 《Journal of Web Semantics》2010,8(2-3):151-154
The SLIF project combines text-mining and image processing to extract structured information from biomedical literature.SLIF extracts images and their captions from published papers. The captions are automatically parsed for relevant biological entities (protein and cell type names), while the images are classified according to their type (e.g., micrograph or gel). Fluorescence microscopy images are further processed and classified according to the depicted subcellular localization.The results of this process can be queried online using either a user-friendly web-interface or an XML-based web-service. As an alternative to the targeted query paradigm, SLIF also supports browsing the collection based on latent topic models which are derived from both the annotated text and the image data.The SLIF web application, as well as labeled datasets used for training system components, is publicly available at http://slif.cbi.cmu.edu. 相似文献
9.
A net energy analysis of district solar heating using seasonal heat storage has been performed. The use of seasonal heat storage is of great importance in northern latitudes when the solar contribution is to be increased. Different system alternatives were considered. Net energy ratios for the most favourable options were found to be between 3 and 5. 相似文献
10.
Supramolecular Ligands for Histone Tails by Employing a Multivalent Display of Trisulfonated Calix[4]arenes 下载免费PDF全文
Dr. Yasuaki Kimura Nae Saito Kayo Hanada Jiaan Liu Prof. Takayoshi Okabe Dr. Shigehiro A. Kawashima Dr. Kenzo Yamatsugu Prof. Motomu Kanai 《Chembiochem : a European journal of chemical biology》2015,16(18):2599-2604
Post‐translational modification of histone tails plays critical roles in gene regulation. Thus, molecules recognizing histone tails and controlling their epigenetic modification are desirable as biochemical tools to elucidate regulatory mechanisms. There are, however, only a few synthetic ligands that bind to histone tails with substantial affinity. We report CA2 and CA3, which exhibited sub‐micromolar affinity to histone tails (especially tails with a trimethylated lysine). Multivalent display of trisulfonated calix[4]arene was important for strong binding. CA2 was applicable not only to synthetic tail peptides but also to endogenous histone proteins, and was successfully used to pull‐down endogenous histones from nuclear extract. These findings indicate the utility of these supramolecular ligands as biochemical tools for studying chromatin regulator protein and as a targeting motif in ligand‐directed catalysis to control epigenetic modifications. 相似文献