Effects of the Addition of Different Types of Fillers on the Properties of BaO–ZnO–B2O3–SiO2 Glass Composites for Application to Barrier Ribs of Plasma Display Panels

Various types of crystalline ceramic fillers (TiO₂, ZrO₂, Al₂O₃, MgO, and cordierite) were added to BaO–ZnO–B₂O₃–SiO₂ (BZBS) glass (5–20 wt%), and the resultant dielectric constant, coefficient of thermal expansion (CTE), and optical reflectance were investigated for the application of the composites to the barrier ribs in plasma display panels. All the investigated fillers were partially dissolved into the glass at the fabrication temperature (575°C), and the residual fillers were aligned along the boundaries of sintered glass frits. By considering all aspects of the properties, the addition of TiO₂ fillers of about 10 wt% to BZBS glass was the most desirable of the types of fillers investigated. The addition of TiO₂ filler (10 wt%) yielded 61% in optical reflectance, 8.3 × 10⁻⁶ K^–1 in coefficient of thermal expansion, and 15.5 in dielectric constant, which were properties comparable with the currently used Pb-based barrier ribs.     

A new graph cut-based multiple active contour algorithm without initial contours and seed points

This paper presents a new graph cut-based multiple active contour algorithm to detect optimal boundaries and regions in images without initial contours and seed points. The task of multiple active contours is framed as a partitioning problem by assuming that image data are generated from a finite mixture model with unknown number of components. Then, the partitioning problem is solved within a divisive graph cut framework where multi-way minimum cuts for multiple contours are efficiently computed in a top-down way through a swap move of binary labels. A split move is integrated into the swap move within that framework to estimate the model parameters associated with regions without the use of initial contours and seed points. The number of regions is also estimated as a part of the algorithm. Experimental results of boundary and region detection of natural images are presented and analyzed with precision and recall measures to demonstrate the effectiveness of the proposed algorithm.     

Thermal and dielectric properties of ZnO-B2O3-MO3glasses (M = W, Mo)

Glasses in the ZnO-B₂O₃-MO₃(M = W, Mo) ternary were examined as potential replacements to PbO-B₂O₃-SiO₂-ZnO glass frits with the low firing temperature (500–600^∘C) for the dielectric layer of a plasma display panels (PDPs). Glasses were melted in air at 950–1150^∘C in a narrow region of the ternary using standard reagent grade materials. The glasses were evaluated for glass transition temperature (T _g ), softening temperature (T _d ), the coefficient of thermal expansion (CTE), dielectric constant (ε _r ), and optical property. The glass transition temperature of the glasses varied between 470 and 560^∘C. The coefficient of thermal expansion and the dielectric constant of the glasses were in the range of 5–8 × 10^{− 6}/^∘C and 8–10, respectively. The addition of MO₃to ZnO-B₂O₃binary could induce the expansion of glass forming region, the reduction of T _g and the increase in the CTE and the dielectric constant of the glasses. Also, the effect of the addition of MO₃to ZnO-B₂O₃binary on the transmittance in the visible-light region (350–700 nm) was investigated.     

Fabrication of an electrolyte-supported protonic ceramic fuel cell with nano-sized powders of Ni-composite anode

Composite anodes of nano-sized Ni and Ba(Zr_0.85Y_0.15)O_3-δ (BZY) were fabricated by infiltrating a single precursor solution of BZY and Ni into the BZY scaffold, and decreasing the calcination temperature to 1173 K. This decrease in the fabrication temperature of the Ni-cermet anode prevents the chemical reaction between the electrolyte and nickel, thus preventing a reduction in the conductivity of the electrolyte. By optimizing the amount of Ni in the Ni-cermet and infiltrating additional catalysts such as CeO₂ and Pd, the non-ohmic ASR of the Ni-cermet anode could be optimized. This resulted in a smaller non-ohmic ASR of anode than one that was fabricated by the conventional co-sintering method. Consequently, a high power density of 790 mW/cm² at 973 K can be obtained from electrolyte-supported cells.     

Limit loads and approximate J estimates for axial through-wall cracked pipe bends

This paper presents plastic limit loads and approximate J estimates for axial through-wall cracked pipe bends under internal pressure and in-plane bending. These loads and estimates are based on small strain finite element limit analyses using elastic-perfectly plastic materials. Geometric variables associated with the crack and pipe bend are systematically varied, and three possible crack locations (intrados, crown and extrados) are considered. Effects of the bend and crack geometries on plastic limit loads are quantified, and closed-form limit load solutions are given. Based on the proposed limit load solutions, a reference stress based the J estimation scheme for axial through-wall cracked pipe bends under internal pressure and in-plane bending is proposed.     

Net-section limit moments and approximate J estimates for circumferential cracks at the interface between elbows and pipes

This paper firstly presents net-section limit moments for circumferential through-wall and part-through surface cracks at the interface between elbows and attached straight pipes under in-plane bending. Closed-form solutions are proposed based on fitting results from small strain FE limit analyses using elastic–perfectly plastic materials. Net-section limit moments for circumferential cracks at the interface between elbows and attached straight pipes are found to be close to those for cracks in the centre of elbows, implying that the location of the circumferential crack within an elbow has a minimal effect on the net-section limit moment. Accordingly it is also found that the assumption that the crack locates in a straight pipe could significantly overestimate the net-section limit load (and thus maximum load-carrying capacity) of the cracked component. Based on the proposed net-section limit moment, a method to estimate elastic–plastic J based on the reference stress approach is proposed for circumferential cracks at the interface between elbows and attached straight pipes under in-plane bending.     

New statistical software for the proportional hazards model with current status data

Currently, there are some statistical software packages such as intcox, survBayes, and BITE that are designed to analyze current status data (in which failure times are known to be either left- or right-censored) based on the proportional hazards model. They, however, either fail to directly provide standard errors for the estimated regression parameters or require frailty terms. As a result, practitioners often analyze their data using packages for right-censored data. By so doing, they mistreat left-censored observations as exact. This paper describes our newly developed statistical software for the proportional hazards model with current status data. The software is implemented in the R and C languages and consists of the following two simple steps: (a) find MLEs of the regression parameter and the cumulative hazard function; (b) compute the variance-covariance matrix of the regression parameter estimator by using the generalized missing information principle (GMIP) developed by Kim [Kim, J.S., 2003b. Efficient estimation for the proportional hazards model with left-truncated and Case 1 interval-censored data. Statista Sinica 13 (2), 519-537]. Our simulation study results show that our method works well in terms of bias, standard error, and power. By treating current status data as right-censored data, we also show the discrepancy in terms of bias, standard error, and power. Real examples are provided to illustrate the use of the software. This method can be extended to both general interval-censored data and truncated and interval-censored data.     

Improvement of Ni-Cermet performance of protonic ceramic fuel cells by catalyst

Generally, the NiO composite anode becomes porous after reduction. To infiltrate additional catalysts such as Pd into the NiO-composite anode before reducing NiO to Ni, a porous NiO composite anode for protonic ceramic fuel cells (PCFCs) was fabricated in this study. The porous NiO composite was fabricated by adding graphite as a pore former along with CuO as a sintering agent. The addition of graphite increased the porosity of the NiO composite anode but resulted in poor sinterability, which was addressed by adding CuO as a sintering agent to the NiO composite anode. The Pd catalyst was added to the NiO-composite anode before reducing NiO to Ni. The composite anode for PCFC with three components, namely Ni, protonic ceramics, and a Pd catalyst, was obtained by reducing NiO to Ni during the measurement. The addition of the Pd catalyst improved the anode performance in methane fuel and hydrogen fuel by enhancing the catalytic activity for the electrochemical reaction on the surface.     

Effects of Bi2O3 and Na2O on the Thermal and Dielectric Properties of Zinc Borosilicate Glass for Plasma Display Panels

An approach to select appropriate network modifiers to tailor the thermal and dielectric properties of zinc borosilicate (ZBS) glass has been explored to apply the glass composition to a dielectric layer of plasma display panels. Based on ionic field strength of the modifiers and the ionic polarizability of the corresponding crystalline form, Bi₂O₃ and Na₂O modifiers have been selected to modify the thermal and dielectric properties of the glass toward the required properties for the application (440< T _g<460°C, 7.5 × 10⁻⁶−6/K, and 10< K <15). Bi₂O₃ addition to ZBS could meet all the required properties simultaneously at a given addition range (8.5–14 mol%), while the addition of Na₂O could not meet all the properties at a single composition range.     

Elastic-plastic fracture mechanics analyses of circumferential through-wall cracks between elbows and pipes

The present work proposes a method for elastic-plastic fracture mechanics analysis of the circumferential through-wall crack in weldment joining elbows and attached straight pipes, subject to in-plane bending. Heterogeneous nature of weldment is not explicitly considered and thus, the proposed method assumes cracks in homogeneous materials. Based on small strain finite element limit analyses using elastic-perfectly plastic materials, closed-form limit loads for circumferential through-wall cracks between elbows and straight pipes under bending are given. Then applicability of the reference stress-based method to approximately estimate J and crack opening displacement (COD) is evaluated. It was found that the limit moments for circumferential cracks between elbows and attached straight pipes can be much lower than those for cracks in straight pipes, particularly for a crack length of less than 30% of the circumference; this result is of great interest in practical cases. This result implies that, if one assumes that the crack locates in the straight pipe, limit moments could be overestimated significantly, and accordingly, reference stress-based J and COD could be significantly overestimated. For the leak-before-break analysis, accurate J and COD estimation equations based on the reference stress approach are proposed.