Role of Pits in Corrosion Fatigue of Offshore Structural Steel

From the corrosion fatigue test under intermit-tent wetting condition for offshore structural steelof A537 cl.l and data analysis,some results associ-ated with the role of pits in fatigue process havebeen discussed.     

Employee stress and health complaints in jobs with and without electronic performance monitoring

Current applications of electronic performance monitoring based on job design theories that consider worker performance rather than stress issues are likely to generate unsatisfying and stressful jobs (Smith et al, 1986). This study examines critical job design elements that could influence worker stress responses in an electronic monitoring context. A questionnaire survey of employees in telecommunications companies representative of each region in the United States examined job stress in directory assistance, service representative and clerical jobs with specific emphasis on the influence of electronic monitoring of job performance, satisfaction and employee health. Useable surveys were received from 745 employees representing seven operating companies and AT & T; a response rate of about 25%. The results of this survey indicated that employees who had their performance electronically monitored perceived their working conditions as more stressful, and reported higher levels of job boredom, psychological tension, anxiety, depression, anger, health complaints and fatigue. It is postulated that these effects may be related to changes in job design due to electronic performance monitoring.     

Supercritical fluid extraction and characterization of lipids from algae Scenedesmus obliquus

Supercritical carbon dioxide (SC-CO2) extractions (with and without ethanol as an entrainer) were carried out to remove lipids and pigments from protein concentrate of green algae (Scenedesmus obliquus) cultivated under controlled conditions. The content and fatty acid composition of algal lipids using column, thin-layer (TLC) and gas-liquid chromatography (GLC) were determined. Absorption spectra of extracted fractions showed the predominance of chlorophyll A (lambda max at 410 nm). Single step supercritical carbon dioxide (SC-CO2) extraction resulted mostly in removal of neutral lipids and a part of glycolipids, but phospholipids were not extracted. Addition of ethanol to SC-CO2 increased the amount of glycolipids and phospholipids in the extract. TLC pattern of algal lipids showed that the main part of neutral lipids consisted of diglycerides, triglycerides, hydrocarbons, free sterols, and sterol esters. The glycolipids were mostly monogalactosyl diglyceride, digalactosyl diglyceride, esterified sterol glycoside, and sterol glycoside. In phospholipids, phosphatidyl choline, phosphatidyl glycerol, and phosphatidyl ethanolamine were the main compounds. Fatty acid composition patterns indicated the main fatty acids to be 16:0, 16:1, 16:2, 16:3, 16:4, 18:1, 18:2, and 18:3(a). Relatively high recovery of polyunsaturated fatty acids and essential fatty acids in supercritical fluid extracted algal lipids and proteins isolates were observed.     

EFFECT OF NaOH CONCENTRATION AND AlO_2~- SPECIES ON CAUSTIC STRESS CORROSION CRACKING OF A LOW ALLOY STEEL AT 260℃

用慢应变速率法（ＳＳＲＴ）、动电位扫描和循环伏安法研究１６ＭｎＲ钢在氧化铝溶出过程中的高温碱脆行为。结果表明，在２６０℃，１６ＭｎＲ钢的碱脆敏感性随ＮａＯＨ浓度（７．４２－１０．０６ｍｏｌ／Ｌ）的升高而增大；当碱液中含有ＡｌＯ２＾－离子时，１６ＭｎＲ钢的碱脆敏感电位区缩小，样品表面腐蚀产物保护性好，ＡｌＯ２＾－离子对低合金钢高温碱脆有一定抑制作用；１６ＭｎＲ钢在２６０℃碱液中生成的腐蚀产物为Ｆｅ３     

酚醛改性环氧粉末复合涂层耐介质渗透性能的研究

本文利用静态浸泡法，测定了熔融结合环氧与酚醛改性环氧粉末自由涂膜在90℃几种典型介质中的增重率-时间关系曲线。用示差扫描量热仪测量了两种涂料固化过程中的反应热特性曲线，从涂层组分和交联结构特性上，探讨酚醛改性环氧粉末涂料的抗介质渗透性能。结果表明：加入适当的酚醛树脂可改善环氧粉末涂料在90℃的耐水及耐酸性，耐碱性也在一定程度上有所提高。     

蛋白质在超滤过程中的膜污染和膜清洗

本文选用四种不同的膜清洗剂对牛血清蛋白溶液超滤后污染的三种超滤膜进行研究，结果表明：在蛋白质的等电点取得在不同ＰＨ值下蛋白质对膜污染的最佳清洗效果，清洗效率与蛋白质的所荷电荷有关。采用适宜的清洗过程将会延长膜使用寿命和增强超滤膜性能。