CO2 Hydrogenation over Ru-NPs Supported Amine-Functionalized SBA-15 Catalyst: Structure–Reactivity Relationship Study

Catalysis Letters - We gave an effective protocol to support Ru NPs on amine-functionalized SBA-15 mesoporous silica to catalyze the CO2 hydrogenation reaction. The amine groups present in the...     

ResearchGate and Google Scholar: how much do they differ in publications,citations and different metrics and why?

ResearchGate has emerged as a popular professional network for scientists and researchers in a very short span. Similar to Google Scholar, the ResearchGate indexing uses an automatic crawling algorithm that extracts bibliographic data, citations, and other information about scholarly articles from various sources. However, it has been observed that the two platforms often show different publication and citation data for the same institutions, journals, and authors. While several previous studies analysed different aspects of ResearchGate and Google Scholar, the quantum of differences in publications, citations, and metrics between the two and the probable reasons for the same are not explored much. This article, therefore, attempts to bridge this research gap by analysing and measuring the differences in publications, citations, and different metrics of the two platforms for a large data set of highly cited authors. The results indicate that there are significantly high differences in publications and citations for the same authors captured by the two platforms, with Google Scholar having higher counts for a vast majority of the cases. The different metrics computed by the two platforms also differ in their values, showing different degrees of correlation. The coverage policy, indexing errors, author attribution mechanism, and strategy to deal with predatory publishing are found to be the main probable reasons for the differences in the two platforms.

     

Synthesis and characterization of poly(ethylene aspartate)-metal complexes

Poly(ethylene aspartate) [PEA] was synthesized by the melt condensation of D,L-aspartic acid and ethylene glycol. PEA containing pendent amino and carbonyl groups in its repeating chain was used as the polymeric ligand for complexation with transition metal ions, viz. Co(II), Ni(II), Cu(II), Mn(II), Zn(II), Cd(II), Ca(II), Mg(II), Pb(II) and Hg(II). Complexation was found to be most effective in DMSO. The resulting polyester-metal complexes were solid coloured materials which have been characterized by IR spectroscopy, elemental analysis and magnetic susceptibility measurements. The thermal stability of the polyester-metal complexes was investigated by thermogravimetric analysis (TGA). On the basis of the physico-chemical studies, an oxygen and nitrogen coordinated structure for the polyester-metal complexes is proposed.     

Development of Low-Oxide MCrAlY Coatings for Gas Turbine Applications

Advanced high-energy plasma systems are being used to achieve the benefits of the high-velocity oxy-fuel (HVOF) system without losing the inherent advantages of plasma for coating of gas turbine parts. MCrAlY coatings play a very important role in the performance and reliability of gas turbine components. One of the important considerations for next generation of gas turbines, which have more demanding conditions and need to withstand ever increasing operating temperatures, is that they should possess very low oxygen content levels in the coating. Low oxygen content coatings are applied by the expensive low-pressure plasma spray (LPPS)/vacuum plasma spray (VPS) technique for critical components in aero- and land-based gas turbines. This work deals with the development of low-cost LPPS equivalent coatings (having low oxygen content) using the high-energy high-velocity plasma spray (HEHVPS) gun and inert gas shroud. A comparison has also been made with CoNiCrAlY coatings by HVOF.     

On the microhardness testing of electrically stressed poly(phenylene oxide): Polystyrene blends

Microhardness measurements have been performed on untreated (virgin) and electrically stressed, solvent‐cast laboratory‐prepared samples of pure poly(phenylene oxide) (PPO), pure polystyrene (PS), and PPO : PS polyblends with different weight proportions. Results of such measurement on untreated polyblend sample show that microhardness (H_v) increases with increase in the content of PS up to 10 wt %, which attributed to the existence of homogeneous phase morphology. However, this feature is not observable in samples containing higher content of PS. Electrical stress is found to modify considerably the mechanical property of polymer. The effect of electric field on the microhardness of such samples (PPO : PS :: 90 : 10) has been characterized by the existence of a peak. Trapping of charge carriers in electrically stressed samples imparts hardening to the polyblend up to an applied step field of 190 kV/cm. However, the excessive charging beyond this step field value destroys this characteristic. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Variation resilient low-power memristor-based synchronous flip-flops: design and analysis

Microsystem Technologies - Flip-flops are the basic digital components for all types of complex digital electronics systems and sequential logic circuits. In this paper, new nonvolatile, low power,...     

Coordination polymers of Zn(II) and N,N'-bis (carboxymethyl) dithiooxamide

Summary Coordination polymers were synthesized using N,N'-Bis (carboxymethyl) dithiooxamide (NN' CMDTO) and Zinc(II) salts. The complexes were characterized by elemental analyses, IR spectral studies, TGA and viscosity measurements. In the proposed structures the ligand was supposed to be coordinated to metal through sulphur and oxygen.     

PHOTOCATALYTIC OXIDATION OF ALDEHYDES/PCE USING POROUS ANATASE TITANIA AND VISIBLE-LIGHT-RESPONSIVE BROOKITE TITANIA

We have synthesized an annealed porous aerogel titania (LUAG2), which demonstrates a very high photocatalytic activity for aldehydes and perchloroethylene (PCE) photocatalytic oxidation (PCO) in gas phase under blacklight and fluorescent light irradiation. LUAG2 has a BET surface area of 237 m²/g and a porosity of 0.31 (volume fraction). X-ray diffraction (XRD) analysis shows LUAG2 is nearly pure anatase. It has improved the destruction of PCE and aldehydes as a group by 10-34% with black light compared to Degussa P-25. The optimum water vapor to butyraldehyde molar ratio is around 1/3. LUAG2 also shows better mineralization to CO₂ than Degussa P-25 TiO₂ does. Under irradiation of a 4 W fluorescent lamp LUAG2 gives a consistently higher conversion than that of Degussa P-25. The highly active photocatalyst indicates potential applications in indoor and outdoor environmental pollution control. A visible-light-responsive TiO₂, NTB 200, is also investigated for comparison purposes.     

A stochastic Kaczmarz algorithm for network tomography

We develop a stochastic approximation version of the classical Kaczmarz algorithm that is incremental in nature and takes as input noisy real time data. Our analysis shows that with probability one it mimics the behavior of the original scheme: starting from the same initial point, our algorithm and the corresponding deterministic Kaczmarz algorithm converge to precisely the same point. The motivation for this work comes from network tomography where network parameters are to be estimated based upon end-to-end measurements. Numerical examples via Matlab based simulations demonstrate the efficacy of the algorithm.