Effect of water aging on the mechanical properties of flax fiber/bio-based resin composites

Present work investigates the effect of hydrothermal aging of flax fiber-reinforced bio-based epoxy resin laminates on the mechanical and thermomechanical properties of the composites. Three different types of bio-based resins were used. Plates reinforced with eight layers plain weave flax fibers of 150 g/m², manufactured using Resin Transfer Molding (RTM), compression molding or autoclave technique depends on type of the resin. One dimensional Fickian behavior shows a good fitting to the experimental data derived from weight measurements. The water uptake at the equilibrium state in the case of 60 °C temperature was slightly greater than that at 40 °C. The mechanical properties after hydrothermal aging show a significant reduction and do not return to their initial values even after the drying process. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48787.     

Urine proteomic studies in preeclampsia

Preeclampsia (PE) is a multisystem disorder of pregnancy that develops after 20 wk of gestation in previously normotensive women and complicates 5–8% of pregnancies. This rapidly progressive syndrome is usually diagnosed when the mother develops hypertension and proteinuria. The only effective treatment is delivery of the baby although early low-dose aspirin has been shown to significantly reduce the risk for PE. Recent advances in proteomic methods of protein separation, identification, and quantitation may allow for the identification of proteins and peptides that could facilitate early detection of disease, improve assessment of prognosis, and allow closer monitoring of women at risk for PE. This review summarizes all currently available markers for prediction and diagnosis of PE and presents urine proteomic studies performed for the identification of novel biomarkers.     

Managing the introduction of information security awareness programmes in organisations

Several studies explore information security awareness focusing on individual and/or organisational aspects. This paper argues that security awareness processes are associated with interrelated changes that occur at the organisational, the technological and the individual level. We introduce an integrated analytical framework that has been developed through action research in a public sector organisation, comprising actor-network theory (ANT), structuration theory and contextualism. We develop and use this framework to analyse and manage changes introduced by the implementation of a security awareness programme in the research setting. The paper illustrates the limitations of each theory (ANT, structuration theory and contextualism) to study multi-level changes when used individually, demonstrates the synergies of the three theories, and proposes how they can be used to study and manage awareness-related changes at the individual, organisational and technological level.     

Amphiphilic diblock and ABC triblock methacrylate copolymers: synthesis and aqueous solution characterization

Three isomeric, linear, equimolar, amphiphilic ABC triblock copolymers comprising methyl methacrylate (MMA, nonionic hydrophobic), 2-(dimethylamino)ethyl methacrylate, (DMAEMA, ionizable hydrophilic) and hexa(ethylene glycol) methacrylate (HEGMA, nonionic hydrophilic) units (10 units in each block) were synthesized by group transfer polymerization (GTP). These were the three block sequence isomers, ABC, ACB and BAC. The corresponding random terpolymer was also prepared. The molecular weights and compositions of all the polymers were characterized by GPC and ¹H NMR. Measurements of the hydrodynamic diameters and cloud points of the copolymers in aqueous solution suggest that the various distributions of monomer units in the four terpolymers (the three triblocks and the random) result in different supramolecular structures with different colloidal stabilities.     

Carbon footprint of green roof installation on school buildings in Greek Mediterranean climatic region

Green roof installation in contemporary urban centres is increasing due to their numerous benefits, including microclimate improvement. However, the magnitudes of influence of the green roof design to energy savings is not fully clear, as well as the environmental benefit, in terms of reducing greenhouse gases emissions. The aim of this study was to estimate the effect of green roofs design on energy savings and their carbon footprint when installed on school buildings. The cooling and thermal insulation features of green roofs have been studied by using the TRNSYS simulation software. Different types of green roof systems (extensive and semi-intensive) and construction options are studied in four types of school buildings. Results showed that the estimated reduction in annual CO₂ emissions due to energy savings and CO₂ capture by plants was many times greater than the CO₂ emissions that caused from roof construction.     

Development and characterization of a digestion model based on olive oil microemulsions

Olive oil microemulsions were used as biomimetic model to simulate aspects of the digestion process in the small intestine. Hydrolytic activity of trypsin and alkaline phosphatase in microemulsions in the presence and in the absence of squalene and phenolic acids at pH 8.5 and 37°C was examined. In the case of trypsin kinetic constants were calculated and found K_m = 0.080 ± 0.002 mM and V_max = 3.8 × 10^?5 ± 0.06 × 10^?5 mM/s. When gallic acid and squalene were added, hydrolytic activity of trypsin was reduced to 77 ± 2% and 69 ± 3%, respectively. In the presence of o‐, m‐, and p‐coumaric acid, protocatechouic acid, and caffeic acid, enzymatic activity was increased up to 142 ± 6%. Hydrolytic activity of alkaline phosphatase was inhibited in the presence of squalene and phenolic acids. To evaluate the size of the dispersed aqueous droplets in the presence and in the absence of enzymes, substrates, and antioxidants, dynamic light scattering (DLS) measurements were carried out and diameters in the range of 8.9–13.4 nm were observed. Membrane flexibility and micropolarity were studied by electron paramagnetic resonance (EPR) spectroscopy. Rotational correlation time (τ_R), order parameter (S), and hyperfine splitting constant (A₀) of doxyl stearic acid in the microemulsions were calculated and found 2.06 ns, 0.17, and 14.30 G, respectively. These values were slightly affected in the presence of additives. Practical applications: The main aim of the present study is to enhance our understanding on the digestibility of proteins and lipids in the presence of food antioxidants suggesting an in vitro digestion model for hydrolases based on virgin olive oil microemulsions. The information generated in this study could potentially facilitate the design and development of novel functional food formulations based on food‐grade colloidal delivery systems. Since modification or fortification of different food products focusing on different areas of health concern are of growing interest among the various sectors of food industry, the proposed research results could be of particular interest.     

Three different types of quasi-model networks: synthesis by group transfer polymerization and characterization

Summary Group transfer polymerization (GTP) chemistry was employed for the preparation of polymethacrylate networks of controlled structure (quasi-model networks) of three different types: (a) regular quasi-model networks, in which all polymer chains were linked at their ends, leaving, in principle, no free chain ends, (b) crosslinked star polymer quasi-model networks, in which star polymers were interlinked via half of their chains, letting the other half free (dangling), and (c) shell-crosslinked polymer quasi-model networks, in which the outer part of the network contained polymer arms (dangling chains). Combination of hydrophilic and hydrophobic monomers led to amphiphilic networks whose aqueous swelling behavior was characterized gravimetrically.     

Equilibrium point analysis of the binary exponential backoff algorithm

A Markovian model of the backoff algorithm used in the slotted 1-persistent carrier sense multiple access/collision detection (CSMA/CD) access protocol is developed in order to analyze the performance of such a network. Due to its complexity, the existing models of the CSMA/CD protocol do not incorporate the effects of the backoff algorithm. In this work, we developed an approximate Markovian model of the system with a multidimensional state vector and we used the equilibrium point analysis technique in order to analyze the model. The throughput–delay characteristics and the stability behavior of the system are extracted, which conform the simulation results and the predictions of other theoretical models presented in the literature.