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为了研究艾丁褐煤液化反应动力学,通过对煤液化产物进行分级处理,得到SO2-4/Fe2O3催化艾丁褐煤温和液化动力学模型,通过origin软件回归出各反应速率常数及相应的表观活化能和指前因子,最后对褐煤温和液化分级反应工艺提出初步设想。结果表明,模型能够较好地模拟动力学试验结果;液化反应中沥青质向酚转化的活化能为267.62 k J/mol,该过程对温度较敏感;反应组分的主要转化为油和沥青质,分别占48%和37%;随反应时间的延长,由沥青质转化得到的油和酚的量逐渐增加,由反应组分转化得到的油和酚的量先增加后趋于恒定,在一定时间内,反应组分是直接转化成油和酚的主要来源;沥青质向油的转化是油增加的速率控制步骤,沥青质向酚的转化是酚增加的速率控制步骤,在煤液化工艺流程中,实行分级加氢液化有利于控制、提高油和酚产率。 相似文献
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在连续进料的操作条件下,选用水、氮气等作为实验介质,在Φ600mm?000mm的耐压不锈钢环流反应器内进行了实验。获得了下降环隙以及中心导流筒气含率的实验数据,并根据所获得的实验数据给出了中心导流筒以及下降环隙的关联式。从能量衡算的角度出发,对中心气升式加压环流反应器进行了理论分析,根据能量平衡推导出了连续操作模式下液相循环速度模型。同时根据实验所获得的数据确定了模型参数,通过计算可以发现,循环液速会随空塔气速以及体系压力的增加而增大,但是液相循环速度不会随着这两个操作工况无限制的变化,当体系压力与空塔气速大于某个值之后,液相循环速度的基本趋于平缓 相似文献
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以煤液化油衍生油为溶剂,在热萃取装置上研究了大唐胜利褐煤等低阶煤的热萃取性能,考察了热萃取温度、热萃取时间、溶煤比、溶剂类型和煤种等因素对煤热萃取性能的影响,同时对大唐胜利褐煤在热萃取过程中氧元素的脱除情况进行了研究.结果表明:煤的热萃取率随温度升高而明显增加,由340℃时的18.7%(daf)增加到430℃时的59.5%(daf),而固体热萃取物回收率在390℃时达到最高值32.4%(daf),反应停留时间以60 min为宜,溶剂与煤的合适质量比为5∶1,在煤液化加氢循环溶剂中具有较高的热萃取率.热萃取过程中大唐胜利5#煤中氧元素的脱除率可达23%(daf). 相似文献
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The dehydrogenation of tetralin over Ni-Mo/A1_2O_3,Fe_2O_3/Al_2O_3,Fe_2O_3 and FeS_2 has been shown inthis investigation to be a typical consecutive reversible reaction,with a small amount of 1,2-dihydronaph-thalene as an intermediate.On the less active catalyst Fe_2O_3,a few percent of 1,4-dihydronaphthalene(DHN)is also formed—the more active the catalyst,the lower the concentration of DHN.The rate of dehydrogena-tion rises with an increase of the partial pressure of tetralin,and declines with an increase of the partialpressure of hydrogen.It was observed that DHN is much more active than tetralin and naphthalene,andin the presence of a catalyst,it can be converted rapidly into naphthalene and tetralin.The fact that hydrogencan accelerate the hydrogenation of DHN is thought to be the main reason for its inhibiting the dehydroge-nation of tetralin.In the presence of a catalyst,1,4-DHN it unstable and can be isomerized into 1,2-DHNvery fast.These different catalysts have almost the same order of activities for dehydrogenation of tetralin,conversion of DHN and hydrogenation of naphthalene.On the hypothesis that the reaction is a consecutiveone on the catalyst surface and that the adsorbed DHN is a very active intermediate,a reaction model hasbeen deduced.The equilibrium constants of adsorption and the rate constants of the catalytic reaction werecalculated.The curves so calculated fit the experimental data very well,thus showing the validity of thismodel.Certain experimental results were explained in the light of this model and the related parameters. 相似文献
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