Effective factors improving catalyst layers of PEM fuel cell

Cathode catalyst layer has an important role on water management across the membrane electrode assembly (MEA). Effect of Pt percentage in commercial catalyst and Pt loading from the viewpoint of activity and water management on performance was investigated. Physical and electrochemical characteristics of conventional and hydrophobic catalyst layers were compared. Performance results revealed that power density of conventional catalyst layers (CLs) increased from 0.28 to 0.64 W/cm² at 0.45 V with the increase in Pt amount in commercial catalyst from 20% to 70% Pt/C for H₂/Air feed. In the case of H₂/O₂ feed, power density of CLs increased from 0.64 to 1.29 W/cm² at 0.45 V for conventional catalyst layers prepared with Tanaka. Increasing Pt load from 0.4 to 1.2 mg/cm², improved kinetic activity at low current density region in both feeding conditions. Scattering electron microscopy (SEM) images revealed that thickness of the catalyst layers (CLs) increases by increasing Pt load. Electrochemical impedance spectroscopy (EIS) results revealed that thinner CLs have lower charge transfer resistance than thicker CLs. Inclusion of 30 wt % Polytetrafluoroethylene (PTFE) nanoparticles in catalyst ink enhanced cell performance for the electrodes manufactured with 20% Pt/C at higher current densities. However, in the case of 70% Pt/C, performance enhancement was not observed. Cyclic voltammetry (CV) results revealed that 20% Pt/C had higher (77 m²/g) electrochemical surface area (ESA) than 70% Pt/C (65 m²/g). In terms of hydrophobic powders, ESA of 30PTFE prepared with 70% Pt/C was higher than 30PTFE prepared with 20 %Pt/C. X-Ray Diffractometer (XRD) results showed that diameter of Pt particles of 20% Pt/C was 2.5 nm, whereas, it was 3.5 nm for 70% Pt/C, which confirms CV results. Nitrogen physisorption results revealed that primary pores of hydrophobic catalyst powder prepared with 70% Pt/C was almost filled (99%) with Nafion and PTFE.     

Design of Unskewed Interior Permanent Magnet Traction Motor with Asymmetric Flux Barriers and Shifted Magnets for Electric Vehicles

Abstract

Interior permanent magnet synchronous motors (IPMSMs) are commonly used in electric and hybrid electric vehicles. Nissan Leaf electric vehicle (EV) uses skewed-rotor IPMSM as a traction motor. This motor is considered as a benchmark in this work. Although, skewing improves the torque quality of the motor by reducing the torque ripple, it reduces the average torque and increases the motor manufacturing complexity and cost. This article proposes improvements to the benchmark motor torque quality without skewing. The proposed motor uses the same stator winding and rotor magnet topologies of the benchmark motor with the same geometric constraints and magnet volume. Modifications are applied to the placement of the magnets in the rotor and the shape of the flux barriers to achieve the performance requirements. The design procedure of the proposed unskewed design is illustrated. Moreover, the electromagnetic performance of the proposed design is investigated. The design shows competitive performance in terms of the average torque, torque ripple, cogging torque, and efficiency compared to the benchmark motor. The mechanical integrity of the design is also verified. The proposed design is found to be a suitable alternative to the benchmark traction motor with a reduced rotor weight and without skewing.     

An exact solution of the navier-stokes equation the vortex with curvilinear axis

This paper studies the steady motion of a viscous incompressible fluid the streamlines of which are, in each plane parallel to a fixed plane Π₀, concentric circles. The locus Γ of the centers of the circles is a skew curve. All motions which are exact solutions of the Navier-Stokes equation are studied and the possible forms of the curve Γ are determined. It is shown that the motions so obtained give an infinite set E of solutions for the motion of the fluid in the instrument called orthogonal rheometer. A subset of E constituted by solutions which are stable with regard to arbitrary disturbances is determined.     

Golden-ratio as a substitute to geometric and harmonic counting to determine multi-author publication credit

Countless bibliometric indexes have been proposed to assess researchers’ productivities, in particular, in fields where the author sequence is regarded helpful in determining authors’ individual credits. Unfortunately, the most popular h-index ignores author ranks and leads to bias with multi-author publications; and of the many bibliometric counting methods proposed for assigning credit to authors, such as harmonic or geometric counting, none seems to have been widely adopted yet. In this work, I challenge the assumption that the total credit for a publication be equal to 1. This total-credit normalization assumption diminishes first-author credit and may impede adoption of multi-author-aware credit assignment rules. Other than on relative contributions, author credit could be based on variables such as accountability, which remains unchanged for the first (and potentially, the last) author regardless of additional coauthors. Therefore, I study the adequacy of several counting methods for first-author-normalized credit, giving full credit to the first author while also crediting coauthors. Harmonic counting has been shown to agree well with empirical data; however, unlike geometric counting, harmonic counting results in unbounded total credit for a publication with first-author-credit normalization in the limit of many authors. I therefore propose adaptable geometric counting and evaluate how it combines the advantages of harmonic and geometric counting through an additional parameter. I show that the golden ratio is a parameter for geometric counting that agrees as well as harmonic counting with empirical data for total-credit normalization; and I discuss the impact of using adaptable geometric counting with first-author-normalized credit. In particular, the latter features bounded total credits even when full credit is given to first authors. In conclusion, geometric counting with the golden ratio can be used for credit assignment without having to choose a parameter value, yet offers customization potential and can be combined with either normalization assumption.     

Facilitation of water management in low Pt loaded PEM fuel cell by creating hydrophobic microporous layer with PTFE,FEP and PDMS polymers: Effect of polymer and carbon amounts

Microporous layers (MPLs) were prepared with different hydrophobic polymers to establish water management in polymer electrolyte membrane (PEM) fuel cells. Besides conventionally used polymers polytetrafluoroethylene (PTFE) and fluorinated ethylene propylene (FEP), two different molecular weights (MW) of polydimethylsiloxane (PDMS) polymer were used as hydrophobic materials in MPL. Membrane electrode assemblies (MEAs) having MPLs with low MW PDMS polymer exhibited the best fuel cell performance compared to the PTFE and FEP based ones. Thus it is concluded that PDMS polymer has a great potential to be used as hydrophobic material for MPL to reduce flooding phenomena in PEM fuel cell.