Poly(Styrene‐Divinylbenzene) Based Media for Liquid Chromatography

The latest developments and in particular important synthetic aspects for the preparation of modern poly(styrene‐divinylbenzene) (PS‐DVB) based liquid chromatography (LC) supports are reviewed. In this context, the chemistry of particular porous and nonporous, functionalized, monolithic, coated silica and more specialized mixed organic PS‐DVB media is covered. Special consideration is given to modern approaches such as micro‐(μ)‐HPLC and coating techniques and their most important applications. Synthetic particularities relevant to the corresponding applications are outlined.     

Introducing the IA-64 architecture

Microprocessors continue on the relentless path to provide more performance. Every new innovation in computing-distributed computing on the Internet, data mining, Java programming, and multimedia data streams-requires more cycles and computing power. Even traditional applications such as databases and numerically intensive codes present increasing problem sizes that drive demand for higher performance. Design innovations, compiler technology, manufacturing process improvements, and integrated circuit advances have been driving exponential performance increases in microprocessors. To continue this growth in the future, Hewlett Packard and Intel architects examined barriers in contemporary designs and found that instruction-level parallelism (ILP) can be exploited for further performance increases. This article examines the motivation, operation, and benefits of the major features of IA-64. Intel's IA-64 manual provides a complete specification of the IA-64 architecture     

A Petri net based design engine for manufacturing systems

Support for the efficient design and operation of complex manufacturing systems requires an integrated modelling, analysis, and control methodology as well as its implementation in a software tool. In this paper the Petri net based design engine TimeNET is presented for this task. Petri nets are able to capture the characteristic features of manufacturing systems in a concise form. A subclass of coloured Petri nets is used, which has been developed especially for the application area of manufacturing. Structure and work plans are modelled separately. Stochastic as well as deterministic and more general distributions are adopted for the firing times of transitions. Fundamental questions about system properties can be answered using qualitative analysis. For an efficient performance and dependability prediction, different evaluation techniques are proposed: direct numerical analysis, approximate analysis, and simulation. Finally, the model can be used to evaluate different control strategies and to control the manufacturing system directly. There is no need to change the modelling methodology, thus avoiding additional effort, for example for model conversion. In the paper this necessary steps are described using an application example.     

Biasing public opinion: Computerized continuous response measurement displays impact viewers’ perceptions of media messages

Computerized displays of continuously acquired audience response measures have become an increasingly common component in television, particularly in political campaign media coverage. However, the effect of such presentations on consumer’s perceptions of both the presenters and their messages remain unclear. To address this concern, simulated computerized continuous response measurement (CRM) graphics were overlaid onto apolitical video content to produce three (negative, neutral, positive) experimental manipulations. The findings revealed considerable symmetry between the valence of the CRM graphics and research participant responses. Evaluations of the presenter and message were significantly more negative following negative CRM graphic manipulation exposure (compared against the neutral and positive conditions) suggesting that CRM graphics can be a powerful device for influencing viewers’ judgments.     

Integrated energy in Germany–A critical look at the development and state of integrated energies in Germany

In the face of global warming and a scarcity of resources, future energy systems are urged to undergo a major and radical transformation. The recognition of the need to embrace renewable energy technologies and to move toward decarbonization has led to significant changes in the German energy generation, consumption and infrastructure. Ambitious German national plans to decrease carbon dioxide emissions on one side, and the unpredictable and volatile nature of renewable energy sources on the other side have elevated the importance of integrated energies in recent years. The deployment of integrated technologies as a solution to interlink various infrastructures creates opportunities for increasing the reliability of energy systems, minimizing environmental impacts and maximizing the share of renewable resources. This paper discusses the role of integrated energy systems in supporting of sustainable solutions for future energy transitions. Moreover, the reinforcement of this movement with the help of different technologies will be discussed and the development of integrated energy systems in Germany will be reviewed.     

Stability of emulsions formulated with high concentrations of sodium caseinate and trehalose

Stability of emulsions formulated with 10 wt.% oil (concentrated fish oil, CFO, sunflower oil, SFO, or olive oil, OO), sodium caseinate concentrations varying from 0.5 to 5 wt.%, giving oil-to-protein ratios of 20–2, and 0, 20, 30 or 40 wt.% aqueous trehalose solution was studied by Turbiscan. Particle size distribution, microstructure, and small angle X-ray scattering (SAXS) patterns were also obtained. The main mechanism of destabilization in a given formulation strongly depended on oil-to-protein ratio. As evidenced by the BS-profile changes with time, emulsions formulated with 0.5 and 1 wt.% NaCas destabilized mainly by creaming while for the 2 wt.% NaCas concentration, both creaming and flocculation mechanisms, were involved. The main destabilization mechanism for the 3, 4 or 5 wt.% NaCas emulsions was flocculation. Stability of emulsions was also affected by the content of trehalose in the aqueous phase. Trehalose diminished the volume-weighted mean diameter (D_4,3) and greatly improved stability.     

Dewetting of conducting polymer inkjet droplets on patterned surfaces

The manufacture of high-performance electronic devices with micrometre or even submicrometre dimensions by solution processing and direct printing, requires the ability to control accurately the flow and spread of functional liquid inks on surfaces. This can be achieved with the help of surface-energy patterns causing inks to be repelled and dewetted from pre-defined regions of the substrate. To exploit this principle for the fabrication of submicrometre device structures, a detailed understanding of the factors causing ink droplets to dewet on patterned surfaces is required. Here, we use hydrophobic surface-energy barriers of different geometries to study the influence of solution viscosity, ink volume, and contact angle on the process of dewetting of inkjet-printed droplets of a water-based conducting polymer. We demonstrate polymer field-effect transistor devices with channel length of 500 nm fabricated by surface-energy-assisted inkjet printing.