表面活性剂辅助水热法中TiO2的形状控制

By hydrolysing titanium isopropoxide in a long hydrocarbon chain surfactant-containing solution, TiO2 fine particles with a diversity of well-defined morphologies was synthesized in this study by a hydrothermal route. The structural change during the formation process was monitored by scanning electron microscopy, transmission electron microscopy and X-ray diffraction analysis. TiO2 with various morphologies such as particle, sheet, rod, tube and flower-like shape was obtained by carefully controlling the preparation conditions. The experimental results show that the pH value is crucial for shape control of the produced TiO2 because it can change the charge state of the surfactant in the solution and the adsorption potential of the surfactant on the TiO2 surface. The shape evolvement of anatase TiO2 was elucidated by quenching the reaction at different stage and the formation mechanism of different shaped TiO2 was suggested.     

Life cycle inventory for base metal ingots production in Japan including mining and mineral processing processes by cost estimating system database

CO2 emission levels of copper and zinc mines from which Japanese smelters import ore concentrates into Japan, were estimated by using a database called MLED. Eleven copper mines selected from data availability of mine site covered 84% of the total imported concentrates. Adding inventories of sea transportation and smelting processes to mine development process, total CO2 emission level for copper and zinc ingots produced in Japan were calculated. The results show that the emission share of mining and mineral processing processes for each mine is indicated around 30%-70% of total emission for ingots, which implies the importance of including the mining activities to the inventory of upper stream products.     

1,6-Anhydro-3,4-O-Fururylidene-β-D-Galactopyranose, A New Furfurylidene Derivative Formed from Lactose During Pyrolysis

A new fufurylidene derivative which tastes bitter was separated from lactose heated at 200°C for 20 hr by ethyl acetate extraction and preparative thin-layer chromatography. The compound was identified as the trans isomer of 1,6-anhydro-3,4-O-furfurylidene-β-D-galactopyranose by ultraviolet, infrared, mass and ¹H-NMR spectroscopy. The compound and its cis isomer were identified in the reaction mixture of furfural and levogalactosan heated at 175°C for 2 hr with nitric acid.     

High pressure synthesis of HgBa2Ca2Cu3Oy without a precursor

Abstracts are not published in this journal     

Gel-Forming Characteristics and Rheological Properties of Kefiran

A water soluble polysaccharide “kefiran” produced by Lactobacillus kefiranofaciens was examined for its gel-forming and rheological properties. Kefiran (3%) formed gel in the presence of ethanol (4–10%). The gel strength in 8% ethanol was comparable to that of 3% gelatin gel in water. Addition of casein (3%) increased gel strength 1.5–2.0 fold. The unique properties of kefiran may make it a useful food additive.     

Chaos and bifurcation in numerical computation by the Runge-Kutta method

In this paper the chaotic phenomenon and bifurcation in numerical computation using the Runge-Kutta method to discretize the nonlinear differential equation are investigated. It is shown that the bifurcation condition in the discretized equation is given by the eigenvalue of the jacobian matrix of the original differential equation. As an example, the bifurcation and chaos when a second-order nonlinear equation is discretized by the Runge-Kutta method is investigated and it is shown that the scenario from a stable fixed point to chaos when the fourth-order Runge-Kutta method is applied is quite different from those of the second-order Runge-Kutta method     

A diagnosability analysis by means of fault distance

A new concept of fault distance is introduced in a failure-diagnosis model. Diagnosability measures such as t-fault diagnosability and t/s-diagnosability are expressed in terms of the fault distance. A new diagnosability measure of partial t-fault diagnosability characterized in terms of fault distance is proposed. In addition, the fault distance of various types of self-diagnosis models are expressed in graph theoretical terms. Applying the fault distance to various types of self-diagnosis models, conditions for diagnosabilities of these models, which have been studied separately, are obtained in a unified manner. Conditions for t-fault diagnosability and sufficient conditions for t/s-diagnosability are obtained with this fault distance.     

Comparative Studies on the α and α-Phosvitin from Hen's Egg Yolk

Physico-chemical properties of α and β-phosvitin were compared. Considerable difference was observed in amino acid composition. Higher concentrations of carbohydrates were found in the β-component than in α. The α-phosvitin was more precipitable with lo-15 mM Ca ion than β. Phosvitin was so heat resistant that no change was observed on electropherogram by heating below 100°C for 10 min, and no coagulation occurred up to 140°C. About 12% of the phosphorus was liberated from whole phosvitin by heating at 140°C for 10 min. All preparations of phosvitin isolated from six individual eggs and mixed yolk of 57 eggs contained the two components.