煤矸石粉/聚酯纤维沥青混合料盐冻损伤研究EI北大核心CSCD

针对煤矸石粉替代率50%、聚酯纤维掺量0.4%的沥青混合料,开展盐冻耦合作用(NaCl溶液质量分数为0%、7.0%、13.0%、26.5%,冻融循环次数为0、2、4、6、8)下的半圆弯曲(SCB)试验,分析了盐冻耦合作用对SCB试件内部损伤劣化过程的影响.结果表明:NaCl溶液质量分数为13.0%、冻融循环为8次时,盐冻耦合作用对沥青混合料的侵蚀破坏作用最强,试件内部损伤最严重;在煤矸石粉与矿粉质量比为1∶1、聚酯纤维掺量为0.4%的条件下,沥青混合料能够形成高黏性、致密、厚实的沥青膜以及由纤维形成的三维网状结构,从而显著降低盐冻侵蚀对沥青混合料的损伤.通过Poly2D模型对SCB试件的极限拉应力损伤量进行拟合,拟合系数为0.944.     

锁紧机构防脱落保持架设计与分析

针对锁紧机构保持架在恶略环境下,反复振动过程中保持架上钢球脱落问题,提出了一种新型防脱落保持架设计方案,重点介绍了锁紧机构中保持架的工作形式,通过ANSYS进行有限元仿真分析,得出新型保持架结构满足刚强度要求以及热变形要求,且在随机振动6.06 g条件位移小,能有效免锁紧机构直线运动时钢球从外部脱落的可能,提高了锁紧机构工作过程中的可靠性与安全性.     

Measuring the disparity among scientific disciplines using Library of Congress Subject Headings

Scientometrics - Examining the relationships among scientific disciplines is important today, but existing methods are limited by the contents and structure of their bibliographic databases. We...     

Adaptive Synchronization-Based Approach for Finite-Time Parameters Identification of Genetic Regulatory Networks

Neural Processing Letters - This paper presents an approach to identify the unknown parameters of genetic regulatory network (GRN) in finite-time. The adaptive synchronization-based method is used...     

Continuous Flow Fabrication of Block Copolymer–Grafted Silica Micro‐Particles in Environmentally Friendly Water/Ethanol Media

Polymer‐grafted inorganic particles (PGIPs) are attractive building blocks for numerous chemical and material applications. Surface‐initiated controlled radical polymerization (SI‐CRP) is the most feasible method to fabricate PGIPs. However, a conventional in‐batch reaction still suffers from several disadvantages, including time‐consuming purification processes, low grafting efficiency, and possible gelation problems. Herein, a facile method is demonstrated to synthesize block copolymer–grafted inorganic particles, that is, poly(poly(ethylene glycol) methyl ether methacrylate) (PPEGMEMA)‐b‐poly(N‐isopropylacrylamide) (PNIPAM)–grafted silica micro‐particles using continuous flow chemistry in an environmentally friendly aqueous media. Immobilizing the chain transfer agent and subsequent SI‐CRP can be accomplished sequentially in a continuous flow system, avoiding multi‐step purification processes in between. The chain length (MW) of the grafted polymers is tunable by adjusting the flow time or monomer concentration, and the narrower molar mass dispersity (Р< 1.4) of the grafted polymers reveals the uniform polymer chains on the particles. Moreover, compared with the in‐batch reaction at the same condition, the continuous system also suppresses possible gelation problems.     

改进Elman神经网络在短期热负荷预测中的应用

热电厂的短期热负荷预测在城市集中供暖中起着至关重要的作用,直接影响热电厂的经济效益和热能利用率。电厂的短期热负荷一般采用神经网络预测模型进行预测,而BP神经网络应用最为广泛。Elman神经网络算法在BP神经网络基础上加入了承接层,作为一步延时算子,实现记忆能力,使系统具备适应时变能力,增强系统全局稳定性。但Elman神经网络算法模型的构造依然需要大量样本的支撑,而且输入层的变量多,导致预测时间依然很长,收敛速度慢。该文在Elman神经网络预测前,进行了相关系数预处理和对样本中异常值的平均化预处理,通过数据归一化运算,使Elman神经网络输入层变量大幅减少。仿真实验表明,改进的Elman神经网络算法使预测模型快速寻优,减少预测时间的同时明显提高预测精度。     

Synthesis of Ionic Ultramicroporous Polymers for Selective Separation of Acetylene from Ethylene

The design of highly stable and efficient porous materials is essential for developing breakthrough hydrocarbon separation methods based on physisorption to replace currently used energy-intensive distillation/absorption technologies. Efforts to develop advanced porous materials such as zeolites, coordination frameworks, and organic polymers have met with limited success. Here, a new class of ionic ultramicroporous polymers (IUPs) with high-density inorganic anions and narrowly distributed ultramicroporosity is reported, which are synthesized by a facile free-radical polymerization using branched and amphiphilic ionic compounds as reactive monomers. A covalent and ionic dual-crosslinking strategy is proposed to manipulate the pore structure of amorphous polymers at the ultramicroporous scale. The IUPs exhibit exceptional selectivity (286.1–474.4) for separating acetylene from ethylene along with high thermal and water stability, collaboratively demonstrated by gas adsorption isotherms and experimental breakthrough curves. Modeling studies unveil the specific binding sites for acetylene capture as well as the interconnected ultramicroporosity for size sieving. The porosity-engineering protocol used in this work can also be extended to the design of other ultramicroporous materials for the challenging separation of other key gas constituents.