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排序方式: 共有69条查询结果,搜索用时 15 毫秒
1.
E. Vetrivendan G. Thendral A. Ravi Shankar C. Mallika 《Materials and Manufacturing Processes》2017,32(12):1435-1441
The insulation resistance of conventional atmospheric plasma-sprayed alumina coatings with 10–15% porosity is ~1011 Ω. The presence of pores, lamellae boundaries, and other non-fillings dampens the insulation resistance of the coating. In the present study, aluminum phosphate was used to seal the surface of plasma-sprayed alumina coating and evaluate the effect of sealing on the insulation resistance and its thermal cycling response. Sealing was carried out with three concentrations of sealant (P/Al molar ratio of 3, 10, and 15). Characterization by X-ray diffraction and scanning electron microscopy revealed the primary sealing phase as aluminum metaphosphate and effective sealing of the pores by the aluminum phosphate phases. Insulation resistance is improved by two orders of magnitude after sealing the coated samples. Sealing with P/Al molar ratio 3 exhibited maximum insulation resistance of ~1013 Ω at room temperature. Thermal cycling studies between 650°C and 200°C on the sealed samples showed deterioration in thermal cycling life after sealing. 相似文献
2.
In this paper, we investigate global uniqueness results for fractional functional differential equations with infinite delay in Fréchet spaces. We shall rely on a nonlinear alternative of Leray-Schauder type in Fréchet spaces due to Frigon and Granas. The results are obtained by using the α-resolvent family (Sα(t))t≥0 on a complex Banach space X combined with the above-mentioned fixed point theorem. As an application, a controllability result with one parameter is also provided to illustrate the theory. 相似文献
3.
K. Swaminathan C. Mallika O. M. Sreedharan 《Journal of the American Ceramic Society》1987,70(7):168-C
The emf of the galvanic cell Pt|UMoO6 UMoO5 |ZrO2 -Y2 O3 |O2 (air, Po2 =0.21 atm)|Pt, measured from 776 to 1127 K, was determined to be E = 751.7−0.4909 ±4.3 mV. Using the standard Gibbs energy of formation, f ΔG°, for UMoO6 reported in the literature from transpiration studies, the f ΔG° for UMoO5 is calculated to be f ΔG°〈UMoO5 〉=−1816.9+0.3748T±6.0 U-mol−1 The magnitudes of the standard entropies of formation, f ΔS°, for UMoO6 and UMoO5 were evaluated from those values reported for the binary oxides which constitute the ternary compounds. 相似文献
4.
Sergei F. Burlatsky Vadim V. Atrazhev Mallika Gummalla Dave A. Condit Fuqiang Liu 《Journal of power sources》2009,190(2):485-492
Proper water management in a hydrogen-fueled polymer electrolyte membrane (PEM) fuel cell is critical for performance and durability. A mathematical model has been developed to elucidate the effect of thermal conductivity and water vapor diffusion coefficient in the gas diffusion layers (GDLs). The fraction of product water removed in the vapor phase through the GDL as a function of GDL properties/set of material and component parameters and operating conditions has been calculated. The current model enables identification of conditions wherein condensation occurs in each GDL component. The model predicts the temperature gradient across various components of a PEM fuel cell, providing insight into the overall mechanism of water transport in a given cell design. The water condensation conditions and transport mode in the GDL components depend on the combination of water vapor diffusion coefficients and thermal conductivities of the GDL components. Different types of GDLs and water transport scenarios are defined in this work, based on water condensation in the GDL and fraction of water that the GDL removes through the vapor phase, respectively. 相似文献
5.
The challenges of growing and aging populations combined with limited clinical resources have created huge demand for wearable and portable healthcare devices. Research advances in wearable biosensors have made it easier to achieve reliable noninvasive monitoring of health and body status. In this review, recent progress in the development of body computing systems for personalized healthcare is presented, with key considerations and case studies. Critical form factors for wearable sensors, their materials, structures, power sources, modes of data communication, and the types of information they can extract from the body are summarized. Statistically meaningful data analysis considerations, including using cohort and longitudinal correlation studies, are reviewed to understand how raw sensor signals can provide actionable information on the state of the body. This informs discussions on how collected sensor data can be used for personalized and even preventative care, such as by guiding closed-loop medical interventions. Finally, outstanding challenges for making wearable sensor systems reliable, practical, and ubiquitous are considered in order to disrupt traditional medical paradigms with personalized and precision care. 相似文献
6.
7.
P. Samarasekara M. A. K. Mallika Arachchi A. S. Abeydeera C. A. N. Fernando A. S. Disanayake R. M. G. Rajapakse 《Bulletin of Materials Science》2005,28(5):483-486
Copper oxide (CuO) thin films with photocurrent as high as 25 μA/cm2 were deposited on conductive glass substrates using d.c. reactive sputtering. This was the highest reported photocurrent
for sputteredp- type copper oxide measured in the electrolyte KI. The photocurrent drastically increased up to 25 (μA/cm2 as the sputtering pressure and the substrate temperature were increased up to 8.5 mbar and 192°C, respectively. All the synthesized
films contained single phase of CuO in this range of pressure and substrate temperature. Variation of the photocurrent, photovoltage,
structure and absorbance with deposition conditions were studied in detail. 相似文献
8.
Corrosion fatigue (CF) behaviour of AISI type 316 LN stainless steels (SS) with three different nitrogen contents was evaluated in a boiling aqueous solution of 5?M NaCl+0·15?M Na2SO4+2·5?ml?l?1 HCl at a stress ratio of 0·5 and a frequency of 0·1?Hz. After the CF tests, the specimens were observed under a field emission gun scanning electron microscope (FEG-SEM) as well as an atomic force microscope (AFM) to understand the deformation mechanism which led to the failure. Slip character could be explained based on the surface deformation features observed using FEG-SEM and AFM. A slip irreversibility relation has been proposed which when applied could explain the CF behaviour of these steels with varying nitrogen contents. Increase in the nitrogen content increased the slip reversibility up to 0·14?wt-% nitrogen; however, further increase in nitrogen content had no beneficial effect on the slip reversibility. 相似文献
9.
10.
Structure‐Guided Design of Thiazolidine Derivatives as Mycobacterium tuberculosis Pantothenate Synthetase Inhibitors 下载免费PDF全文
Parthiban Brindha Devi Ganesh Samala Jonnalagadda Padma Sridevi Shalini Saxena Mallika Alvala Elena G. Salina Prof. Dharmarajan Sriram Prof. Perumal Yogeeswari 《ChemMedChem》2014,9(11):2538-2547
The pantothenate biosynthetic pathway is essential for the persistent growth and virulence of Mycobacterium tuberculosis (Mtb) and one of the enzymes in the pathway, pantothenate synthetase (PS, EC: 6.3.2.1), encoded by the panC gene, has become an appropriate target for new therapeutics to treat tuberculosis. Herein, we report nanomolar thiazolidine inhibitors of Mtb PS developed by a rational inhibitor design approach. The thiazolidine compounds were discovered by using energy‐based pharmacophore modelling and subsequent in vitro screening, which resulted in compounds with a half maximal inhibitory concentration (IC50) value of (1.12±0.12) μM . These compounds were subsequently optimised by a combination of modelling and synthetic chemistry. Hit expansion of the lead by chemical synthesis led to an improved inhibitor with an IC50 value of 350 nM and an Mtb minimum inhibitory concentration (MIC) of 1.55 μM . Some of these compounds also showed good activity against dormant Mtb cells. 相似文献