Self-aligning planarization and passivation for integration applications in III-V semiconductor devices

This work reports an easy planarization and passivation approach for the integration of III-V semiconductor devices. Vertically etched III-V semiconductor devices typically require sidewall passivation to suppress leakage currents and planarization of the passivation material for metal interconnection and device integration. It is, however, challenging to planarize all devices at once. This technique offers wafer-scale passivation and planarization that is automatically leveled to the device top in the 1-3-/spl mu/m vicinity surrounding each device. In this method, a dielectric hard mask is used to define the device area. An undercut structure is intentionally created below the hard mask, which is retained during the subsequent polymer spinning and anisotropic polymer etch back. The spin-on polymer that fills in the undercut seals the sidewalls for all the devices across the wafer. After the polymer etch back, the dielectric mask is removed leaving the polymer surrounding each device level with its device top to atomic scale flatness. This integration method is robust and is insensitive to spin-on polymer thickness, polymer etch nonuniformity, and device height difference. It prevents the polymer under the hard mask from etch-induced damage and creates a polymer-free device surface for metallization upon removal of the dielectric mask. We applied this integration technique in fabricating an InP-based photonic switch that consists of a mesa photodiode and a quantum-well waveguide modulator using benzocyclobutene (BCB) polymer. We demonstrated functional integrated photonic switches with high process yield of >90%, high breakdown voltage of >25 V, and low ohmic contact resistance of /spl sim/10 /spl Omega/. To the best of our knowledge, such an integration of a surface-normal photodiode and a lumped electroabsorption modulator with the use of BCB is the first to be implemented on a single substrate.     

Maternal Power Assertion in Discipline and Moral Discourse Contexts: Commonalities, Differences, and Implications for Children's Moral Conduct and Cognition.

Parental power assertion is traditionally studied in the behavioral domain--discipline triggered by the child's immediate misbehavior--but rarely in the cognitive domain--parent-child discussions of the child's past misbehavior. Maternal power assertion was observed in "do" and "don't" discipline contexts from 14 to 45 months and in the context of mother-child discourse about a recent misbehavior at 56 months. Mothers' use of power cohered across the "do," "don't," and discourse contexts, but its implications were domain specific. Power assertion in the "don't" discipline context predicted behavioral outcomes (more moral conduct at 56 and 73 months, less antisocial conduct at 73 months) but not cognitive outcomes (moral cognition at 56 and 73 months). Power assertion in the discourse context predicted less mature moral cognition but not moral or antisocial conduct. Mothers' high Neuroticism predicted more power assertion in all three contexts. Child effects were examined. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Revealing determinants of two‐phase dynamics of P53 network under gamma irradiation based on a reduced 2D relaxation oscillator model

This study proposes a two‐dimensional (2D) oscillator model of p53 network, which is derived via reducing the multidimensional two‐phase dynamics model into a model of ataxia telangiectasia mutated (ATM) and Wip1 variables, and studies the impact of p53‐regulators on cell fate decision. First, the authors identify a 6D core oscillator module, then reduce this module into a 2D oscillator model while preserving the qualitative behaviours. The introduced 2D model is shown to be an excitable relaxation oscillator. This oscillator provides a mechanism that leads diverse modes underpinning cell fate, each corresponding to a cell state. To investigate the effects of p53 inhibitors and the intrinsic time delay of Wip1 on the characteristics of oscillations, they introduce also a delay differential equation version of the 2D oscillator. They observe that the suppression of p53 inhibitors decreases the amplitudes of p53 oscillation, though the suppression increases the sustained level of p53. They identify Wip1 and P53DINP1 as possible targets for cancer therapies considering their impact on the oscillator, supported by biological findings. They model some mutations as critical changes of the phase space characteristics. Possible cancer therapeutic strategies are then proposed for preventing these mutations’ effects using the phase space approach.Inspec keywords: physiological models, cellular biophysics, cancer, difference equations, delays, enzymes, biochemistry, molecular biophysics, gamma‐rays, radiation therapyOther keywords: two‐phase dynamics model, P53 network, gamma irradiation, 2D relaxation oscillator model, ATM model, Wip1 variables, p53‐regulators, cell fate decision, excitable relaxation oscillator, Wip1 time delay, state‐dependent delay differential equation, cell cycle arrest, cell apoptosis, cancer therapies, Wip1 overexpression, Wip1 downregulation, ATM deficiency, Mdm2 overexpression, Mdm2 downregulation, mutation effects, phase space approach     

Multiobjective evolutionary clustering of Web user sessions: a case study in Web page recommendation

In this study, we experiment with several multiobjective evolutionary algorithms to determine a suitable approach for clustering Web user sessions, which consist of sequences of Web pages visited by the users. Our experimental results show that the multiobjective evolutionary algorithm-based approaches are successful for sequence clustering. We look at a commonly used cluster validity index to verify our findings. The results for this index indicate that the clustering solutions are of high quality. As a case study, the obtained clusters are then used in a Web recommender system for representing usage patterns. As a result of the experiments, we see that these approaches can successfully be applied for generating clustering solutions that lead to a high recommendation accuracy in the recommender model we used in this paper.     

Experiments and simulations of short-pulse laser-pumped extreme ultraviolet lasers

Recent experimental work on the development of extreme ultraviolet lasers undertaken using as the pumping source the VULCAN laser at the Rutherford Appleton Laboratory is compared to detailed simulations. It is shown that short duration (/spl sim/picosecond) pumping can produce X-ray laser pulses of a few picosecond duration and that measurement of the emission from the plasma can give an estimate of the duration of the gain coefficient. The Ehybrid fluid and atomic physics code developed at the University of York is used to simulate X-ray laser gain and plasma emission. Two postprocessors to the Ehybrid code are utilized: 1) to raytrace the X-ray laser beam amplification and refraction and 2) to calculate the radiation emission in the kiloelectronvolt photon energy range. The raytracing and spectral simulations are compared, respectively, to measured X-ray laser output and the output of two diagnostics recording transverse X-ray emission. The pumping laser energy absorbed in the plasma is examined by comparing the simulations to experimental results. It is shown that at high pumping irradiance (>10/sup 15/ Wcm/sup -2/), fast electrons are produced by parametric processes in the preformed long scalelength plasmas. These fast electrons do not pump the population inversion and so pumping efficiency is reduced at high irradiance.     

Remote cutting of Li-ion battery electrodes with infrared and green ns-pulsed fibre lasers

Thin sheet anode and cathode materials made in composite structures constitute some of the most important components of a Li-ion battery. These materials are currently cut by punching technology, which shows degrading behaviour as the tool wears out. A viable option for Li-ion battery electrode manufacturing is the use of remote laser cutting. However, the operation requires fulfilling both productivity and quality aspects to substitute the conventional production method. One of the most critical aspects in quality is the clearance width, which is defined as the extent of the exposed middle layer of the sandwich at the laser cut kerf. This work investigates the quality aspects of laser cutting of Li-ion electrodes when a green fibre laser source (λ?=?532 nm, τ?=?1 ns) is used rather than the more traditional infrared (IR) fibre laser source (λ?=?1,064 nm, τ?=?250 ns). The processing conditions were investigated to reveal the technological feasibility zones. Clearance width was studied within the technological feasibility zones for all the material-laser combinations. Results showed that high productivity criterion is met by the IR system, since cutting speed could reach 30 m/min with 54 W average laser power on both anode and cathode. On the other hand, the green laser provided clearance width below 20 μm. In the best case, the clearance on anode could be eliminated with the green laser system. Although the maximum cutting speed was 4.5 m/min, upscaling of green laser power can provide required productivity.     

On-Chip-Integrated Nanowire Device Platform With Controllable Nanogap for Manipulation, Capturing, and Electrical Characterization of Nanoparticles

We propose and demonstrate nanowire (NW) device platforms on-chip integrated using electric-field-assisted self-assembly. This platform integrates from nanoprobes to microprobes, and conveniently allows for on-chip manipulation, capturing, and electrical characterization of nanoparticles (NPs). Synthesizing segmented (Au-Ag-Au) NWs and aligning them across predefined microelectrode arrays under ac electric field, we controllably form nanogaps between the self-aligned end (Au) segments by selectively removing the middle (Ag) segments. We precisely control and tune the size of this middle section for nanogap formation in the synthesis process. Using electric field across nanogaps between these nanoprobes, we capture NPs to electrically address and probe them at the nanoscale. This approach holds great promise for the construction of single NP devices with electrical nanoprobe contacts.     

Functionalized Hybrid Coatings on ABS Surfaces by PLD and Dip Coatings

It is important to give water-repellent and antibacterial properties to the acrylonitrile butadiene styrene (ABS) surfaces of the hearing aids. In this study, the sol–gel Si and sol–gel Ti solutions were prepared from the reactions of silicon ethoxide, titanium butoxide and methacrylic acid. The catalyst and Dynasylan F8815 were added to the sol–gel solutions to give hydrophobic properties onto the ABS surfaces. Additionally, silver nanoparticles were synthesized by nanosecond laser and added to the coating solutions to give extra antibacterial properties. The surfaces of the ABS targets were coated using the sol–gel dip coating and pulsed laser deposition techniques. The coatings with good adhesion between film and substrate and good water-repellent properties were achieved. The average contact angles for the coated ABS surfaces were measured in the range between 120 and 125 degrees. The obtained sol–gel materials and produced thin films onto the ABS surfaces were also analyzed in terms of the antibacterial properties. The highly antibacterial properties were observed in the sol–gel solutions and the thin films.