Einfluß des Spannungsarmglühens auf die mechanischen Eigenschaften und das Gefüge von schweißsimulierend wärmebehandelten Proben aus warmfesten Feinkornbaustählen

Untersuchung der Eigenschaften des grobkörnigen Gefüges im wärmebeeinflußten Bereich neben einer Schweißnaht an simulierend wärmebehandelten Proben von sechs Feinkornbaustählen, nämlich 17 MnMoV 6 4, 17 MnNiMoV 5 4, 17 MnNiMoNb 6 6, 22 NiMoCr 3 7, 17 MnNiMo 5 4 und 17 NiCrMo 10 6. Einfluß des Spannungsarmglühens vorwiegend bei 580 °C bis 100 h Dauer auf Härte und Kerbschlagzähigkeit. Ermittlung der Übergangstemperatur für die Kerbschlagzähigkeit, der Bruchzähigkeit und der Rißfortschrittgeschwindigkeit. Zeitstandversuche bis 100 h Dauer vorwiegend bei 580 °C an glatten und gekerbten Proben sowie Entspannungsversuche an glatten Proben. Zusammenhang zwischen Zeitstandkerbempfindlichkeit, Zeitbruchdehnung, Entspannungsverhalten und Rißbildung bei Spannungsarmglühen. Abgrenzung der Bedingungen für das Entstehen von Rissen beim Spannungsarmglühen.     

Role of ATRX in chromatin structure and function: implications for chromosome instability and human disease

Functional differentiation of chromatin structure is essential for the control of gene expression, nuclear architecture, and chromosome stability. Compelling evidence indicates that alterations in chromatin remodeling proteins play an important role in the pathogenesis of human disease. Among these, α-thalassemia mental retardation X-linked protein (ATRX) has recently emerged as a critical factor involved in heterochromatin formation at mammalian centromeres and telomeres as well as facultative heterochromatin on the murine inactive X chromosome. Mutations in human ATRX result in an X-linked neurodevelopmental condition with various degrees of gonadal dysgenesis (ATRX syndrome). Patients with ATRX syndrome may exhibit skewed X chromosome inactivation (XCI) patterns, and ATRX-deficient mice exhibit abnormal imprinted XCI in the trophoblast cell line. Non-random or skewed XCI can potentially affect both the onset and severity of X-linked disease. Notably, failure to establish epigenetic modifications associated with the inactive X chromosome (Xi) results in several conditions that exhibit genomic and chromosome instability such as fragile X syndrome as well as cancer development. Insight into the molecular mechanisms of ATRX function and its interacting partners in different tissues will no doubt contribute to our understanding of the pathogenesis of ATRX syndrome as well as the epigenetic origins of aneuploidy. In turn, this knowledge will be essential for the identification of novel drug targets and diagnostic tools for cancer progression as well as the therapeutic management of global epigenetic changes commonly associated with malignant neoplastic transformation.     

Active cellular preform derived from stems of jute and sticks of cane and their suitability for bulk porous Si/SiC ceramics

Stems of Jute (Corchorus capsularis L.) and sticks of Cane (Calamus rotang L.), plants of immense economic importance in the Indian subcontinent, were converted into carbonaceous perform (C-preform) maintaining the circular cylindrical shapes in lengths of 0.02–0.05 m by controlled thermal processing. Plant material precursors were characterized by analysis of elemental (C, H, N) and molecular (cellulose, hemicellulose, lignin) compositions, by determination of Bulk Density (BD) and ash content and by optical microscopy and X-ray diffractometry (XRD). C-preforms were also characterized by measurement of BD and by Scanning Electron Microscopy (SEM) and XRD. The C-preforms were further subjected to infiltration with Si-melt (1823–1923 K) under vacuum. Spontaneous infiltration and reaction yielded composite ceramics preserving the morphology of native Jute Stem (JS) and Cane Stick (CS) precursors on macro and micro scale. The materials were found to be duplex composites with Si and β-SiC as crystalline phases. The end ceramics were characterized by measurement of BD, and also by SEM and by XRD. Measured mean BD of the Si/SiC composites derived from JS and CS were 2190 Kg m⁻³ and 2250 Kg m⁻³. The respective volume fractions of large diameter (>100 μm) bulk pores were 0.134 and 0.204, in the composites derived from JS and CS. Taking into account the measured volume fraction internal pores of 0.11 and 0.149, the volume fractions of SiC were calculated to be 0.136 and 0.307 in the composites derived from JS and CS respectively, closely tallying with those calculated from the C-preform bulk densities. The cellular Si/SiC ceramics derived from JS and CS having special morphologies with long and large porous channels and oriented growth of constituent phases are likely to be suitable for devices such as high temperature insulators, catalyst support structures for gas phase reactions at elevated temperatures, molten metal filters and others.     

Biodegradable film. IV. Printability study on biodegradable film

A starch‐based biodegradable (BD) low density polyethylene (LDPE) film can be directly printable without any corona treatment, unlike virgin LDPE film. Such a film shows poor adhesion and nail scratch resistance of the ink on the printed area of the film. In order to increase the adhesion and nail scratch resistance of the ink on the printed BD film, grafting of acrylonitrile onto the BD film is carried out. The polyacrylonitrile grafted BD film shows better adhesion, nail scratch resistance, and printability. The printability of the polyacrylonitrile grafted BD film is comparable to the conventional corona treated LDPE film. The extent of printability is a function of the surface smoothness, as well as the optimum percentage of grafting on the biodegradable film. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 79: 1273–1277, 2001     

A new rigid rodlike colored poly(amide hydrazide): Thermal,optical anisotropic,and mechanical behavior

A new aromatic all-para oriented poly(amide hydrazide) containing an azo group in the main chain was prepared by reacting a symmetric diamine containing a preformed hydrazide group, viz., N,N′-bis(4-aminobenzoyl)hydrazine (BABH), with 4,4′-azobenzoyl chloride (ADBC). The thermal behavior of the polymer was studied by TGA and DSC in air and nitrogen. Films of the polymer were prepared by two processes, viz., wet and dry processes, by using its solution in DMAc containing LiCl. The optical anisotropy, surface morphology, and tensile properties of the films were studied. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 1211–1215, 1997     

Cognitive vertical handover engine for vehicular communication

Always best connected (ABC) communication is an essential requirement for intelligent transportation system. In this paper, we propose a cognitive vertical handover (CVHO) engine to ensure seamless connectivity on the move. Analytic hierarchy process and artificial neural network are used for the development of the algorithm and MATLAB is used as simulation platform. The CVHO engine, which is knowledge based context aware system, takes into account multiple relevant criteria and previous experiences. This system is capable of performing both voluntary and reflex actions. A detailed literature review is presented to compare this work with the conventional methods of vertical handover. A case study, considering the network selection in a typical highway traffic scenario, which consists of both peer-to-peer (P2P) and mobile networks, is presented for the validation of the design. Three radio access technologies, WLAN (P2P), UMTS and WiMAX (mobile networks), are considered for simulation. The results show that the presented model not only realistically optimizes the best available network on the move but also avoids unnecessary handovers. This algorithm is specific to vehicular communication system and hence variation in network selection with vehicle speed is shown.     

Development of mineral oil free offset printing ink using vegetable oil esters

Until the middle of this century, fats and oils are the major raw material source for paints, coating and lubricating applications. These markets are completely taken over by petroleum based stocks due to their abundance and versatility. However, recent public awareness to use environmentally acceptable products that minimize pollution, are compatible to human health and readily biodegradable created opportunities for vegetable oils for application in paints and printing inks. The formulation of vegetable oil methyl ester based 'green' offset printing ink that reduces the volatile organic compounds (VOC) has been discussed in the present study. Methyl esters of rapeseed, soybean, rice bran and palm oil have been prepared and their physical properties have been measured and compared with standard petroleum feed stock. Varnishes were prepared with these esters and their properties are also compared with that of the petroleum based products. Rheological properties of the inks are also evaluated and compared with standard printing ink using petroleum based solvent. In general performance of the ester-based printing inks are comparable with that of the mineral oil based product. On the basis of tack stability and gloss, ester based inks are much superior than the mineral oil based products. In conclusion, a new non-volatile diluent for printing ink has been developed. The diluent is made from common vegetable oils like rapeseed, soybean, rice bran and palm oil, a renewable source that is environmental friendly. Vegetable oil esters offer a cost effective solution for mineral oil based printing ink to meet VOCs regulations.