Oil Families and Their Potential Sources in the Southern Gulf of Suez, Egypt

Four oil families are identified in the southern Gulf of Suez, through high-resolution geochemical studies including gas chromatography, gas chromatography-mass spectrometry, and carbon isotope analyses. Biological features characterize oils in family 1a, suggesting tertiary carbonate source rocks for these oils, rich in type II organic matter and deposited under anoxic depositional environment. Family 1b oil shows minor variations in the source of organic matter and the depositional environment, as it was derived from carbonate source rock with more algal and bacterial contribution and minor input of terrestrial organic sources, deposited under less saline condition compared to family 1a oil. Family 2 oil, although genetically related to family 1a oil, has some distinctive features, such as diasterane to sterane and pristane to phytane ratios, which suggest clay-rich source rocks and a more oxic depositional environment. Also, the lack of oleanane indicates pre-tertiary source rocks for this oil. In contrast, family 3 oil is of mixed sources (marine and non-marine), generated from low sulfur and clay-rich source rock of tertiary and/or younger age. Family 4 oil seems to be mixed from family 1b and family 3 oils, sourced mainly from carbonate source rocks rich in clay minerals with algal and bacterial contributions. Family 4 oil is highly mature, family 1b oil lies within equilibrium values (peak oil generation stage), while the other families are more or less near equilibrium.     

Novel hybrid DNN approaches for speaker verification in emotional and stressful talking environments

Neural Computing and Applications - In this work, we conducted an empirical comparative study of the performance of text-independent speaker verification in emotional and stressful environments....     

Preparation and characterization of new photoactive polyamides containing 4‐(4‐dimethylaminophenyl)urazole units

4‐(4‐dimethylaminophenyl)‐1,2,4‐triazolidine‐3,5‐dione ( DAPTD ) was prepared from 4‐dimethylaminobenzoic acid in five steps. The compound DAPTD was reacted with excess acetyl chloride in N,N‐dimethylacetamide (DMAc) solution and gave 1,2‐bisacetyl‐4‐[4‐(dimethylaminophenyl)]‐1,2,4‐triazolidine‐3,5‐dione as a model compound. Solution polycondensation reactions of monomer with succinyl chloride (SucC), suberoyl chloride (SubC), and sebacoyl chloride (SebC) were performed under conventional solution polymerization techniques in the presence of triethylamine and pyridine as a catalyst in N‐methylpyrrolidone (NMP) and led to the formation of novel aliphatic polyamides. These novel polyamides have inherent viscosities in the range of 0.09–0.21 dL/g in N,N‐dimethylformamide (DMF) at 25°C. Fluorimetric studies of the model compound as well as polymers were performed. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 947–954, 2007     

Synthesis of Photoactive Polyureas Derived from 4-(4-Dimethylaminophenyl)-1,2,4-triazolidine-3,5-dione and Diisocyanates

Summary 4-(4-Dimethylaminophenyl)-1,2,4-triazolidine-3,5-dione (DAPTD) was prepared from 4-dimethylaminobenzoic acid in five steps. The reaction of monomer DAPTD with n-isopropylisocyanate was performed at room temperature in N,N-dimethylacetamide (DMAc) solution and the resulting bis-urea derivative was obtained in high yield and was finally used as a model compound for polymerization reaction. The step-growth polymerization reactions of monomer with hexamethylene diisocyanate (HMDI), isophorone diisocyanate (IPDI) and toluene-2,4-diisocyanate (TDI) were performed in DMAc solution in the presence of pyridine, triethylamine or dibutyltin dilurate as catalysts. Some physical properties and structural characterization of these novel polyureas are reported. Fluorimetric studies of the model compound as well as polymers were performed.     

Employing both gender and emotion cues to enhance speaker identification performance in emotional talking environments

Speaker recognition performance in emotional talking environments is not as high as it is in neutral talking environments. This work focuses on proposing, implementing, and evaluating a new approach to enhance the performance in emotional talking environments. The new proposed approach is based on identifying the unknown speaker using both his/her gender and emotion cues. Both Hidden Markov Models (HMMs) and Suprasegmental Hidden Markov Models (SPHMMs) have been used as classifiers in this work. This approach has been tested on our collected emotional speech database which is composed of six emotions. The results of this work show that speaker identification performance based on using both gender and emotion cues is higher than that based on using gender cues only, emotion cues only, and neither gender nor emotion cues by 7.22 %, 4.45 %, and 19.56 %, respectively. This work also shows that the optimum speaker identification performance takes place when the classifiers are completely biased towards suprasegmental models and no impact of acoustic models in the emotional talking environments. The achieved average speaker identification performance based on the new proposed approach falls within 2.35 % of that obtained in subjective evaluation by human judges.     

Modulation Based Combination of High Level Features Generated from SCCF & Contourlet Transforms for CBIR Applications

The need for suitable and cost-effective technologies rise with the growth of the internet of things (IoT) applications. These aim at handling voluminous data transmission in addition to minimum energy and latency cost constraints. LoRa networks are recommended for applications in confined spaces, long ranges, and less battery consumption requirements. However, the end devices in these networks communicate to all gateways in their ranges, thereby expediting energy unproductively in redundant transmissions. In our article, we explore the possibilities of whether LoRa networks could employ the advantages of clustering and propose two algorithms, path-based and data-centric, for such networks. We suggest that LoRaWAN technology with clustering can be apt for long-range, low power consumption IoT applications in the future. We study the impact of network density, node range, and cluster range on the energy consumption in data transmissions. The algorithms are compared with the inherent star-based communication of LoRa networks based on energy consumed, and our results show that, for dense deployments, clustering becomes advantageous.

     

Dynamic estimation of the modeling error statistics in Diffuse Optical Tomography

Diffuse Optical Tomography (DOT) is a non-invasive imaging technique that suffers from a typical large-scale and ill-posed inverse problem with low spatial resolution. In DOT, the inverse problem is computationally intensive and decreasing the computation complexity and making it well-posed is the one of the most challenging research areas. More precisely, one of the well-known complexity reduction techniques is defined as applying modelling error originated from discretization of forward problem. Applying the discretization error in Bayesian inference has already been discussed; the method in which the likelihood is modified by an off-line prior density estimation. This paper implements a new method to enhance the modelling error approach using an iterative scheme to update statistical parameters of modelling discrepancy in DOT. The algorithm is very similar to Ensemble Kalman Filter. Moreover, the reconstruction process in the applied method is conducted by a small sample size rather than off-line method. Hence, the computation complexity is decreased and the algorithm converges in few iterations. The efficiency of the proposed method is illustrated by simulations.     

An enumeration algorithm for integer‐valued data envelopment analysis

Data envelopment analysis (DEA) models assume real‐valued inputs and outputs, but on many occasions, some inputs and/or outputs can only take integer values. In these cases, using DEA models can result in misleading efficiency assessments and inaccurate performance targets. In this paper, we propose an enumeration algorithm for computing efficiency scores and performance targets of decision‐making units with integer value inputs/outputs. In the presented algorithm, we do not use any of the mixed integer linear programming (MILP) models that are used in previous studies. We show that the result of our algorithm and that of the MILP model presented in this context is the same. We also generalize our algorithm for different types of returns to scale as well as for the hybrid setting with real‐valued data.     

Probabilistic design of ground improvement by vertical drains for soil of spatially variable coefficient of consolidation

The design of soil consolidation via prefabricated vertical drains (PVDs) has been traditionally carried out deterministically and thus can be misleading due to the ignorance of the uncertainty associated with the inherent variability of soil properties. To treat such uncertainty in the course of design of soil improvement by PVDs, more rational probabilistic methods are necessary. In this paper, a simplified probabilistic method is proposed in which the inherent variability of the coefficient of consolidation, which is the most significant uncertain soil parameter that affects the consolidation process, is considered. An easy-to-use design procedure and charts are provided for routine use by practitioners.     

Prediction of carbon dioxide separation from gas mixtures in petroleum industries using the Levenberg–Marquardt algorithm

In this study, two mathematical models for hydrate formation process to separate carbon dioxide by a combination of two different kinds of organic and surfactant promoters are presented. Promoters such as sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, and dodecyl trimethyl ammonium chloride as surfactant promoters; also, tetrahydrofuran, cyclopentane, 1,3-dioxolane, and 2-methyl tetrahydrofuran as organic promoters have been used in recent years. The results showed that a combination of 3000 ppm of surfactant promoters and 4 wt% organic promoters had the highest separation rate of carbon dioxide and; consequently, the investigated models were based on this optimum condition. As a matter of fact, by using these simulations the hydrate formation behavior was predicted with high accuracy; moreover, conducting consuming experiments is not essential anymore. To sum up, in the present research both Vandermonde matrix model and Levenberg-Marquardt algorithm were applied to predict the hydrate formation behavior; in addition, their results were precisely considered and validated with experimental data.