Differences of behaviour in electrooxidation of 3,3′-dimethoxybenzidine and its N,N,N′,N′-tetraalkylated derivatives: a further example of potential inversion

The anodic oxidation of 3,3′-dimethoxybenzidine and its derivatives were studied by cyclic voltammetry, voltammetry at a rotating platinum electrode, chronopotentiometry and constant potential coulometry. The exhaustive oxidation of 3,3′-dimethoxybenzidine led at the potential of the first oxidation peak and second oxidation peak, respectively, to a stable cation radical salt (characterized by ESR spectroscopy) and to a quinone-diimine. Whereas, 3,3′-dimethoxy-N,N,N′,N′-tetramethylbenzidine afforded directly a dication salt owing to potential inversion 3,3′-dimethoxy-N,N,N′,N′-tetraethylbenzidine gave the corresponding soluble cation radical salt.     

Analysis of information exchange activities to actualize and validate situation awareness during shift changeovers in nuclear power plants

Shift work situations occur in almost all safety‐critical organizations, and the investigations of some catastrophes like Chernobyl, Exxon Valdez, and the Gol/Legacy mid‐air collision indicated that shift work information exchange played an important role during the evolution of the situation before the accidents. Inadequate communications during shift changeovers challenged operators' work in the moments that preceded these accidents, because they got inadequate information about the current situation. Our research focuses on the information exchange activities (verbal, written, and nonverbal) of nuclear power plant control operators during shift changeovers. Our aim is to investigate how verbal exchanges and other representations enable operator crews to share information regarding the events that occurred in the previous shift to achieve adequate situation awareness. Our findings indicated the importance and richness of the information exchange during the shift changeover process to update and validate individual and collective situation awareness, showing that information adequately shared enables the ad hoc configurations of regulation loops and a safer use of simplified strategies that can be understood and be validated by other operators, reducing the occurrence of cognitive overloads and contributing to the construction of a common cognitive ground that enhances system resilience. © 2010 Wiley Periodicals, Inc.     

An Efficient Mobile Data Gathering Method with Tree Clustering Algorithm in Wireless Sensor Networks Balanced and Unbalanced Topologies

Wireless Personal Communications - Electroencephalography (EEG) is a technique of Electrophysiology used in a wide variety of scientific studies and applications. Inadequately, many commercial...     

Plasma lipids are affected similarly by dietary lauric or palmitic acid in gerbils and monkeys

To compare the relative impact of dietary lauric acid (12∶0) and palmitic acid (16∶0) on plasma lipids, two fat-sensitive species, Mongolian gerbils and cebus monkeys, were fed cholesterol-free, purified diets enriched with either 12∶0-rich or 16∶0-rich fats, while all other fatty acids were held constant by selective blending of up to five natural fats or oils. The two gerbil diets (40 en% from fat) allowed for an 8 en% exchange between 12∶0 and 16∶0, and the monkey diets (31 en% from fat) allowed for 6 en% exchange beteen these two fatty acids. Eight gerbils received the diets for eight weeks, and 12 cebus monkeys were fed each diet in a cross-over design for up to 22 wk. Both diets resulted in similar plasma cholesterol, triglyceride, and high density lipoprotein cholesterol concentrations within each species. Additionally, separation of cebus lipoproteins by discontinuous density-gradient ultracentrifugation failed to show any dietary differences in concentration or composition of the three major lipoprotein classes (d<1.019, 1.019–1.055, and 1.055–1.168 g/mL). Thus, in two species sensitive to manipulations in dietary fat while consuming cholesterol-free diets, 16∶0 was not hypercholesterolemic relative to 12∶0. Based on a paper presented at the PORIM International Palm Oil Congress (PIPOC) held in Kuala Lumpur, Malaysia, September 1993.     

Development of a simulation model for a three-dimensional wind velocity field using Ténès Algeria as a case study

A mathematical simulation model was developed that can determine the three-dimensional wind velocity field over a complex terrain. The Ténès area in the Valley of Cheliff in Algeria was used as a case study. This region is exposed to south-west circulation that makes it favorable to the use of wind energy. Knowledge of wind fields is crucial for predicting the dispersion of pollutants, for forecasting meteorological weather, for fire spread prediction and in the design and implementation of wind turbines. By means of a mass consistent model, an in-house program was developed to calculate the three-dimensional wind velocity field in the study region. The model was supported by a numerical box in which flow through is allowed for in the upper and lateral boundaries. The bottom boundary through which no flow through occurs was determined by the topographic relief at the surface. From measured wind velocities, observed values were calculated by interpolation-extrapolation. Using an optimization method, the adjusted velocities were obtained from constraints, observed velocities and the continuity equation. The model was verified with wind point data, the relative error did not exceed 6%.     

Co1−xZnxFe2O4 (0 ≤ x ≤ 1) nanocrystalline solid solution prepared by the polyol method: Characterization and magnetic properties

Highly crystalline stoichiometric Co_1?xZn_xFe₂O₄ (0 ≤ x ≤ 1) nanoparticles were successfully synthesized by the polyol process. X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), transmission electron microscopy (TEM), infrared spectroscopy (IR), zero-field ⁵⁷Fe Mössbauer spectrometry and magnetic measurements using a SQUID magnetometer were employed to investigate the effect of the substitution of Zn²⁺ ions for Co²⁺ ones on the structure, and the magnetic properties of the cobalt ferrite, CoFe₂O₄. The unit cell parameter almost increases linearly with increasing Zn concentration, x, following Vegard's law. The red and blue shifts observed for the metal-oxygen ν₁ and ν₂ IR vibration bands, respectively, were consistent with the preferential entrance of Zn²⁺ ions in tetrahedral sites. Besides, detailed magnetic investigation in correlation with the cation distribution has been reported. All the particles exhibit superparamagnetic behaviour at room temperature. In addition, the magnetic characteristics (blocking temperature, saturation magnetization, coercivity, Curie temperature) clearly depend on the chemical composition and cation distribution. Both the blocking temperature and Curie temperature decrease drastically with Zn composition, x, increase. Further, the saturation magnetization follows an almost bulk-like behaviour with values notably larger than that of the bulk, mainly attributed to cation distribution deviation.     

An effective hybrid learning system for telecommunication churn prediction

Customer churn has emerged as a critical issue for Customer Relationship Management and customer retention in the telecommunications industry, thus churn prediction is necessary and valuable to retain the customers and reduce the losses. Moreover, high predictive accuracy and good interpretability of the results are two key measures of a classification model. More studies have shown that single model-based classification methods may not be good enough to achieve a satisfactory result. To obtain more accurate predictive results, we present a novel hybrid model-based learning system, which integrates the supervised and unsupervised techniques for predicting customer behaviour. The system combines a modified k-means clustering algorithm and a classic rule inductive technique (FOIL).Three sets of experiments were carried out on telecom datasets. One set of the experiments is for verifying that the weighted k-means clustering can lead to a better data partitioning results; the second set of experiments is for evaluating the classification results, and comparing it to other well-known modelling techniques; the last set of experiment compares the proposed hybrid-model system with several other recently proposed hybrid classification approaches. We also performed a comparative study on a set of benchmarks obtained from the UCI repository. All the results show that the hybrid model-based learning system is very promising and outperform the existing models.     

A component-based policy-neutral architecture for kernel-level access control

Protection should fundamentally be flexible for devices roaming in Beyond 3G networks. In this federation of heterogeneous access networks, each sub-network comes with its own security requirements, policies, and protocols. Foundational element of device security, the embedded OS itself, should become adaptable to make it possible to tune its protection mechanisms to the current security context, notably to support multiple authorization policies. We show how flexibility can be applied to the kernel authorization architecture by adopting a component-based OS design, the component serving as single abstraction for reconfiguration and security. We present a policy-neutral access control architecture called CRACKER (Component-based Reconfigurable Access Control for KERnels) for component-based operating systems. CRACKER supports a wide range of authorization policies, and permits policy reconfiguration, in the same or in different security models. Specified in the Fractal component model, and implemented in the Think OS, CRACKER illustrates how flexible kernel authorization can be realized while maintaining acceptable system performance.     

HVOF sprayed WC–Co coatings: Microstructure,mechanical properties and friction moment prediction

This study aims at gaining a better understanding of the microstructural features that control the mechanical and the tribological performances of WC–12 wt.% Co coatings under High Velocity Oxygen Fuel (HVOF) spraying conditions. This paper looks at the influences of the HVOF process parameters for WC–12Co material on the microstructural and the tribological behaviours of the coatings. The correlation between the coating microstructure and the wear behaviour is investigated by observing and analysing the microstructure and by studying the friction moment using enhanced statistical tool based on neural computations. According to the experimental and the numerical results, it has been shown that the spray parameters affect the phase composition, hardness and porosity of HVOF sprayed WC–12Co coatings and the correlations with HVOF process parameters are fully predictable in the steady-state regime.     

Utilisation of attenuated total reflectance MIR and front-face fluorescence spectroscopies for the identification of Saint-Nectaire cheeses varying by manufacturing conditions

Twelve samples of cheeses (three types of Saint-Nectaire PDO cheeses and Savaron cheeses) differing by manufacturing and ripening conditions, from 12 different producers, were characterised by attenuated total reflectance mid-infrared (MIR) and front-face fluorescence spectroscopies, dynamic testing rheology and physico-chemical analysis. Fluorescence spectra (tryptophan residues, vitamin A and riboflavin) and MIR (3,000–2,800 (fat region), 1,700–1,500 (protein region) and 1,500–900 cm⁻¹ (fingerprint region)) spectra were recorded on cheese samples. The potential of the data tables was investigated for discriminating the four different groups of cheeses. The results of factorial discriminant analysis (FDA) performed on the fluorescence and mid-infrared spectra showed a good discrimination of the four cheese groups. Considering cross-validation results, the best classifications (100%) were achieved from mid-infrared and fluorescence spectra, while only 91.7 and 72.2% of correct classification were obtained by applying FDA to rheology and physico-chemical data, respectively. Spectroscopic techniques could provide useful fingerprints and allow the identification of investigated cheeses according to manufacturing conditions. Simple and rapid spectroscopic methods offer a promising approach to the authentication of cheeses.