Synthesis of Hollow Three-Dimensional Channels LiNi_(0.5)Mn_(1.5)O_4 Microsphere by PEO Soft Template Assisted with Solvothermal Method

A appropriate size with three-dimension(3 D) channels for lithium diffusion plays an important role in constructing highperforming LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode materials, as it can not only reduce the transport path of lithium ions and electrons, but also reduce the side effects and withstand the structural strain in the process of repetitive Li~+ intercalation/deintercalation. In this work, an e fficient method for designing the hollow LNMO microsphere with 3 D channels structure by using polyethylene oxide(PEO) as soft template agent assisted solvothermal method is proposed. Experimental results indicate that PEO can make the reagents mingle evenly and nucleate slowly in the solvothermal process, thus obtaining a homogeneous distribution of carbonate precursors. In the final LNMO products, the hollow 3 D channels structure obtained by the decomposition of PEO and carbonate precursor in the calcination can provide abundant electroactive zones and electron/ion transport paths during the charge/discharge process, which benefits to improve the cycling performance and rate capability. The LNMO prepared by adding 1 g PEO possesses the most outstanding electrochemical performance, which presented an excellent discharge capacity of 143.1 mAh g~(-1) at 0.1 C and with a capacity retention of 92.2% after 100 cycles at 1 C. The superior performance attributed to the 3 D channels structure of hollow microspheres, which provide uninterrupted conductive systems and therefore achieve the stable transfer for electron/ion.     

Thermodynamic analysis of ethanol synthesis from hydration of ethylene coupled with a sequential reaction

Coal-based ethanol production by hydration of ethylene is limited by the low equilibrium ethylene conversion at elevated temperature. To improve ethylene conversion, coupling hydration of ethylene with a potential ethanol consumption reaction was analyzed thermodynamically. Five reactions have been attempted and compared: (1) dehydration of ethanol to ethyl ether ({\mathrm{2C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}\mathrm{OH}\iff{\mathrm{C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{OC}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{+H}}_{\mathrm{2}}\mathrm{O}), (2) dehydrogenation of ethanol to acetaldehyde ({\mathrm{C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}\mathrm{OH}\iff {\mathrm{CH}}_{\mathrm{3}}{\mathrm{CHO+H}}_{\mathrm{2}}), (3) esterification of acetic acid with ethanol ({\mathrm{C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{OH+CH}}_{\mathrm{3}}\mathrm{COOH}\iff {\mathrm{CH}}_{\mathrm{3}}{\mathrm{COOC}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{+H}}_{\mathrm{2}}\mathrm{O}), (4) dehydrogenation of ethanol to ethyl acetate ({\mathrm{2C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}\mathrm{OH}\iff {\mathrm{CH}}_{\mathrm{3}}{\mathrm{COOC}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{+2H}}_{\mathrm{2}}), and (5) oxidative dehydrogenation of ethanol to ethyl acetate ({\mathrm{2C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{OH+O}}_{\mathrm{2}}\iff {\mathrm{CH}}_{\mathrm{3}}{\mathrm{COOC}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{+2H}}_{\mathrm{2}}\mathrm{O}). The equilibrium constants and equilibrium distributions of the coupled reactions were calculated and the effects of feed composition, temperature and pressure upon the ethylene equilibrium conversion were examined. The results show that dehydrogenation of ethanol to acetaldehyde has little effect on ethylene conversion, whereas for dehydrogenation of ethanol to acetaldehyde and ethyl acetate, ethylene conversion can be improved from 8% to 12.8% and 18.5%, respectively, under conditions of H₂O/C₂H₄ = 2, 10 atm and 300°C. The esterification of acetic acid with ethanol can greatly enhance the ethylene conversion to 22.5%; in particular, ethylene can be actually completely converted to ethyl acetate by coupling oxidative dehydrogenation of ethanol.     

A computer aided design method for car form and its application based on shape parameters

In the early design stage, automotive modeling should both meet the requirements of aesthetics and engineering. Therefore, a vehicle CAD (computer aided design) model that can be easily adjusted by feedbacks is necessary. Based on CE-Bézier surface, this paper presents a set of algorithms for parametric segmentation and fairing surface generation in a car model. This model is defined by a simplified automotive template and relevant control points, shape parameters and segmentation parameters, which can be modified to alter the car form efficiently. With this model and the corresponding adjustment method, more than fifty various vehicle models are established in this research according to different parameters. And two methods for calculating similarity index between car models are constructed, which are suitable for brand design trend analysis and modelling design decisionmaking.     

EXPERIMENTAL INVESTIGATIONS ON LONGITUDINAL DISPERSION CHARACTERISTICS OF TIDAL RIVERS

1 .　ＩＮＴＲＯＤＵＣＴＩＯＮＵｎｄｅｒｔｈｅｉｎｆｌｕｅｎｃｅｏｆｎａｔｕｒａｌｔｉｄｅｓ,ｔｈｅｉｎｔｅｒａｃ ｔｉｏｎｓｂｅｔｗｅｅｎｆｌｏｗｆｅａｔｕｒｅｓａｎｄｐｏｌｌｕｔａｎｔｌｏｎｇｉｔｕｄｉｎａｌｄｉｆｆｕｓｉｏｎｉｎｔｉｄａｌｒｉｖｅｒｓａｒｅｉｍｐｏｒｔａｎｔｆｏｒｗａｔｅｒｅｎｖｉ ｒｏｎｍｅｎｔｒｅｃｔｉｆｉｃａｔｉｏｎｉｎｅｓｔｕａｒｉｎｅｒｅｇｉｏｎｓ.Ｔｈｅｄｉｆｆｕ ｓｉｏｎａｎｄｔｒａｎｓｐｏｒｔｏｆｐｏｌｌｕｔａｎｔｉｎｎａｔｕｒａｌｒｉｖｅｒｓｆａｌｌｉｎ ｔｏｍ…     

A NEW LARGE CAVITATION CHANNEL IN CHINA SHIP SCIENTIFIC RESEARCH CENTER

1 .　INTRODUCTIONIntherecentdecades ,itisrealizedthatitisquitenecessarytocarryouttestsathighReynoldsnumberwithalowbackgroundnoiselevelinordertomeetmoreandmoreurgentneedsofmodernnavyandmaritimeindustry .Anewlargecavita tionchannelisdevelopedinCSSRCfortestingcompletehull/ propulsor/appendagesarrange ments[1] .Itrepresentsoneofthelatestintechno logicallyadvancedlargecavitationtestfacilities.Inthefollowingsections ,thefeaturesandthefirsttestresultsofthechannelwillbedescribed .2 .　DICRIP…     

EXPERIMENTAL INVESTIGATIONS ON DIFFUSION CHARACTERISTICS OF HIGH CONCENTRATION JET FLOW IN NEAR REGION

1 .　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｒｅｓｅａｒｃｈｏｆｊｅｔｉｓａｎｉｍｐｏｒｔａｎｔｆｉｅｌｄｉｎｆｌｕｉｄｍｅｃｈａｎｉｃｓ.Ｉｔａｌｓｏｈａｓｍａｎｙａｐｐｌｉｃａｔｉｏｎｓｉｎｅｎｇｉｎｅｅｒｉｎｇ ,ｆｏｒｅｘａｍｐｌｅ ,ｔｈｅｄｉｓｃｈａｒｇｅｏｆｐｏｌｌｕｔａｎｔａｎｄｃｏｏｌｉｎｇｗａｔｅｒｉｎｉｎｄｕｓｔｒｉｅｓ .Ｗｈｅｎｔｈｅｉｎｉｔｉａｌｄｅｎｓｉｔｙｏｆｔｈｅｊｅｔｉｓｄｉｆｆｅｒｅｎｔｆｒｏｍｔｈａｔｏｆｔｈｅａｍｂｉｅｎｔｗａｔｅｒｂｏｄｙ ,ｔｈｅｊｅｔｗｉｌｌｂｅａｆ…     

Thermal Radiative Properties of Xonotlite Insulation Material

Introduction Xonotlite-type calcium silicate (6CaO?6SiO2?H2O) is synthesized porous insulation material by hydrothermal processing with quartz powder and limestone as the raw material (with CaO/ SiO2≈1:1). Compared with fire- retardant fibre, xonotlite has more excellent insulating performance, such as low thermal conductivity, environment friendly, high intension, and wide applying temperature range, which has been emphasized in recent years by many scholars and widely used in many indu…     

The Cubooctahedron Shape──A Suboptimal Cell Shape for 3－Dimensional Cellular System

ＴｈｅＣｕｂｏｏｃｔａｈｅｄｒｏｎＳｈａｐｅ──ＡＳｕｂｏｐｔｉｍａｌＣｅｌｌＳｈａｐｅｆｏｒ３－ＤｉｍｅｎｓｉｏｎａｌＣｅｌｌｕｌａｒＳｙｓｔｅｍＣｈａＧｕａｎｇｍｉｎｇ；ＬｉＺｈｅｎｇｍａｏ；ＬｕＦａｎ（ＵｎｉｖｅｒｓｉｔｙｏｆＥｌｅｃｔｒｏｎｉ...     

基于空洞模型的地理位置路由改进算法研究

针对现有WSN中地理位置路由遇路由空洞后会产生冗余路由的问题,提出一种基于感知空洞形状的分段贪婪路由(Easy Modeling Greedy Routing,EMGR)算法。EMGR引入虚拟坐标概念,利用空洞边界探测包收集空洞边界节点信息,将其映射到虚拟坐标系中;根据空洞边界节点在虚拟坐标系的不同分布,定义凹、凸域来概括路由空洞形状;根据不同的空洞形状找到合适的中转节点,采用分段贪婪路由方式传输数据。仿真实验结果表明,相较于GPSR算法,EMGR算法产生的路由跳数减少了35%,网络能耗低,路径扩张率和网络时延小。     

Multiview face recognition: from TensorFace to V-TensorFace and K-TensorFace

Face images under uncontrolled environments suffer from the changes of multiple factors such as camera view, illumination, expression, etc. Tensor analysis provides a way of analyzing the influence of different factors on facial variation. However, the TensorFace model creates a difficulty in representing the nonlinearity of view subspace. In this paper, to break this limitation, we present a view-manifold-based TensorFace (V-TensorFace), in which the latent view manifold preserves the local distances in the multiview face space. Moreover, a kernelized TensorFace (K-TensorFace) for multiview face recognition is proposed to preserve the structure of the latent manifold in the image space. Both methods provide a generative model that involves a continuous view manifold for unseen view representation. Most importantly, we propose a unified framework to generalize TensorFace, V-TensorFace, and K-TensorFace. Finally, an expectation-maximization like algorithm is developed to estimate the identity and view parameters iteratively for a face image of an unknown/unseen view. The experiment on the PIE database shows the effectiveness of the manifold construction method. Extensive comparison experiments on Weizmann and Oriental Face databases for multiview face recognition demonstrate the superiority of the proposed V- and K-TensorFace methods over the view-based principal component analysis and other state-of-the-art approaches for such purpose.