Annealing effects on structural and electrical properties of fluorinated amorphous carbon films deposited by plasma enhanced chemical vapor deposition

The annealing effects on the structural and electrical properties of fluorinated amorphous carbon (a-C:F) thin films prepared from C₆F₆ and Ar plasma are investigated in a N₂ environment at 200 mTorr. The a-C:F films deposited at room temperature are thermally stable up to 250 °C, but as the annealing temperature is increased beyond 300 °C, the fluorine incorporation in the film is reduced, and the degree of crosslinking and graphitization in the film appears to be enhanced. At the annealing temperature of 250 °C, the chemical bond structures of the film are unchanged noticeably, but the interface trapped charges between the film and the silicon substrate are reduced significantly. The increased annealing temperature contributes the decrease of both the interface charges and the effective charge density in the a-C:F film. Higher self-bias voltage is shown to reduce the charge density in the film.     

Effect of the addition of Fe2O3 and heat treatment duration on the magnetic susceptibility of V2O5-P2O5-B2O3 glass system

The effect of the addition of Fe₂O₃ and heat treatment duration on the magnetic susceptibility of vanadium borophosphate glass were studied. The magnetic susceptibility of glass samples was found to increase with increasing Fe₂O₃ content, which may be explained by the formation of the FeO₆ group and the change of Fe²⁺ to Fe³⁺ which has higher paramagnetic properties. No detectable changes in the magnetic susceptibility with heat treatment for the samples containing 0.0, 0.5 and 1.0 mol% Fe₂O₃ was observed. The magnetic susceptibility for the heat treated samples containing 2.5, 5.0 and 7.5 mol% Fe₂O₃ decreases sharply with increasing duration of heat treatment up to 6 h and then remains almost constant. The sharp decrease in magnetic susceptibility of 2.5 mol% Fe₂O₃ is attributed to the increase in the number of ferrous ions. The sharp decrease for samples containing 5.0 and 7.5 mol% Fe₂O₃ is attributed to the increase in the number of Fe³⁺ in tetrahedral co-ordination. The rate of crystallization owing to the heat treatment was calculated and was found to increase with increasing iron oxide content. The geometry of crystallization was found to be in three-, two-and one-dimension(s) for samples containing 2.5, 5.0 and 7.5 mol% Fe₂O₃, respectively.     

Fabrication and characterization of Cu2ZnSnS4 thin films deposited by spray pyrolysis technique

We have investigated synthesis conditions and some properties of sprayed Cu₂ZnSnS₄ (CZTS) thin films in order to determine the best preparation conditions for the realization of CZTS based photovoltaic solar cells. The thin films are made by means of spraying of aqueous solutions containing copper chloride, zinc chloride, tin chloride and thiourea on heated glass substrates at various temperatures. In order to optimize the synthesis conditions of the CZTS films, two series of experiments are performed. In the first series the sprayed duration was fixed at 30 min and in the second it is fixed at 60 min. In each series, the substrate temperature was changed from 553°K to 633°K. The X-ray diffraction shows, on one hand, that the best crystallinity was obtained for 613°K as substrate temperature and 60 min as sprayed duration. On the other hand, these CZTS films exhibit the kesterite structure with preferential orientation along the [112] direction. Atomical Force Microscopy was used to determine the grain sizes and the roughness of these CZTS thin film. After the annealing treatment, we estimated the optical band-gap energy of the CZTS thin film exhibiting the best crystallinity as 1.5 eV which is quite close to the optimum value for a solar cell.     

A meta-modelling framework for knowledge consistency in collaborative design

The design of complex system requires a lot of interactions between experts and then between numerous Computer Aided X software (CAX) (where X can be Design (CAD), Engineering (CAE), Manufacturing (CAM), etc.). In order to improve the consistency of the whole system design and the related data and information, knowledge crossing the expertises must be tracked and formalized regarding a shared reference. That means that instead of defining a large reference models to which each expert refers to, a light collaborative model is defined enabling to connect data from each expert model to adhoc data from other expert models, following the least commitment principle. In this topic, a new meta-model is proposed in a Model-Driven Engineering approach to manage the integration of heterogeneous experts’ knowledge models in a collaborative process. The structure of the proposed knowledge meta-model is defined taking into account the complexity of knowledge definition and the properties of its components. This meta-model is split in a meta-model of data on one hand and a Collaboration Meta-Model in the other hand, to represent the distinction between the core concepts of knowledge and additional elements serving to represent the relation between these concepts, and between concepts of heterogeneous experts’ models. The proposed meta-model is illustrated on an industrial case study to highlight the way to put it in use, and its interests to enable collaboration between experts throughout the design process.     

Effect of SiO2 Addition on Chromium Transitions in Borate Glasses

Silicon - Melt-quenching technique was used to prepare borosilicate glasses of composition xSiO2- (75-x) B2O3–24.7Li2O-0.3Cr2O3 (x = 0, 10, 20, 30, 40 and 50 mol%). With...     

Thermal decomposition and pore structure of pure and doped stannic oxide gel

The surface properties of a stannic oxide gel and its thermal dehydration products obtained both in vacuo and in the presence of air in the temperature range 100–600°C have been examined by N₂ adsorption. Phase and structural changes have been followed by differential thermal analysis and X-ray diffractometry. Complete pore structure analysis showed that samples dehydrated at or below 250°C were microporous. Above 250°C the pores were found to widen with increase of temperature, the widening occurring concurrently with the crystallisation process. Doping with cations of lower valency (Li⁺ and Al³⁺) than the host cation (Sn⁴⁺) had little effect on the pore structure and specific surface area for the low temperature samples (≤250°), whereas at higher temperatures, e.g. 600°C, it increased the specific area remarkably. The dope ions produce oxygen vacancies and hinder or retard sintering in SnO₂.     

Bio-based sustainable films from the Algerian Opuntia ficus-indica cladodes powder: Effect of plasticizer content

The present study investigated the fabrication and characterization of bio-based sustainable films composed of a terrestrial plant raw material, namely Opuntia ficus-indica (OFI) cladodes powder (CP) and a marine seaweed derivative, namely agar (A). The effect of glycerol concentration on the properties of the casted films was evaluated at four different contents, namely 30, 40, 50 and 60 wt%. The films present UV-blocking properties, as well as moderate mechanical performance, thermal stability, and water vapor transmission rate (WVTR). The results point to an increase in thickness, elongation at break, moisture content, water solubility, and WVTR with increasing glycerol content. On the contrary, Young's modulus, tensile strength, and water contact angle decreased as glycerol concentration increased. The best combination is obtained for the film with 30% glycerol, based on an intermediate compromise between physical, mechanical, thermal, and barrier properties. All these outcomes express the potentiality of the powder obtained from grinding the OFI cladodes as raw material to produce low-cost films for the development of sustainable packaging materials.     

Performance analysis of a non-preemptive priority queuing system subjected to a correlated Markovian interruption process

In this paper, we consider a discrete-time queuing system with head-of-line non-preemptive priority scheduling and a single server subjected to server interruptions. We model the server interruptions by a correlated Markovian on/off process with geometrically distributed on and off periods. Two classes of traffic are considered, namely high-priority and low-priority traffic. In the first part of the paper, we derive an expression for the functional equation describing the transient evolution of this priority queuing system. This functional equation is then manipulated and transformed into a mathematical tractable form. This allows us to derive the joint probability generating function (pgf) of the system contents. From this pgf, closed-form expressions for various performance measures, such as mean and variance of system contents and customer delay can be derived. Finally, we illustrate our solution technique with some numerical examples, whereby we demonstrate the negative effect of correlation in the interruption process on the performance of both classes. Some numerical results illustrating the impact of second-order characteristics of the arrival process on mean delays are also presented. The proposed approach which is purely based on pgfs is entirely analytical and enables the derivation of not only steady-state but transient performance measures, as well. The paper presents new insights into the performance analysis of discrete-time queues with service interruption and it also covers some previously published results as a special case.

Scope and purpose

In this contribution, we consider a practical queuing model, with HOL priority scheduling, two classes of traffic, and a server which is subjected to a correlated Markovian interruption process. We first derive a non-linear functional equation relating the joint pgf of the system state vector between two consecutive slots. Then we outline a solution technique to solve for this functional equation. This allows us to derive the joint pgf of the system contents of both classes, from which various performance measures related to mean system contents and customer delays are derived. We also demonstrate how the proposed approach allows for derivation of transient performance measures, as well. It should be noted that detailed coverage of the transient analysis of the system is beyond the scope of this paper.To our best knowledge, this is the first initiative that aims to explore the performance of queuing systems with priority scheduling when the shared server is subjected to service interruption. The paper also generalizes the results of Walraevens et al. (Analysis of a single-server ATM queue with priority scheduling, Computers & Operations Research 2003;30(12):1807–30) by incorporating service interruption into their original queuing model. By means of numerical results, the paper also demonstrates the effect of correlation in the service interruption process on the performance of both classes of customers. The impact of second-order characteristics of the arrival process on mean delays is also investigated.     

A branch-and-bound algorithm to minimize total weighted completion time on identical parallel machines with job release dates

In this paper, we consider an identical parallel machine scheduling problem with release dates. The objective is to minimize the total weighted completion time. This problem is known to be strongly NP-hard. We propose some dominance properties and two lower bounds. We also present an efficient heuristic. A branch-and-bound algorithm, in which the heuristic, the lower bounds and the dominance properties are incorporated, is proposed and tested on a large set of randomly generated instances.     

An effective scheduling scheme for multi-hop multicast in wireless mesh networks

With the utilization of concurrent transmission strategy, a throughput-enhanced scheduling scheme is devised for multicast service in wireless multi-hop mesh networks. Since the performance of a multicast mechanism is constrained in a wireless setting due to the interference among local wireless transmissions, the interference relationships are first characterized by introducing a graph transformation method. Based on the graph transformation, the multicast scheduling problem is converted to the graph coloring problem, and then a capacity greedy algorithm is designed to provide concurrent transmission scheduling so that the demanded multicast transmission rate can be achieved. Moreover, the necessary and sufficient conditions of multicast schedulable feasibility are derived. Through corresponding simulations, it is shown that the proposed strategy can enhance the throughput of wireless multi-hop multicast systems significantly.