Sustainability evaluation framework for building cooling systems: a comparative study of snow storage and conventional chiller systems

In Canada, the residential building sector consumes 17 % of the total energy and 15 % of the total greenhouse gas emissions. In particular, the energy demand for cooling in the residential sector is increasing due to the large occupancy floor area and high usage of air conditioning. Minimizing energy use and greenhouse gas emissions is one of the highest priority goals set for national energy management strategies in developed countries including Canada. In this study, a framework based on the life cycle assessment approach is developed to assess the environmental impacts of different building cooling systems, namely conventional snow storage system, watertight snow storage system, high-density snow storage system, and the conventional chiller cooling system. Moreover, all these systems have varying energy requirements and associated environmental impacts during different phases (extraction and construction, utilization, and end of life) of the life cycle of a building. A low-rise residential building in Kelowna (BC, Canada) has been selected for the pragmatic application of the proposed framework. The annual cooling energy demand for the building is estimated for different phases. Subsequently, the life cycle impact assessment has been carried out using SimaPro 8.1 software and TRACI 2.1 method. For sustainability evaluation of different cooling systems over their life cycle, multi-criteria decision analysis has been employed using the ‘Preference Ranking Organization Method for Enrichment Evaluation (PROMETHEE II).’ The results showed that the snow storage systems tend to reduce greenhouse gas emissions and associated environmental impacts more than the conventional system.     

Reliability analysis of TLP tethers under impulsive loading

In the present study, reliability assessment of Tension Leg Platform (TLP) tethers against maximum tension (i.e. tension exceeding yield) has been carried out under combined action of extreme wave and impulsive forces. For this purpose, a nonlinear dynamic analysis of TLP has been carried out in time domain. A limit state function for maximum tension (i.e. tension exceeding yield) has been derived employing Von-Mises theory of failure. Using this derived limit state function and responses obtained after dynamic analysis under sinusoidal, half-triangular and triangular impulsive forces, reliability assessment of the TLP tethers has been carried out. Design point, important for probabilistic design of tethers, has been located on the failure surface after solving a constrained optimization problem. To study the influence of various random variables on tether reliability, sensitivity analysis has been carried out. Effects of angle of impact; effect of variable submergence; and effect of material yield strength on tether reliability have also been studied on parametric basis. Effect of uncertainty on overall tether reliability has also been discussed to show the importance of quality control in the various design parameters.     

Recent developments in catalyst synthesis using DBD plasma for reforming applications

The catalyst has a significant role in gas processing applications such as reforming technologies for H₂ and syngas production. The stable catalyst is requisite for any industrial catalysis application to make it commercially viable. Several methods are employed to synthesize the catalysts. However, there is still a challenge to achieve a controlled morphology and pure catalyst which majorly influences the catalytic activity in reforming applications. The conventional methods are expansive, and the removal of the impurities are major challenges. Nevertheless, it is not straightforward to achieve the desired structure and stability. Therefore, significant interest has been developed on the advanced techniques to take control of the physicochemical properties of the catalyst through non-thermal plasma (NTP) techniques. In this review, the systematic evolution of the catalyst synthesis using NTP technique is elucidated. The emerging DBD plasma to synthesized and effective surface treatment is reviewed. DBD plasma synthesized catalyst performance in reforming application for H₂ and syngas production is summarised. Furthermore, the status of DBD plasma for catalyst synthesis and proposed future avenues to design environmentally suitable and cost-effective synthesis techniques are discussed.     

A kinetic study of acetoxylation of benzyl chloride—a model of activated allylic chlorides in PVC—using a crown ether complex

Benzyl chloride has been used in a kinetic study of chlorine replacement by acetoxy groups to model the behaviour of allylic chlorine during the acetoxylation of poly(vinyl chloride). Chlorine substitution was carried out in tetrahydrofuran at 30°C using a potassium acetate-crown ether complex with methanol to ensure homogeneous solution. The process followed an S_N2 mechanism. The orders of reaction with respect to benzyl chloride and potassium acetate were close to one, and the second order velocity constant was 4.2 x 10^?5 litre mol^?1 s^?1 when the molar ratio of crown ether to potassium acetate was approximately unity. Higher ratios caused a slight increase in rate constant. Substitution was followed by NMR spectroscopy which also revealed a proton exchange between methanol and acetate anion with an equilibrium constant 9.4 x 10^?2. This observation has suggested an explanation for the effect of some free-radical inhibitors on the rate of acetoxylation of poly(vinyl chloride) by potassium acetate in the presence of crown ether.     

Pseudohalogenation of methyl 9-hydroxy-cis-12-and 12-hydroxy-cis-9-octadecenoate

Pseudohalogenation of methyl 9-hydroxy-cis-12-octadecenoate (I) and methyl 12-hydroxy-cis-9-octadecenoate (II) has been carried out with N,N-dibromobenzenesulfonamide (NNDBS). Compounds I and II, on reaction with NNDBS, formed four and three products, respectively. The interesting feature of these reactions was the formation of 1,4-epoxy compounds. The structures of individual compounds were established with the help of elemental and spectral analysis.     

A medium access protocol exploiting multiuser-detection in CDMA ad-hoc networks

A new medium access protocol which exploits the physical layer capability of multiuser detection is proposed to help in improving the throughput/delay performance of ad-hoc networks. When more than one node has packets buffered for a common node in the neighborhood, all such nodes can simultaneously transmit their packets to the common receiver after reserving their surrounding channel. This is achieved in our protocol by extending the (sender-initiated) CSMA/CA collision avoidance framework by the receiver-initiated medium access technique and incorporating the transmission power control. We analyze the improvement in the throughput that can be achieved over the basic sender-initiated collision avoidance protocol in the network. Since the throughput improvement via multi-packet reception is influenced by the network layer activity as well, the performance of our protocol rolls back to that of the basic sender-initiated protocol in case of no coordination from the network layer. For the evaluation of performance of our protocol we simulate ad-hoc networks for different network topologies and traffic configurations. We observe the scheme to be capable in significantly improving the throughput/delay performance of the network.     

A new algorithm for the normal distribution function

In this paper new algorithms for the rapid, efficient and accurate evaluation of the standard normal integral and its tail are developed. It is shown how the accuracy of the computation can easily be improved so as to achieve machine accuracy for the particular computer being used.