Transesterification of Palm-based Methyl Palmitate into Esteramine Catalyzed by Calcium Oxide Catalyst

The technology for transesterification reactions between methyl esters and alcohols is well established by using classical homogeneous alkaline catalysts, which provide high conversion of methyl esters to specialty or nonindigenous esters. However, in certain products where the purity of the esters is of concern, the removal of homogeneous catalysts after the completion of the reaction is a challenge in terms of production cost and water footprint. Therefore, a study to investigate the potential of heterogeneous catalysts was conducted on reactions between methyl palmitate and triethanolamine. The degree of basicity and active surface area of calcium oxide (CaO), zinc oxide (ZnO), and magnesium oxide (MgO) were first characterized by using temperature-programmed desorption (TPD-CO₂) and Brunauere–Emmett–Teller (BET), respectively. Among the metal oxides investigated, the CaO catalyst showed the best catalytic activity toward the transesterification process as it gave the highest conversion of methyl palmitate and yielded fatty esteramine compositions similar to the conventional homogeneous catalyst. The optimum transesterification condition by using the CaO catalyst utilized a lower vacuum system of approximately 200 mbar, which could minimize a considerable amount of energy consumption. Furthermore, low CaO dosage of 0.1% was able to give a conversion of 94.5% methyl ester and formed esteramine at 170 °C for 2 h. Therefore, the production of esterquats from esteramine may become more economically feasible through the methyl ester route by using the CaO catalyst, which can be recycled three times.     

Miscibility of oligomeric poly(dimethyl siloxanes) with long-chain unbranched alkanes: 2. Unsymmetrical cloud point curves

Previously obtained cloud point curves for mixtures of oligomeric poly(dimethyl siloxanes) (weight fraction W₁) with oligomeric polyethylenes have been supplemented by the use of samples of higher molecular weight. Initial flat regions at low-medium W₁ as well as a slight shoulder at extremely high W₁ are now considered to be due to crystallization, since the temperatures at which they occur are the melting points of the oligoethylenes. The actual cloud point curves were of an unsymmetrical dome shape, the form of which could not be simulated by using a concentration-independent interaction parameter g in the Flory-Huggins equation. However, spinodals calculated by assuming a quadratic dependence of g on composition were of the same shape as the experimental cloud point curves. The critical compositions calculated on this basis were also close to the experimental ones.     

Organic geochemistry of Cretaceous Lamza and Chikila coals, upper Benue trough, Nigeria

Some biomarkers and other compounds in the aliphatic and aromatic fractions of the Lamza and the Chikila coals were characterized and used in assessing the source input, maturity, hence the hydrocarbon generative potentials of the coals. The samples exhibit a slight n-alkanes odd carbon preference (CPI ∼ 1), high pristane/phytane ratios and a dominance of 20S epimer of C₂₉ sterane. The ratio of C₃₀ αβ/(αβ + βα) sterane and 22S/(22S + 22R) C₃₁-homohopane gave values of 0.77-0.83 and 0.58-0.60, respectively. The low Ts/Tm ratios are in agreement with the calculated vitrinite reflectance, R_c (0.60-0.70%). The methylphananthrenes maturity derived parameters (1-MP/9-MP; MPR; MPI-1; R_c) revealed a very slight variation and a consistent order of samples maturity with the exception of the R_c values. All these together with some other hopanoid ratios, show that the organic matter is terrestrially derived, deposited in an oxic environment and at marginal maturity for hydrocarbon generation.     

Polyurethane composites based on oil palm empty fruit bunches: Effect of isocyanate/hydroxyl ratio and chemical modification of empty fruit bunches with toluene diisocyanate and hexamethylene diisocyanate on mechanical properties

This study focuses on the effect of isocyanate (NCO)/hydroxyl (OH) group ratios and chemical modification of oil palm empty fruit bunches (EFBs) with toluene diisocyanate (TDI) and hexamethylene diisocyanate (HMDI) on the mechanical properties of EFB–polyurethane (PU) composites. The tensile, flexural, and impact properties are affected by the NCO/OH ratios. The tensile strengths, flexural strengths, and toughness increase as the NCO/OH increases; however, the modulus decreases. The reduction in the modulus is attributable to the increased flexibility of the PU linkages. Chemical modification of the EFBs increases the tensile strength, flexural strength, and toughness; however, the modulus is lowered as the percentage of treated EFB is increased. Impact strength results show that the strength increases as the NCO/OH ratio is increased. At NCO/OH ratios of 1.0 and 1.1, the composites with HMDI‐treated fibers exhibit higher impact strength than those with TDI‐treated and untreated fibers, respectively. This may be due to the longer and more flexible chain length of HMDI as compared to TDI, which enables the composites to absorb more energy before failure. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Characterising and exploiting workloads of highly interactive video-on-demand

This paper presents a detailed characterisation of user behaviour for a series of interactive video experiments over a 12 month period, in which we served popular sporting and musical content. In addition to generic VCR-like features, our custom-built video-on-demand application provides advanced interactivity features such as bookmarking. The dramatic impact of such functionality on how users consume content is studied and analysed. We discuss in detail how this user behaviour can be exploited by content distributors to improve user experience. Specifically, we study how simple dynamic bookmark placement and interactivity-aware content pre-fetching and replication can reduce the impact of highly interactive media on CDN performance.     

Production planning in automotive powertrain plants: a case study

Based on a real case study from the automotive industry, this paper deals with production planning in powertrain plants. We present an overview of the production planning process and propose a mixed integer linear programme to determine the production quantities of each product over a planning horizon of several days. Then, using real data of an engine assembly line, we simulate the performance obtained through the proposed model within a rolling horizon planning process. We perform multiple tests in order to evaluate the impact of two parameters involved in this process: planning frequency and frozen horizon length. Furthermore, in order to illustrate the value of improving coordination between engine plants and their customers, we evaluate the impact of the quality of demand information (orders and forecasts). We analyse the simulation results and provide insights and recommendations in order to achieve a good trade-off between service level, inventory, and planning stability.