Long Duration Persistent Photocurrent in 3 nm Thin Doped Indium Oxide for Integrated Light Sensing and In-Sensor Neuromorphic Computation

Miniaturization and energy consumption by computational systems remain major challenges to address. Optoelectronics based synaptic and light sensing provide an exciting platform for neuromorphic processing and vision applications offering several advantages. It is highly desirable to achieve single-element image sensors that allow reception of information and execution of in-memory computing processes while maintaining memory for much longer durations without the need for frequent electrical or optical rehearsals. In this work, ultra-thin (<3 nm) doped indium oxide (In₂O₃) layers are engineered to demonstrate a monolithic two-terminal ultraviolet (UV) sensing and processing system with long optical state retention operating at 50 mV. This endows features of several conductance states within the persistent photocurrent window that are harnessed to show learning capabilities and significantly reduce the number of rehearsals. The atomically thin sheets are implemented as a focal plane array (FPA) for UV spectrum based proof-of-concept vision system capable of pattern recognition and memorization required for imaging and detection applications. This integrated light sensing and memory system is deployed to illustrate capabilities for real-time, in-sensor memorization, and recognition tasks. This study provides an important template to engineer miniaturized and low operating voltage neuromorphic platforms across the light spectrum based on application demand.     

Polyethers with phosphate pendant groups by monomer activated anionic ring opening polymerization: Syntheses,characterization and their lithium-ion conductivities

This paper describes the preparations and lithium-ion conductivities of various solid polymer electrolytes for potential use in high-energy density lithium-ion batteries. The ring opening polymerization of epoxides (M1–M6), catalyzed by Zn(II), Cu(II) and Cd(II) complexes in the presence of tetrabutylammonium bromide (TBAB), yielded polyethers (P1–P6) in which phosphates were attached as pendant groups. A reaction condition where Zn(II) catalyst used slightly excess to TBAB increased the polymerization rate remarkably and yielded the polyethers with higher molar masses in a short time. These polymerizations proceeded following a “monomer activated anionic ring opening polymerization” mechanism. These living like polymerizations also progressed according to “formation of polymer chain per initiator” model. The solid-state lithium-ion conductivities of these polymers were examined using lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). The conductivity of one of the solid polymer electrolytes with 40 wt% of LiTFSI was 5.2 × 10⁻⁵ S cm⁻¹ at room temperature and 2.9 × 10⁻⁴ S cm⁻¹ at 80 °C.     

The error performance of Gray encoded QPSK and 8-PSK schemes in afading channel with cochannel interference

Closed-form BER (bit error rate) expressions are derived for Gray-encoded QPSK (quadrature phase shift keying) and 8-PSK schemes using coherent detection in a slow Rayleigh fading narrowband channel with fading cochannel interference. Earlier work has been limited to deriving the approximate BER using the canonical Stein (1961) receiver concept. The symbol error rate (SER) for the QPSK scheme is also derived. The desired signal and the cochannel interferer are both PSK signals, modulated by different baseband pulses with identical signaling rate     

Structural alterations in the workpiece by ultrasonic drilling

The surface integrity of glass workpieces in ultrasonic drilling was investigated. X-ray diffraction studies on glass workpieces drilled by ultrasonic machining revealed the apparent formation of a layer of crystalline material on the surface of the holes drilled, a hitherto unreported phenomenon.     

Optimal Distributed Location Management in Mobile Networks

An important issue in the design of future Personal Communication Services (PCS) networks is the efficient management of location information. In this paper, we consider a distributed database architecture for location management in which update and query loads of the individual databases are balanced. We obtain lower bounds to the worst-case delay in locating a mobile user, to the average delay, and to the call blocking probability. We then propose a dynamic location management algorithm that meets these lower bounds. The optimality of this algorithm with respect to these three performance measures, as well as simplicity, make it an appealing candidate for distributed location management in PCS networks.     

Anatase-brookite mixed phase nano TiO2 catalyzed homolytic decomposition of ammonium nitrate

Compared to the conventional ammonium perchlorate based solid rocket propellants, burning of ammonium nitrate (AN) based propellants produce environmentally innocuous combustion gases. Application of AN as propellant oxidizer is restricted due to low reactivity and low energetics besides its near room temperature polymorphic phase transition. In the present study, anatase-brookite mixed phase TiO₂ nanoparticles (∼10 nm) are synthesized and used as catalyst to enhance the reactivity of the environmental friendly propellant oxidizer ammonium nitrate. The activation energy required for the decomposition reactions, computed by differential and non-linear integral isoconversional methods are used to establish the catalytic activity. Presumably, the removal of NH₃ and H₂O, known inhibitors of ammonium nitrate decomposition reaction, due to the surface reactions on active surface of TiO₂ changes the decomposition pathway and thereby the reactivity.     

Functional imaging in small animals using X-ray computed tomography--study of physiologic measurement reproducibility

X-ray computed tomography (CT) has been traditionally used for morphologic analysis and in the recent past has been used for physiology imaging. This paper seeks to demonstrate functional CT as an effective tool for monitoring changes in tissue physiology associated with disease processes and cellular and molecular level therapeutic processes. We investigated the effect of noise and sampling time on the uncertainty of tissue physiologic parameters. A whole body compartmental model of mouse was formulated to simulate tissue time density curves and study the deviation of tissue physiologic parameters from their true values. These results were then used to determine the appropriate scanning protocols for the experimental studies. Dynamic contrast enhanced CT (DCE-CT) was performed in mice following the injection of hydrophilic iodinated contrast agent (CA) at three different injection rates, namely 0.5 ml/min, 1 ml/min, and 2.0 ml/min. These experiments probed the Nyquist sampling limit for reproducibility of tissue physiologic parameters. Separate experiments were performed with three mice at four different X-ray tube currents corresponding to different image noise values. A two-compartment model (2CM) model was formulated to describe the contrast kinematics in the kidney cortex. Three different 2CMs were implemented namely the 4-parameter (4P), 5-parameter (5P), and the 6-parameter (6P) model. The tissue kinematics is fitted to the models by using the Levenberg-Marquardt algorithm implemented in IDL (RSI Inc.) programming language to minimize the weighted sum of squares. The relevant tissue physiologic parameters extracted from the models are the renal blood flow (RBF), glomerular filtration rate (GFR), fractional plasma volume, fractional tubular volumes and urine formation rates. The experimental results indicate that the deviation of the tissue physiologic parameters is within the limits required for tracking disease physiology in vivo and thus small animal functional X-ray CT would be able to determine changes in tissue physiology in vivo.     

Liquid-Metal Synthesized Ultrathin SnS Layers for High-Performance Broadband Photodetectors

Atomically thin materials face an ongoing challenge of scalability, hampering practical deployment despite their fascinating properties. Tin monosulfide (SnS), a low-cost, naturally abundant layered material with a tunable bandgap, displays properties of superior carrier mobility and large absorption coefficient at atomic thicknesses, making it attractive for electronics and optoelectronics. However, the lack of successful synthesis techniques to prepare large-area and stoichiometric atomically thin SnS layers (mainly due to the strong interlayer interactions) has prevented exploration of these properties for versatile applications. Here, SnS layers are printed with thicknesses varying from a single unit cell (0.8 nm) to multiple stacked unit cells (≈1.8 nm) synthesized from metallic liquid tin, with lateral dimensions on the millimeter scale. It is reveal that these large-area SnS layers exhibit a broadband spectral response ranging from deep-ultraviolet (UV) to near-infrared (NIR) wavelengths (i.e., 280–850 nm) with fast photodetection capabilities. For single-unit-cell-thick layered SnS, the photodetectors show upto three orders of magnitude higher responsivity (927 A W⁻¹) than commercial photodetectors at a room-temperature operating wavelength of 660 nm. This study opens a new pathway to synthesize reproduceable nanosheets of large lateral sizes for broadband, high-performance photodetectors. It also provides important technological implications for scalable applications in integrated optoelectronic circuits, sensing, and biomedical imaging.     

Biological decolourization of C.I. Direct Black 38 by E. gallinarum

In the present study, an Enterococcus gallinarum strain was isolated from effluent treatment plant of a textile industry based on its ability to decolourize C.I. Direct Black 38 (DB38), a benzidine-based azo dye. Effects of dye concentration and medium composition on dye decolourization were studied. The strain was found to decolourize DB38 even under aerobic conditions. Kinetics of DB38 decolourization was also examined, and V(max) and K(s) of decolourization were found to be higher in Luria broth (12.8 mg l(-1)h(-1) and 490.6 mg l(-1)) than in minimal medium (4.09 mg l(-1)h(-1) and 161.84 mg l(-1)). However, decolourization rate/biomass was found to be higher in minimal medium than in Luria broth, indicating greater decolourization efficiency of biomass in the former. The study also revealed biodegradation of DB38 to benzidine and its further deamination to 4-aminobiphenyl (4-ABP) by the culture. Ammonia released during this process was used as nitrogen source for growth of the culture.