Grain size effects on the mechanical properties of some squeeze cast light alloys

Mechanical property-grain size relationships have been examined for squeeze cast Al-4.5% Cu alloy, for an aluminium alloy with a composition corresponding to wrought 7010, and for a magnesium alloy AZ91. The general trend of the results obtained showed that the tensile properties and the fatigue strength improved as grain size decreased and the reverse was found to be the case for the fatigue crack propagation resistance and fracture energy of these castings. However, the results also showed that no simple common relationship existed between grain size and the tensile properties of the different alloys. The results are discussed in respect of their microstructures.     

Design Rules for Reliability & Maintainability in Electronics

The automation of the design of electronics has advanced greatly since the middle 1970s. The state of this development is such that additional considerations are now being incorporated into the automation process. One of the essential elements of a successful electronics design is reaching the reliability and maintainability (R&M) potential that should be achieved in any design effort. The automation of portions of the design process to address R&M must be based upon design rules that are basic to producing a reliable and maintainable system. This paper discusses a framework for considering these R&M design rules and points the developers of computer-aided engineering systems in the direction that is necessary if electronics designs are to realize their potential.     

Finite element study of the effect of material properties on reaction forces produced by solitary wave propagation in granular chains

The response of a granular chain to impulse loading was investigated as a function of material properties. Using COMSOL Multiphysics, the elastic modulus and density of the grains were varied while the piston and force sensor properties remained fixed. The result of solitary wave propagation through the granular chain was recorded at the force sensor as a series of reaction force waves. It was found that wave velocity and amplitude increased with elastic modulus. Increasing density caused a decrease in wave velocity and an increase in amplitude. In addition, higher density granular chains exhibited a decrease in the number of waves in their respective reaction force wave trains. LS-DYNA was then used to explore the response of a variety of ceramic and metallic granular chains. Density, elastic modulus, and Poisson’s ratio were all set to representative values for the respective material. It was found that solitary wave development and decay occurred at different rates for different materials. In addition, the kinetic energy decay of the impactor was slower for glass compared with tungsten. Finally, it was shown that a single reaction force wave with no train could be produced by impacting a high density, high modulus chain such as tungsten with a glass piston, which has relatively low density and elastic modulus. Increasing impact velocity for this case resulted in a single high-amplitude wave with no train.     

Evaluation of a modified TCLP methodology for RCRA toxicity characterization of computer CPUs

A leaching method similar to the toxicity characteristic leaching procedure (TCLP) was designed and evaluated for testing of bulky wastes, such as discarded electronic devices. The objective was to meet the intent of the TCLP (same leaching solution, liquid-to-solid ratio and same leaching time) but to allow more representative and rapid testing. The procedure was evaluated by examining lead leaching from computer CPUs as a test case; disassembled CPUs were leached in their entirety (or close to entirety) in a large vessel using a drum rotator. The difference in rotation speed between the large-scale test and the TCLP was found to have no statistical impact on lead leaching. The lack of size reduction resulted in less reducing conditions than the standard TCLP (because of increased iron and zinc leaching), and this resulted in greater lead leaching. For electronic wastes with large amounts of steel, the large-scale procedure provides a more conservative estimate of TCLP lead leaching. The large-scale procedure greatly reduces sample processing effort but does increase the cost of analysis. Evaluation of this approach by the regulatory community is important as the CPUs tested here tended to leach lead at greater than the toxicity characteristic (TC) limit (5 mg/L) using the large-scale test, but less than the TC limit using the standard TCLP.     

RCRA toxicity characterization of discarded electronic devices

The potential for discarded electronic devices to be classified as toxicity characteristic (TC) hazardous waste under provisions of the Resource Conservation and Recovery Act (RCRA) using the toxicity characteristic leaching procedure (TCLP) was examined. The regulatory TCLP method and two modified TCLP methods (in which devices were disassembled and leached in or near entirety) were utilized. Lead was the only element found to leach at concentrations greater than its TC limit (5 mg/L). Thirteen different types of electronic devices were tested using either the standard TCLP or modified versions. Every device type leached lead above 5 mg/L in at least one test and most devices leached lead above the TC limit in a majority of cases. Smaller devices that contained larger amounts of plastic and smaller amounts of ferrous metal (e.g., cellular phones, remote controls) tended to leach lead above the TC limit at a greater frequency than devices with more ferrous metal (e.g., computer CPUs, printers).     

Assessment of the anaerobic degradation of six active pharmaceutical ingredients

Research examined the anaerobic degradation of 17α-ethynylestradiol, acetaminophen, acetylsalicylic acid, ibuprofen, metoprolol tartrate, and progesterone by methanogenic bacteria. Using direct sample analysis and respirometric testing, anaerobic degradation was examined with (a) each compound as the sole organic carbon source and (b) each compound at a lower concentration (250 µg/L) and cellulose serving as the primary organic carbon source. The change in pharmaceutical concentration was determined following 7, 28, 56, and 112 days of anaerobic incubation at 37 °C. Only acetylsalicylic acid demonstrated significant degradation; the remaining compounds showed a mixture of degradation and abiotic removal mechanisms. Experimental results were compared with BIOWIN, an anaerobic degradation prediction model of the US Environmental Protection Agency. The BIOWIN model predicted anaerobic biodegradability of the compounds in the order: acetylsalicylic acid > metoprolol tartrate > ibuprofen > acetaminophen > 17α-ethinylestradiol > progesterone. This corresponded well with the experimental findings which found degradability in the order: acetylsalicylic acid > metoprolol tartrate > acetaminophen > ibuprofen.     

YO!—a time-of-arrival receiver for removal of helicity-correlated beam effects

A parity violation experiment, G⁰, at Jefferson Lab is sensitive to arrival time differences, at the target, of electron beams in the two helicity states. Instead of the Jefferson Lab standard 499 MHz beam structure, G⁰ uses a 31.1875 MHz structure where only 1 out of 16 microbunches contains electrons. Photon counters triggered by time-of-arrival at the target mandate that timing must be independent of delays associated with different orbits taken by the electrons in two helicity states. Corrections to the parity violating asymmetries due to any arrival time differences require the generation of a clean 31.1875 MHz trigger signal and phase matching this signal to the beam's arrival at the target. The time of arrival receiver, named the YO! receiver, has 10 kHz output bandwidth which is sufficiently larger than the settling time (500 μs) of the ≈30 Hz helicity flip. This enables the correction of each helicity bin for any orbit-induced timing inequalities. The device combines conventional receiver and DSP techniques for maximum sensitivity, bandwidth and flexibility and eliminates the 2π/n phase shifts associated with frequency dividers by means of a sampling phase detection scheme. This paper describes the performance of this device during bench testing, commissioning and in data taking phase of the experiment.