Organic Semiconducting Luminophores for Near-Infrared Afterglow,Chemiluminescence, and Bioluminescence Imaging

Optical imaging has played a pivotal role in deciphering in vivo bioinformatics but is limited by shallow penetration depth and poor imaging performance owing to interfering tissue autofluorescence induced by concurrent photoexcitation. The emergence of near-infrared (NIR) self-luminescence imaging independent of real-time irradiation has timely addressed these problems. There are two main kinds of self-luminescent agents, namely inorganic and organic luminophores. Inorganic luminophores usually suffer from long-term biotoxicity concerns resulting from potential heavy-metal ions leakage and nonbiodegradability, which hinders their further translational application. In contrast, organic luminophores, especially organic semiconducting luminophores (OSLs) with good biodegradable potential, tunable design, and outstanding optical properties, are preferred in biological applications. This review summarizes the recent progress of OSLs used in NIR afterglow, chemiluminescence, and bioluminescence imaging. Molecular manipulation and nanoengineering approaches of OSLs are discussed, with emphasis on strategies that can extend the emission wavelength from visible to NIR range and amplify luminescence signals. This review concludes with a discussion of current challenges and possible solutions of OSLs in the self-luminescence field.     

Deacetylated Cellulose Acetate/Polyurethane Composite Nanofiber Membranes with Highly Efficient Oil/Water Separation and Excellent Mechanical Properties

Nowadays, oil pollution has become more serious, which causes great threats both to the ecological environment and human life. In this study, a novel type of multifunctional deacetylated cellulose acetate/polyurethane (d-M_CA:M_TPU) composite nanofiber membranes for oil/water separation are successfully fabricated by electrospinning, which show super-amphiphilicity in air, super-hydrophilicity in oil, and oleophobicity in water. All the d-M_CA:M_TPU composite nanofiber membranes with different mass ratios can be used as water-removing, oil-removing, and emulsion separation substance only by gravity driving force. The highest separation flux for water and oil reaches up to 37 000 and 74 000 L m⁻² h⁻¹, respectively, and all the separation efficiencies are more than 99%. They have outstanding comprehensive mechanics performance, which can be controlled by simply adjusting the mass ratios. They show excellent antifouling and self-cleaning ability, endowing powerful cyclic stability and reusability. Those results show that d-M_CA:M_TPU composite nanofiber membranes have great application prospects in oil/water separation.     

One-Dimensional Deep Convolutional Neural Network for Mineral Classification from Raman Spectroscopy

Neural Processing Letters - Raman spectroscopy is often used for the composition determination and rapid classification of materials because it can reflect the molecular information of materials....     

Fractional order battery modelling methodologies for electric vehicle applications: Recent advances and perspectives

Science China Technological Sciences - Accurate modelling of lithium ion batteries is crucial for battery management in electric vehicles. Recent studies have revealed the fractional order nature...     

济阳坳陷下古生界潜山油气藏特征及成藏模式

济阳坳陷下古生界潜山具有多样性、复杂性的特点，潜山差异性的形成演化、油气成藏主控因素和控藏模式不明确，严重制约了该区潜山油气勘探。在潜山分类的基础上，综合利用系统恢复、分类对比和典型解剖等方法，揭示了济阳坳陷下古生界不同类型潜山的形成演化过程和油气成藏主控因素差异性，分类建立了油气成藏模式。研究表明，济阳坳陷下古生界主要发育高位新盖侵蚀残丘潜山、中位古盖拉张断块潜山、中位新古盖拉张剪切断块潜山、中位中古盖挤压拉张断块潜山和低位古盖拉张滑脱断块潜山5种潜山类型。不同类型潜山的形成演化和油气成藏各具特色，其中，高位新盖侵蚀残丘潜山的发育受隆升、侵蚀作用控制，油气成藏主要受控于油源和盖层条件，表现为"单向供烃、砂体-不整合岩溶体联合输导、残丘控藏"的成藏模式；中位古盖拉张断块潜山的发育受掀斜、断裂作用控制，油气成藏主要受控于储集条件，表现为"单向供烃、顺向断层输导、反向断层控藏"的成藏模式；中位新古盖拉张剪切断块潜山的发育受反转、翘倾和走滑切割作用控制，油气成藏主要受控于输导条件，表现为"多源供烃、断溶体立体输导、断裂控藏"的成藏模式；中位中古盖挤压拉张断块潜山的形成受强烈挤压、拉张滑脱作用控制，油气成藏主要受控于储集条件，表现为"多源供烃、断缝体输导、断褶控藏"的成藏模式；低位古盖拉张滑脱断块潜山的形成受强烈拉张滑脱作用控制，油气成藏主要受控于输导条件，表现为"顶部供烃、断缝体输导、断裂控藏"的成藏模式。     

快速切换(SMED)在空调制造厂的研究与应用

在目前市场需求呈现规模扩张和品类个性化的冲击下,制造业面对的竞争压力愈发明显.且随着新时代自动化、信息化、大数据智能化等先进制造特征的兴起,更加促使制造业向转型升级不断进军.以空调制造业的控制器版块为例,从制约此单位效率的SMT车间切换浪费为切入点,在SMED快速换模的理念基础上,通过使用IE分析工具对切换流程进行研究,提炼出一套多模组固定料站切换模型,同时结合自动化、信息化等智能制造技术引进,完成SMT车间人力投入减少35人,日均产出点数提升18.29％,设备运行率提升15.46％,综合成本降低110.6万元/年的效益.成功推广应用至电子物料拣选版块,并开发信息化看板,夯实应用效益,再次证实"多模组固定料站"快速切换模型是典型小、多、高生产模式,具有可行性的解决方案.     

山东某难选贫磁铁矿石工艺矿物学研究

山东某难选贫磁铁矿石一直处于待开发状态。为了给矿石资源的开发利用提供依据，进行了系统的工艺矿物学研究。结果表明：①矿石中的主要有用矿物为磁铁矿，其次为假象赤铁矿和赤铁矿，含量分别为13.93%、5.65%和3.31%，褐铁矿分布较少为1.01%；主要脉石矿物为石英，其次为黑云母、碳酸盐类矿物和辉石，含量分别为39.12%、11.23%、7.78%和6.57%。②矿石主要构造为块状构造、层纹状构造，少量角砾状构造；主要结构有条带状结构、粒状结构，其次为脉状结构、交织结构，少量交代残余结构、辉绿结构、浸染状结构、斑状结构和纤维状结构。③矿石中有用铁矿物结晶粒度微细，主要分布在-0.04 mm粒级，其中磁铁矿（含假象赤铁矿）和赤、褐铁矿分布率分别为63.29%和72.50%，而-0.01 mm粒级分布率则占21.13%和29.16%，因此，欲使铁矿物与脉石达到较好解离，矿石必须细磨。