Description of the thermodynamic properties and fluid-phase behavior of aqueous solutions of linear,branched, and cyclic amines

The SAFT-γ Mie group-contribution equation of state is used to represent the fluid-phase behavior of aqueous solutions of a variety of linear, branched, and cyclic amines. New group interactions are developed in order to model the mixtures of interest, including the like and unlike interactions between alkyl primary, secondary, and tertiary amine groups (NH₂, NH, N), cyclic secondary and tertiary amine groups (cNH, cN), and cyclic methine-amine groups (cCHNH, cCHN) with water (H₂O). The group-interaction parameters are estimated from appropriate experimental thermodynamic data for pure amines and selected mixtures. By taking advantage of the group-contribution nature of the method, one can describe the fluid-phase behavior of mixtures of molecules comprising those groups over broad ranges of temperature, pressure, and composition. A number of aqueous solutions of amines are studied including linear, branched aliphatic, and cyclic amines. Liquid–liquid equilibria (LLE) bounded by lower critical solution temperatures (LCSTs) have been reported experimentally and are reproduced here with the SAFT-γ Mie approach. The main feature of the approach is the ability not only to represent accurately the experimental data employed in the parameter estimation, but also to predict the vapor–liquid, liquid–liquid, and vapor–liquid–liquid equilibria, and LCSTs with the same set of parameters. Pure compound and binary phase diagrams of diverse types of amines and their aqueous solutions are assessed in order to demonstrate the main features of the thermodynamic and fluid-phase behavior.     

Optimization of waste quail eggshells as biocomposites for polyaniline in ammonia gas detection

A simple, cost-effective, and novel chemical sensor for ammonia (NH₃) gas detection was developed from polyaniline (PANI)/quail eggshell (QES) composites. QES is a natural waste enriched in calcium carbonate. In this work, pure PANI was synthesized from chemical oxidation method and PANI/QES composites were prepared from physical mixing of QES with the synthesized PANI at different mass ratio. A series of complementary techniques including Fourier transform infrared and ultraviolet-visible spectrometers, scanning electron microscope with energy dispersive detection coupled with mapping, thermogravimetric analysis, and X-ray diffractometer were used to characterize the physicochemical and textural properties of the biocomposites. From the results, PANI/QES composite with a mass ratio of 1 exhibited the lowest NH₃ detection limit of 5.24 ppm with a linear correlation coefficient (R²) of close to unity (0.9932) between the signal and NH₃ gas concentration. As a whole, the PANI/QES biocomposites synthesized from this work exhibited excellent selectivity toward NH₃ gas even in the presence of other gas impurities, such as acetone, ethanol, and hexane. For the sensor reusability, the PANI/QES biocomposites can be reused in the application of NH₃ gas detection for at least 4 cycles.     

A New Variable Diffusion Drying Model for the Second Falling Rate Period of Paddy Dried in a Rapid Bin Dryer

The objectives of this article is to propose a new drying model for the second falling rate period known as the variable diffusion controlled period that follows after the first falling rate period and to propose a new method to determine the second critical moisture content that separates these two periods. Experimental work on paddy drying at minimum fluidization velocity was carried out in a rapid bin dryer. The effects of operating temperatures (60-120°C) and bed depths (2-6 cm) on the paddy drying characteristics were investigated. It was found that the normalized drying rate of paddy was proportional to the normalized moisture content in the first falling rate period but in the second falling rate period, the normalized drying rate of the material varies exponentially with the normalized moisture content. The different relationship between the normalized drying rate and the normalized moisture content in the first and second falling rate periods indicate that two different mechanism of moisture transport are at work. The new exponential model of the second falling rate period and the linear model of the first falling rate period were found to fit the experimental data very well. Derivation from variable diffusion equation shows that the linear model is the result of constant diffusion coefficient whereas the new exponential model is the result of linear diffusion coefficient. This also implies that the first falling rate period is a constant diffusion controlled period and the second falling rate period is a variable diffusion controlled period. In addition, drying kinetics data of a drying process that fits the exponential model over a very slow drying period will show that the drying process is under the effect of a linear diffusion coefficient. It was also found that the proposed new method to determine the second critical moisture content that distinguishes between the first and second falling rate periods by using a sudden change in the value of the drying rate gradient to a much lower value at that point is more rigorous and yet simpler than the method of determining the specific location of the receding drying boundary since it is based on the behavior of the actual drying kinetic data.     

新疆农产品质量安全发展现状与对策

农产品质量安全直接关系到消费者的生存、生活和健康,越来越受到人们的普遍关注.主要分析了新疆农产品质量安全发展现状,并有针对性地提出了发展对策,要完善农产品质量安全监督管理法规体系、加快农业标准体系建设、依法开展农产品质量安全检验检测等.     

An H∞non‐fragile observer‐based adaptive sliding mode controller design for uncertain fractional‐order nonlinear systems with time delay and input nonlinearity

In this paper the problem of non‐fragile adaptive sliding mode observer design is addressed for a class of nonlinear fractional‐order time‐delay systems with uncertainties, external disturbance, exogenous noise, and input nonlinearity. An H_∞ observer‐based adaptive sliding mode control considering the non‐fragility of the observer is proposed for this system. The sufficient asymptotic stability conditions are derived in the form of linear matrix inequalities. It is proven that the sliding surface is reachable in finite time. An illustrative example is provided which corroborates the effectiveness of the theoretical results.     

A NEW AGENT MATCHING SCHEME USING AN ORDERED FUZZY SIMILARITY MEASURE AND GAME THEORY

In this paper, an agent matching method for bilateral contracts in a multi-agent market is proposed. Each agent has a hierarchical representation of its trading commodity attributes by a tree structure of fuzzy attributes. Using this structure, the similarity between the trees of each pair of buyer and seller is computed using a new ordered fuzzy similarity algorithm. Then, using the concept of Stackelberg equilibrium in a leader–follower game, matchmaking is performed among the sellers and buyers. The fuzzy similarities of each agent with others in its personal viewpoint have been used as its payoffs in a bimatrix game. Through a case study for bilateral contracts of energy, the capabilities of the proposed agent-based system are illustrated.     

Model updating of multistory shear buildings for simultaneous identification of mass,stiffness and damping matrices using two different soft-computing methods

In this research, two novel methods for simultaneous identification of mass–damping–stiffness of shear buildings are proposed. The first method presents a procedure to estimate the natural frequencies, modal damping ratios, and modal shapes of shear buildings from their forced vibration responses. To estimate the coefficient matrices of a state-space model, an auto-regressive exogenous excitation (ARX) model cooperating with a neural network concept is employed. The modal parameters of the structure are then evaluated from the eigenparameters of the coefficient matrix of the model. Finally, modal parameters are used to identify the physical/structural (i.e., mass, damping, and stiffness) matrices of the structure. In the second method, a direct strategy of physical/structural identification is developed from the dynamic responses of the structure without any eigenvalue analysis or optimization processes that are usually necessary in inverse problems. This method modifies the governing equations of motion based on relative responses of consecutive stories such that the new set of equations can be implemented in a cluster of artificial neural networks. The number of neural networks is equal to the number of degree-of-freedom of the structure. It is shown the noise effects may partially be eliminated by using high-order finite impulse response (FIR) filters in both methods. Finally, the feasibility and accuracy of the presented model updating methods are examined through numerical studies on multistory shear buildings using the simulated records with various noise levels. The excellent agreement of the obtained results with those of the finite element models shows the feasibility of the proposed methods.     

Network Formation: Bilateral Contracting and Myopic Dynamics

We consider a network formation game where nodes wish to send traffic to each other. Nodes contract bilaterally with each other to form bidirectional communication links; once the network is formed, traffic is routed along shortest paths (if possible). Cost is incurred to a node from four sources: 1) routing traffic; 2) maintaining links to other nodes; 3) disconnection from destinations the node wishes to reach; and 4) payments made to other nodes. We assume that a network is stable if no single node wishes to unilaterally deviate, and no pair of nodes can profitably deviate together (a variation on the notion of pairwise stability). We study such a game under a form of myopic best response dynamics. In choosing their action, nodes optimize their single period payoff only. We characterize a simple set of assumptions under which these dynamics converge to a stable network; we also characterize an important special case, where the dynamics converge to a star centered at a node with minimum cost for routing traffic. In this sense, our dynamics naturally select an efficient equilibrium.     

An adaptive local binarization method for document images based on a novel thresholding method and dynamic windows

Binary image representation is essential format for document analysis. In general, different available binarization techniques are implemented for different types of binarization problems. The majority of binarization techniques are complex and are compounded from filters and existing operations. However, the few simple thresholding methods available cannot be applied to many binarization problems. In this paper, we propose a local binarization method based on a simple, novel thresholding method with dynamic and flexible windows. The proposed method is tested on selected samples called the DIBCO 2009 benchmark dataset using specialized evaluation techniques for binarization processes. To evaluate the performance of our proposed method, we compared it with the Niblack, Sauvola and NICK methods. The results of the experiments show that the proposed method adapts well to all types of binarization challenges, can deal with higher numbers of binarization problems and boosts the overall performance of the binarization.     

GENOTOXICITY IN CHIRONOMUS KIIENSIS (CHIRONOMIDAE: DIPTERA) AFTER EXPOSURE TO POLLUTED SEDIMENTS FROM RIVERS OF NORTH PENINSULAR MALAYSIA: IMPLICATION FOR ECOTOXICOLOGICAL MONITORING

Rapid industrialization and urbanization has led to increasing input of chemical contaminants into the aquatic environment of Malaysia. Despite the threat civilization poses to the biota, there are still very few relevant studies on ecotoxicological testing of river ecosystems. To overcome this knowledge gap, we examined lethal and genotoxic effects of sediments from different rivers of the northern Malaysia against Chironomus kiiensis, a group well represented in the aquatic fauna of this region. We exposed the larvae to sediments from Selama River (SR), Permatang Rawa River (PRR) and Kilang Ubi River (KUR) at various durations (0, 6, 12, 24 and 48 h). The larval mortality was monitored, whereas DNA damage in survivors' cells was determined using the comet assay. Pollution level indexed by the amounts of heavy metals and other organic contaminants in the sediment showed progressive increases from SR to PRR to KUR. Highly polluted sediments (PRR to KUR) were detrimental to C. kiiensis larvae, most of which did not survive following exposure for long periods. DNA analyses revealed greater damages in nuclei derived from larvae maintained on polluted sediments, in particular, those from KUR. The effects on the genomic material of C. kiiensis larvae occurred in a time‐dependent manner, with damage level increasing as exposure time progressed. Our results highlight the genotoxic properties of polluted sediments. More importantly, this study showed that C. kiiensis larvae could respond to different levels of pollution with respect to exposure time. It is concluded that C. kiiensis larvae is a potential candidate for river ecotoxicological monitoring. Copyright © 2012 John Wiley & Sons, Ltd.