Characterization of Thai limestone for desulphurization in a fluidized bed combustor

The objective of this study is to determine the chemical kinetics of desulphurization of Thai limestone in an atmospheric fluidized bed combustor (AFBC). The experiments, which employed the batch technique using the limestone samples from six major sources in Thailand, were performed in a laboratory‐scale AFBC. The results obtained were analysed and correlated in the form of apparent reaction rate and deactivation rate constants as a function of operating conditions of the furnace and their properties, respectively. The formulae derived from these correlations were kept as general as possible in order that they could be used as input parameters for the selected mathematical model of desulphurization in an AFBC that is suitable for practical use. The predicted results were in good agreement with the experimental data reported in the literature. Copyright © 2003 John Wiley & Sons, Ltd.     

A fast tag identification anti‐collision algorithm for RFID systems

In this work, we propose a highly efficient binary tree‐based anti‐collision algorithm for radio frequency identification (RFID) tag identification. The proposed binary splitting modified dynamic tree (BS‐MDT) algorithm employs a binary splitting tree to achieve accurate tag estimation and a modified dynamic tree algorithm for rapid tag identification. We mathematically evaluate the performance of the BS‐MDT algorithm in terms of the system efficiency and the time system efficiency based on the ISO/IEC 18000‐6 Type B standard. The derived mathematical model is validated using computer simulations. Numerical results show that the proposed BS‐MDT algorithm can provide the system efficiency of 46% and time system efficiency of 74%, outperforming all other well‐performed algorithms.     

A prediction of defluidization time in biomass fired fluidized bed combustion

Two mathematical models to describe the complete defluidization time in biomass FBC were presented in this study; one was newly developed and another was a modified model. They considered the effects of the chemical properties of fuel ash and bed operating conditions such as air velocity, bed particle size and static bed height. The model formulations employed the approach of force balance, defining the viscous flow sintering and the gas bubble behaviors to evaluate the adhesive and segregated forces, respectively. The models were achieved by the statistical regression analyzes with the early laboratory scale experimental results and then verified by the pilot scale experimental results and previous published data. The regression analyzes revealed that the inorganic composition of ash in the fuel and temperature were most significant. In addition, the fluidizing velocity showed a strong effect among the observed operating variables. The model predictive results followed the lab scale data with the error range of ±22% and ±35% and provided fairly well predictability with the pilot scale and published data of previous bed agglomeration tests, carried out with several kinds of biomass fuels.     

Heat transfer in a crater bed

The aim of this work is to study heat transfer in a laboratory scale crater bed, which was set up from a cylindrical acrylic/quartz tube, using sand as the bed particle. The bed employs a downward gas jet from a nozzle which causes the particles to ascend fountain-like into the freebroad, leaving a crater on the bed surface. After reaching a certain height, these particles will descend again to the bed surface and move into the crater, where the cycle or circulation pattern starts again. The study had been separated into three parts. Firstly, the void fraction of the bed fountain zone was studied by direct measurement of the ascending sand weight within the specific volume. Secondly, the convection heat transfer coefficients between the fountain zone and the external surface of the gas inlet tube were determined by measuring the quantity of heat loss from an electrical heater that was wrapped on the outside surface at desired positions of the gas inlet tube. Thirdly, the radiation heat transfer coefficients were evaluated by heat balance of LPG combustion in the crater bed. From experimental results, the void fraction of the fountain zone could be approximated as a dilute bed (>0.98). For convective heat transfer coefficients, the value found experimentally varied from 80–260 W/m² K depending on the experimental conditions, showing an increase when the gas velocity increases, and a decrease along the height of the gas inlet tube. Radiation heat transfer coefficients, the values of which are (within the experimental temperature range), the same order as the convective mode, increase when the bed temperature is increased and when the bed particle diameter is decreased. Empirical correlations for both bed voidage and heat transfer coefficients are proposed. The combined model, gas and particle convection and the published data on radiation heat transfer, showed good prediction when compared with experimental data.     

Fouling behavior of coconut milk at pasteurization temperatures

Fouling by coconut milk at different heating temperatures (50–54.5 °C, 60–64.5 °C, and 70–74.5 °C) and at three volumetric flows (2,4 and 6 LPM) in a test section equipped with four flat plates was studied. Measurement of the overall heat transfer coefficient (U) and the compositions of deposit mass were completed in order to obtain fouling factors (R_f) and an empirical model for the rate of increase of Biot number (?Bi/?t) as a function of the temperature (T) and the flow (F). The results illustrated that the fouling factor increased, when the temperature fell due to a combination of chemical reaction fouling from proteins and precipitation fouling from fat. The fouling factor also increased, when the flow was lowered due to a slow rate of deposit removal introduced by small shear force. Combination of the two effects revealed that the effect of flow was less significant at higher temperatures. All results can be confirmed by an analysis of fouling compositions. At high temperature conditions, more denaturation of proteins resulted in less ability to entrap fat globules onto heating surface. The heat resistance was found decreasing with increasing temperature.     

Modeling of soil temperature and moisture with and without rice husks in an agriculture greenhouse

An agricultural greenhouse with natural ventilation in Thailand has to deal with high temperature. This problem shows the necessity of having a tool capable of predicting soil temperature and moisture in the greenhouse using the statistical data from the meteorological station. Rice husks were used to cover soil in the greenhouse to reduce soil temperature and maintain soil moisture. Soil temperature and moisture with and without rice husks were compared. The model that would justify and be capable of simulating the complexity of the temperature and moisture of a greenhouse was developed and validated again using experimental data.     

Effect of kaolin addition on ash characteristics of palm empty fruit bunch (EFB) upon combustion

Palm empty fruit bunch (EFB), a by-product of the palm oil industry, is being recognized as one of the most potential kinds of biomass for energy production in Thailand. However, it has been reported that, in combusting EFB in boilers, some compounds evolving from abundant alkali metals in EFB into gas-phase condense and deposit on low-temperature surfaces of heat exchange equipment, causing fouling and corrosion problems. To come up with a solution to impede the deposition, kaolin, which is abundant in kaolinite (Al₂Si₂O₅(OH)₄), is employed to capture the alkali metal vapours eluding from the combustion region. The experiments were designed to simulate the combustion situations that may take place when kaolin is utilized in two different approaches: premixing of kaolin with EFB prior to combustion and gas-phase reaction of volatiles from EFB with kaolin. The amounts of kaolin used were 8% and 16% by weight based on dry weight of EFB, which were equivalent to one and two times of the theoretical kaolin requirement to capture all potassium originally present in the EFB. The furnace temperatures used for EFB combustion were 700–900 °C and ashes were analyzed by XRF and XRD. The results revealed that, under the kaolin premixing condition, 8% kaolin addition was sufficient to capture the potassium compounds at low temperature, i.e. 700 and 800 °C. However, when the temperature was increased to 900 °C, 16% kaolin addition was needed to completely capture the potassium compounds. The results from gas-phase experiments showed that kaolin can capture volatile potassium at maximum 25% at 900 °C. The XRD results showed, for both experimental cases, the evidence of formation of the high melting temperature potassium-alumino-silicates, which confirmed the reaction of potassium compounds with kaolin. The study also suggests that the premixing method is better than the other because of its higher overall capture efficiency.     

Radiation cross-linking of small electrical wire insulator fabricated from NR/LDPE blends

A low voltage, radiation-crosslinked wire insulator has been fabricated from blends of natural rubber block (STR-5L) and LDPE with phthalic anhydride (PA) as a compatibilizer. Physical properties of the NR/LDPE blend ratios of 50/50 and 60/40 with 0.5, 1.0, and 1.5 wt% PA were evaluated. The gel content increased as the radiation dose increased. Tensile at break exhibited a maximum value of 12 MPa at 120 kGy for 1.0 and 1.5 wt% PA of both blend ratios. A higher PA content yielded a higher modulus for the same blend ratio. Blends of 60/40 ratio with 1.0 wt% PA and 0.8 wt% antimony oxide flame retardant gave the highest limiting oxygen index (LOI) of >30% at above 150 kGy. Other electrical properties of the wire insulator were investigated. It was found that an insulator fabricated from a PA content of 1.0 wt% in the NR/LDPE blend ratio of 50/50, after gamma ray cross-linked at a dose of 180 kGy in low vacuum (1 mm Hg), met the Thai Industrial Standard 11-2531 for low voltage wire below 1.0 kV. To comply with the standard for vertical flame test, a more suitable flame retardant was needed for the insulator.