全文获取类型
收费全文 | 16609篇 |
免费 | 1514篇 |
国内免费 | 760篇 |
专业分类
电工技术 | 1069篇 |
技术理论 | 1篇 |
综合类 | 906篇 |
化学工业 | 2812篇 |
金属工艺 | 866篇 |
机械仪表 | 1105篇 |
建筑科学 | 1317篇 |
矿业工程 | 405篇 |
能源动力 | 502篇 |
轻工业 | 1026篇 |
水利工程 | 264篇 |
石油天然气 | 1091篇 |
武器工业 | 124篇 |
无线电 | 2151篇 |
一般工业技术 | 2105篇 |
冶金工业 | 796篇 |
原子能技术 | 129篇 |
自动化技术 | 2214篇 |
出版年
2024年 | 55篇 |
2023年 | 324篇 |
2022年 | 501篇 |
2021年 | 838篇 |
2020年 | 537篇 |
2019年 | 462篇 |
2018年 | 482篇 |
2017年 | 564篇 |
2016年 | 481篇 |
2015年 | 665篇 |
2014年 | 877篇 |
2013年 | 1023篇 |
2012年 | 1000篇 |
2011年 | 1215篇 |
2010年 | 987篇 |
2009年 | 900篇 |
2008年 | 940篇 |
2007年 | 851篇 |
2006年 | 916篇 |
2005年 | 797篇 |
2004年 | 530篇 |
2003年 | 435篇 |
2002年 | 385篇 |
2001年 | 330篇 |
2000年 | 356篇 |
1999年 | 479篇 |
1998年 | 412篇 |
1997年 | 308篇 |
1996年 | 276篇 |
1995年 | 205篇 |
1994年 | 196篇 |
1993年 | 126篇 |
1992年 | 108篇 |
1991年 | 76篇 |
1990年 | 59篇 |
1989年 | 37篇 |
1988年 | 32篇 |
1987年 | 11篇 |
1986年 | 22篇 |
1985年 | 5篇 |
1984年 | 12篇 |
1983年 | 8篇 |
1982年 | 16篇 |
1981年 | 12篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1977年 | 4篇 |
1976年 | 5篇 |
1975年 | 3篇 |
1959年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 218 毫秒
1.
Kedong Xia Shuoshuo Yu Yunling Li Huijuan Han Lingyao Duan Zhenyu Hou Xiao Liu 《Journal of the European Ceramic Society》2021,41(4):2375-2385
In this study, C/SiOC and C/SiO2 composites were prepared by using carbonaceous microspheres with different surface functional groups. Carbonaceous microspheres based on hydrothermal reaction of glucose contains hydroxyl group, while the surface carboxyl group increases after NaOH etching. The hydroxyl group increases the oxygen-enriched structural units of SiOC ceramics, and the C spheres are closely enwrapped in SiOC matrix after pyrolysis at 900 °C. However, the interfacial reaction of surface carboxyl with Si–OH results in the formation of cristobalite SiO2, and C spheres are not only encased inside the SiOC matrix, but also dispersed outside of SiOC ceramics. After removal of C via calcination at 500 °C for 5 h, C/SiOC and C/SiO2 composites are transformed into amorphous SiO2 and cristobalite SiO2, respectively. The thermogravimetric analysis indicates the oxidation resistance of SiOC is superior to that of C and SiO2. 相似文献
2.
目的:鉴定中国白酒发酵过程中的微生物种类,研究关键酶的特征与作用机制有利于提高白酒的优质品率。方法:本研究用形态学和生理学、16S rRNA、gyr B基因和antiSMASH分析的方法对酒曲中的一株微生物进行了验证;对该菌株的特性进行了研究,采用分子建模的方法获得了羧酸酯酶的3D模型,用分子对接的方法探讨了该菌株的羧酸酯酶的机理。结果:该菌株为产羧酸酯酶的革兰氏阴性菌Pb1(MW580690);该菌株呈现典型的S型生长曲线,产物曲线为S型,羧酸酯酶活化最优pH范围为5.0~9.0。分子对接结果显示Phe21A为该酶具有催化活性的主要氨基酸,水解三丁酸甘油酯为丁酸和甘油。分子对接结果显示三丁酸甘油酯经过构象变化被转移到催化中心后,进一步被加工;酶的亲水性和疏水性的相互作用表面有利于配体向下转移,进而从疏水性通道释放产物到的酶表面。结论:产羧酸酯酶的菌株为贝莱斯芽胞杆菌,并为羧酸酯酶水解三丁酸甘油酯类物质的底物识别、转移和催化机理提供了新的见解。 相似文献
3.
ABSTRACT In this study, effect of calcium and gypsum on scheelite and fluorite was investigated using sodium oleate as collector. Micro-flotation and contact angle results showed that the adsorption of calcium could inhibit the hydrophobicity of scheelite and fluorite. Moreover, sulfate could enhance the inhibition. FT-IR results showed that calcium could be priori precipitated into calcium oleate and adsorb on mineral surface. The adsorption of calcium could increase the scheelite potential to IEP, while it showed limited effect on fluorite potential. However, the interaction of calcium on scheelite and fluorite in gypsum solution was more complex than that in calcium solution. 相似文献
4.
Qi Yang Qilong Wu Yang Liu Shuiping Luo Xiaotong Wu Xixia Zhao Haiyuan Zou Baihua Long Wen Chen Yujia Liao Lanxi Li Pei Kang Shen Lele Duan Zewei Quan 《Advanced materials (Deerfield Beach, Fla.)》2020,32(36):2002822
Engineering novel Sn-based bimetallic materials could provide intriguing catalytic properties to boost the electrochemical CO2 reduction. Herein, the first synthesis of homogeneous Sn1−xBix alloy nanoparticles (x up to 0.20) with native Bi-doped amorphous SnOx shells for efficient CO2 reduction is reported. The Bi-SnOx nanoshells boost the production of formate with high Faradaic efficiencies (>90%) over a wide potential window (−0.67 to −0.92 V vs RHE) with low overpotentials, outperforming current tin oxide catalysts. The state-of-the-art Bi-SnOx nanoshells derived from Sn0.80Bi0.20 alloy nanoparticles exhibit a great partial current density of 74.6 mA cm−2 and high Faradaic efficiency of 95.8%. The detailed electrocatalytic analyses and corresponding density functional theory calculations simultaneously reveal that the incorporation of Bi atoms into Sn species facilitates formate production by suppressing the formation of H2 and CO. 相似文献
6.
7.
8.
Nitrile rubber (NBR) blends with excellent performance have always been a hot research topic in petroleum field. Due to the excellent performance and compatibility of polyamide 6 (PA6), it provides an opportunity for the preparation of high-performance NBR/PA6 blends. In this article, NBR/PA6 blends were prepared by the three-step molding process. Experimentally, it was found that PA6 has a prominent reinforcement effect in NBR matrix. The variation of this mechanical property was investigated from different aspects of the crystal structure, crystallinities, phase morphology, and so on. It can be cleared that the formation of fibrous structure of PA6 phase is the main factor for reinforcement of the polymer blends. Meanwhile, the formation mechanism of the special phase structure induced by the three-step process is deeply expounded and its structural evolution schematic is established. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47472. 相似文献
9.
Mineralization of Para-Chlorobenzoic Acid in Water by Cobalt-Incorporated MCM-41 Catalyzed Ozonation
Cobalt-incorporated MCM-41(Co-MCM-41) was used as a heterogeneous catalyst for the ozonation of para-chlorobenzoic acid (p-CBA) in aqueous solution. Cobalt oxide supported on MCM-41(Co/MCM-41) was synthesized for comparison. Their textural properties were elucidated by various characterization techniques to understand the relationship between surface texture and catalytic activity. TOC removal at 60 min reached 91% with Co-MCM-41, 83% with Co/MCM-41 and only 52% with ozone alone, respectively. Observations from diffuse reflection spectroscopy demonstrated that different metal phases were formed in these cobalt-modified molecular sieves samples. Radical scavenger experiments indicated the formation of hydroxyl radicals that were responsible for the effective degradation of p-CBA. An integrated approach to the catalytic mechanism was proposed by considering the variation of pH in the course of ozonation as well as its subsequent influence on the dissociation of targeted compounds and surface charge of the catalyst. In the reusability experiments, the reused Co-MCM-41 was able to regain the same catalytic capability as the fresh one within 5 cycles. X-ray photoelectron spectroscopy results indicated that a part of Co2+ was oxidized to Co3+ after oxidation reaction. 相似文献
10.
微型步进马达线圈组卷线上下料基本靠手动作业,效率低下,同时因工人技术水平的不同造成产品品质不稳定的问题多发.为此专门设计了微型步进马达线圈组自动卷线及上下料设备.通过结合现阶段的先进工业技术,采用振动盘分离区分进料,多机构并联三菱PLC及威纶人机界面触摸屏研发了此微型步进马达线圈组自动上下料及卷线设备.通过该设备实现了微型步进马达因工人不足导致产能减少和品质多发问题,减少企业成本,提升产品品质. 相似文献