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Two kinds of CACs with different monocalcium aluminate(CA) contents were used in the PC/CAC(PAC) mixtures. Effects of CA and CACs on the properties of PAC were analyzed by setting times and the compressive strength tests, and also by means of calorimetry, XRD, DTA-TG and ESEM. The experimental results show that the compressive strength of the PAC mortars decreases with increasing content of CAC while it declines sharply with a higher content of CA in CAC. Compared with neat PC paste, the content of calcium hydroxide in hydrates of PAC paste decreases significantly, and the hydration time of PC is prominently prolonged. Additionally, the higher the content of CA in CAC, the more obviously the hydration of PC is delayed, confi rming that the CA phase in CAC plays an important role in the delay of PC hydration. 相似文献
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通过对比分别用萘系减水剂和Glenium〇R 6000 SDC系列聚羧酸减水剂配制的自密实混凝土的电通量和碳化深度,探讨两种减水剂对混凝土耐久性影响的差异。结果表明,采用Gle-nium〇R 6000SDC系列聚羧酸减水剂时,混凝土的抗氯离子渗透性和抗碳化性能比掺萘系减水剂时更优良;且当Glenium〇R 6000 SDC系列聚羧酸减水剂掺量增加,混凝土达到自密实状态时,早期强度虽略有降低,但抗碳化性能大幅提升。 相似文献
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通过对比4种铝酸盐水泥(CAC)常见水化产物CAH_(10)、C_(2)AH_(8)、C_(3)AH_(6)、NO_(3)-AFm与氯离子充分结合所得Fs样品在高温和碳化前后的氯离子结合量、浸泡液pH值、物相组成及微观形貌等,研究了温度和碳化作用对CAC水化产物与氯离子结合稳定性的影响.结果表明:高温仅影响CAC水化产物物理吸附氯离子的稳定性,对化学结合稳定性基本无影响;碳化作用导致Friedel's盐溶解,生成以方解石为主的CaCO_(3),使浆体中的自由氯离子浓度增加;相比之下,CAH_(10)、C_(2)AH_(8)与氯离子结合后的Fs样品抗碳化能力较好. 相似文献