Annealing effects on structural and electrical properties of fluorinated amorphous carbon films deposited by plasma enhanced chemical vapor deposition

The annealing effects on the structural and electrical properties of fluorinated amorphous carbon (a-C:F) thin films prepared from C₆F₆ and Ar plasma are investigated in a N₂ environment at 200 mTorr. The a-C:F films deposited at room temperature are thermally stable up to 250 °C, but as the annealing temperature is increased beyond 300 °C, the fluorine incorporation in the film is reduced, and the degree of crosslinking and graphitization in the film appears to be enhanced. At the annealing temperature of 250 °C, the chemical bond structures of the film are unchanged noticeably, but the interface trapped charges between the film and the silicon substrate are reduced significantly. The increased annealing temperature contributes the decrease of both the interface charges and the effective charge density in the a-C:F film. Higher self-bias voltage is shown to reduce the charge density in the film.     

Effect of the addition of Fe2O3 and heat treatment duration on the magnetic susceptibility of V2O5-P2O5-B2O3 glass system

The effect of the addition of Fe₂O₃ and heat treatment duration on the magnetic susceptibility of vanadium borophosphate glass were studied. The magnetic susceptibility of glass samples was found to increase with increasing Fe₂O₃ content, which may be explained by the formation of the FeO₆ group and the change of Fe²⁺ to Fe³⁺ which has higher paramagnetic properties. No detectable changes in the magnetic susceptibility with heat treatment for the samples containing 0.0, 0.5 and 1.0 mol% Fe₂O₃ was observed. The magnetic susceptibility for the heat treated samples containing 2.5, 5.0 and 7.5 mol% Fe₂O₃ decreases sharply with increasing duration of heat treatment up to 6 h and then remains almost constant. The sharp decrease in magnetic susceptibility of 2.5 mol% Fe₂O₃ is attributed to the increase in the number of ferrous ions. The sharp decrease for samples containing 5.0 and 7.5 mol% Fe₂O₃ is attributed to the increase in the number of Fe³⁺ in tetrahedral co-ordination. The rate of crystallization owing to the heat treatment was calculated and was found to increase with increasing iron oxide content. The geometry of crystallization was found to be in three-, two-and one-dimension(s) for samples containing 2.5, 5.0 and 7.5 mol% Fe₂O₃, respectively.     

A meta-modelling framework for knowledge consistency in collaborative design

The design of complex system requires a lot of interactions between experts and then between numerous Computer Aided X software (CAX) (where X can be Design (CAD), Engineering (CAE), Manufacturing (CAM), etc.). In order to improve the consistency of the whole system design and the related data and information, knowledge crossing the expertises must be tracked and formalized regarding a shared reference. That means that instead of defining a large reference models to which each expert refers to, a light collaborative model is defined enabling to connect data from each expert model to adhoc data from other expert models, following the least commitment principle. In this topic, a new meta-model is proposed in a Model-Driven Engineering approach to manage the integration of heterogeneous experts’ knowledge models in a collaborative process. The structure of the proposed knowledge meta-model is defined taking into account the complexity of knowledge definition and the properties of its components. This meta-model is split in a meta-model of data on one hand and a Collaboration Meta-Model in the other hand, to represent the distinction between the core concepts of knowledge and additional elements serving to represent the relation between these concepts, and between concepts of heterogeneous experts’ models. The proposed meta-model is illustrated on an industrial case study to highlight the way to put it in use, and its interests to enable collaboration between experts throughout the design process.     

Effect of SiO2 Addition on Chromium Transitions in Borate Glasses

Silicon - Melt-quenching technique was used to prepare borosilicate glasses of composition xSiO2- (75-x) B2O3–24.7Li2O-0.3Cr2O3 (x = 0, 10, 20, 30, 40 and 50 mol%). With...     

Thermal decomposition and pore structure of pure and doped stannic oxide gel

The surface properties of a stannic oxide gel and its thermal dehydration products obtained both in vacuo and in the presence of air in the temperature range 100–600°C have been examined by N₂ adsorption. Phase and structural changes have been followed by differential thermal analysis and X-ray diffractometry. Complete pore structure analysis showed that samples dehydrated at or below 250°C were microporous. Above 250°C the pores were found to widen with increase of temperature, the widening occurring concurrently with the crystallisation process. Doping with cations of lower valency (Li⁺ and Al³⁺) than the host cation (Sn⁴⁺) had little effect on the pore structure and specific surface area for the low temperature samples (≤250°), whereas at higher temperatures, e.g. 600°C, it increased the specific area remarkably. The dope ions produce oxygen vacancies and hinder or retard sintering in SnO₂.     

Bio-based sustainable films from the Algerian Opuntia ficus-indica cladodes powder: Effect of plasticizer content

The present study investigated the fabrication and characterization of bio-based sustainable films composed of a terrestrial plant raw material, namely Opuntia ficus-indica (OFI) cladodes powder (CP) and a marine seaweed derivative, namely agar (A). The effect of glycerol concentration on the properties of the casted films was evaluated at four different contents, namely 30, 40, 50 and 60 wt%. The films present UV-blocking properties, as well as moderate mechanical performance, thermal stability, and water vapor transmission rate (WVTR). The results point to an increase in thickness, elongation at break, moisture content, water solubility, and WVTR with increasing glycerol content. On the contrary, Young's modulus, tensile strength, and water contact angle decreased as glycerol concentration increased. The best combination is obtained for the film with 30% glycerol, based on an intermediate compromise between physical, mechanical, thermal, and barrier properties. All these outcomes express the potentiality of the powder obtained from grinding the OFI cladodes as raw material to produce low-cost films for the development of sustainable packaging materials.     

A branch-and-bound algorithm to minimize total weighted completion time on identical parallel machines with job release dates

In this paper, we consider an identical parallel machine scheduling problem with release dates. The objective is to minimize the total weighted completion time. This problem is known to be strongly NP-hard. We propose some dominance properties and two lower bounds. We also present an efficient heuristic. A branch-and-bound algorithm, in which the heuristic, the lower bounds and the dominance properties are incorporated, is proposed and tested on a large set of randomly generated instances.     

An effective scheduling scheme for multi-hop multicast in wireless mesh networks

With the utilization of concurrent transmission strategy, a throughput-enhanced scheduling scheme is devised for multicast service in wireless multi-hop mesh networks. Since the performance of a multicast mechanism is constrained in a wireless setting due to the interference among local wireless transmissions, the interference relationships are first characterized by introducing a graph transformation method. Based on the graph transformation, the multicast scheduling problem is converted to the graph coloring problem, and then a capacity greedy algorithm is designed to provide concurrent transmission scheduling so that the demanded multicast transmission rate can be achieved. Moreover, the necessary and sufficient conditions of multicast schedulable feasibility are derived. Through corresponding simulations, it is shown that the proposed strategy can enhance the throughput of wireless multi-hop multicast systems significantly.     

On the application of quantum clustering on speech data

In this work, Quantum clustering (QC) algorithm is applied to a labeled dataset of Arabic vowels. The accuracy and processing time are, then, compared with nonhierarchical kernel approaches for unsupervised clustering; namely, k-means, self-organizing map and fuzzy c-means. The choice of speech data is according to large database statistics which reveal that vowels class represents about 60–70% of Arabic speech whereas the remaining percentage is distributed among other sounds. The analysis features, in this work, are the mel-frequency cepstarl coefficients. The results show that all algorithms are competitive from accuracy point of view while QC still guarantees the solution stability.     

Metaheuristics and exact methods to solve a multiobjective parallel machines scheduling problem

This paper deals with a multiobjective parallel machines scheduling problem. It consists in scheduling n independent jobs on m identical parallel machines. The job data such as processing times, release dates, due dates and sequence dependent setup times are considered. The goal is to optimize two different objectives: the makespan and the total tardiness. A mixed integer linear program is proposed to model the studied problem. As this problem is NP-hard in the strong sense, a metaheuristic method which is the second version of the non dominated sorting genetic algorithm (NSGA-II) is proposed to solve this problem. Since the parameters setting of a genetic algorithm is difficult, a fuzzy logic controller coupled with the NSGA-II (FLC-NSGA-II) is therefore proposed. The role of the fuzzy logic is to better set the crossover and the mutation probabilities in order to update the search ability. After that, an exact method based on the two phase method is also developed. We have used four measuring criteria to compare these methods. The experimental results show the advantages and the efficiency of FLC-NSGA-II.