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1.
The influence of demineralisation and ammoxidation on the adsorption properties of an activated carbon prepared from a Polish lignite 总被引:1,自引:0,他引:1
Julien Starck Sebastien Muller Guy Furdin Cathie Vix_Guterl Pierre Faure 《Carbon》2006,44(12):2549-2557
The preparation of cheap nitrogen-enriched materials with large adsorptive capacities and selectivity towards volatile organic compounds remains a challenge. Ammoxidation has been used to prepare nitrogen-enriched activated carbons using a demineralised Polish lignite. The lignite samples were demineralised by two different methods before nitrogen-enrichment by ammoxidation and physical activation in steam. The surface chemistry was investigated by elemental analysis, Boehm titration, infrared and XPS spectroscopies and adsorptive properties by a linear solvation energy relationship approach. Results show a quasi-total demineralisation and a higher reactivity towards nitrogen for the demineralised samples. The BET surface is also higher than for the non-demineralised lignite. Active carbons previously ammoxidated and demineralised are more interesting in terms of selective removal of gaseous pollutants. 相似文献
2.
Placement of Substrate Contacts to Minimize Substrate Noise in Mixed-Signal Integrated Circuits 总被引:1,自引:0,他引:1
Radu M. Secareanu Scott Warner Scott Seabridge Cathie Burke Thomas E. Watrobski Christopher Morton William Staub Thomas Tellier Eby G. Friedman 《Analog Integrated Circuits and Signal Processing》2001,28(3):253-264
The placement of substrate contacts in epi and non-epi technologies is analyzed in order to control and reduce the substrate noise amplitude and spreading. The choice of small or large substrate contacts or rings for each of the two major technologies is highlighted. Design guidelines for placing substrate contacts so as to improve the noise immunity of digital circuits in mixed-signal smart-power systems are also presented. 相似文献
3.
Willem G.J. Langeveld Cathie CondronMashal Elsalim Mike Ingle 《Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment》2011,652(1):79-83
We introduce Noise Spectroscopy (NS) and show the results of an analysis of three data-sets demonstrating the feasibility of this technique. The NS effect is first shown to be present in a set of X-ray radiography images of low- and high-Z materials taken using the 6 MV Rapiscan Eagle P60HP portal cargo inspection system. Image-Based NS is, however, relatively insensitive. Using a data-set obtained using a fast plastic scintillator and photo-multiplier tube (PMT), we demonstrate that NS works very well when using fast detectors, fast electronics and waveform digitization. Another data-set was taken using Lutetium-Yttrium Ortho-Silicate (LYSO), which is suitable for use in X-ray cargo radiography. Although LYSO is slower than plastic scintillator, it was shown that NS also works very well using this material, paving the way for NS to be implemented using the primary imaging array of X-ray cargo inspection systems. 相似文献
4.
A new direct formulation of the boundary element method based on the initial stress approach has been developed which is more generally applicable than existing formulations. A complete scheme of numerical calculations is presented and it has been demonstrated that the method can be used for routine analysis of engineering plasticity problems. 相似文献
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W.P.Cathie Lee Lling-Lling Tan S. Sumathi Siang-Piao Chai 《International Journal of Hydrogen Energy》2018,43(2):748-756
A facile synthesis approach to fabricate Cu-doped MoS2/Bi2S3 (Cu-MoS2/Bi2S3) photocatalysts is reported. The photocatalyst samples with varying amounts of Cu are applied in the photocatalytic splitting of water to produce H2 under the irradiation of simulated solar light. The Cu-MoS2/Bi2S3 photocatalysts with an optimum Cu loading of 20 mol% exhibited high photocatalytic performance, achieving a total H2 yield of 32.4 μmol/h after 6 h of reaction. The photoactivity of the Cu-doped sample was shown to have risen more than 40% than that of pure MoS2/Bi2S3. The improved performance is attributed to the impurity states generated within Cu-doped MoS2, which serve as trapping sites for photogenerated electrons. The effective charge transfer mechanism achieved was evidenced by photoelectrochemical measurements. Based on the experimental results obtained, a plausible mechanism for the photocatalytic process associated with Cu-MoS2/Bi2S3 was proposed. 相似文献
7.
Yang LM Tam PY Murray BJ McIntire TM Overstreet CM Weiss GA Penner RM 《Analytical chemistry》2006,78(10):3265-3270
A dense virus layer, readily tailored for recognition of essentially any biomarker, was covalently attached to a gold electrode surface through a self-assembled monolayer. The resistance of this "virus electrode", Z(Re), measured in the frequency range from 2 to 500 kHz in a salt-based pH 7.2 buffer, increased when the phage particles selectively bound either an antibody or prostate-specific membrane antigen (PSMA), a biomarker for prostate cancer. In contrast to prior results, we show the capacitive impedence of the virus electrode, Z(Im), is both a noisier and a less sensitive indicator of this binding compared to Z(Re). The specificity of antibody and PSMA binding, and the absence of nonspecific binding to the virus electrode, was confirmed using quartz crystal microbalance gravimetry. 相似文献
8.
Philippe Dibandjo Claudia Zlotea Roger Gadiou Camelia Matei Ghimbeu Fermin Cuevas Michel Latroche Eric Leroy Cathie Vix-Guterl 《International Journal of Hydrogen Energy》2013
Hydrogen adsorption on porous materials is one of the possible methods proposed for hydrogen storage for transport applications. One way for increasing adsorption at room temperature is the inclusion of metal nanoparticles to increase hydrogen–surface interactions. In this study, ordered mesoporous carbon materials were synthesized by replication of nanostructured mesoporous SBA-15 silica. The combination of different carbon precursors allowed to tailor the textural, structural and chemical properties of the materials. These carbons were used for the synthesis of hybrid nanostructured carbon/palladium materials with different sizes of metal nanoparticles. The hydrogen sorption isotherms were measured at 77 K and 298 K between 0.1 and 8 MPa. Hydrogen storage capacities strongly correlate with the textural properties of the carbon at 77 K. At room temperature, Pd nanoparticles enhance hydrogen storage capacity by reversible formation of hydride PdHx and through the spillover mechanism. The hydrogen uptake depends on the combined influences of metal particle size and of carbon chemical properties. Carbons obtained from sucrose precursors lead to the hybrid materials with the highest storage capacities since they exhibits a large microporous volume and a high density of oxygenated surface groups. 相似文献
9.
Highly ordered porous carbon materials obtained by a replica technique have been used for supercapacitor application and electrochemical hydrogen storage. For the preparation of the well-tailored carbons, MCM-48, SBA-15 and MSU-1 molecular sieves served as templates, whereas a sucrose solution, propylene and pitch were the carbon source. A careful physico-chemical characterization (CO2 and N2 adsorption, X-ray diffraction, electron microscopy observations) allowed to estimate the total surface area, the pore size distribution, the micro/mesopore volume as well as the structure and the microtexture of the investigated carbons. The specific capacitance (F/g) and the hydrogen adsorption capacity in the carbon nanopores were correlated with the microtextural properties. Especially, a linear dependence has been found between the capacitance or the amount of electrochemically stored hydrogen and the ultramicropores (pores smaller than 0.7 nm) volume. It clearly indicates that in these carbons: (a) the major part of the electrical double layer is charged with non-solvated ions; (b) ultramicropores play a determinant role for hydrogen storage. 相似文献
10.
Kiecolt-Glaser Janice K.; Marucha Phillip T.; Atkinson Cathie; Glaser Ronald 《Canadian Metallurgical Quarterly》2001,69(4):674
To assess the influence of a hypnotic intervention on cellular immune function during a commonplace stressful event, the authors selected 33 medical and dental students on the basis of hypnotic susceptibility. Initial blood samples were obtained during a lower stress period, and a second sample was drawn 3 days before the first major exam of the term. Half of the participants were randomly assigned to hypnotic-relaxation training in the interval between samples. Participants in the hypnotic group were, on average, protected from the stress-related decrements that were observed in control participants' proliferative responses to 2 mitogens, percentages of CD3+ and CD4+ T-lymphocytes, and interleukin 1 production by peripheral blood leukocytes. More frequent hypnotic-relaxation practice was associated with higher percentages of CD3+ and CD4+ T-lymphocytes. These data provide encouraging evidence that interventions may reduce the immunological dysregulation associated with acute stressors. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献