Magnetically Modified Waste Bark of Aegle marmelos Tree as a Promising Biosorbent for Uranium(VI) Sorption

Radiochemistry - Magnetically modified waste bark of the Aegle marmelos tree was prepared by using green synthesis method and was used in a batch system for U(VI) removal from aqueous solution. The...     

Nonlinear model predictive control with polytopic invariant sets

Ellipsoidal invariant sets have been widely used as target sets in model predictive control (MPC). These sets can be computed by constructing appropriate linear difference inclusions together with additional constraints to ensure that the ellipsoid lies within a given inclusion polytope. The choice of inclusion polytope has a significant effect on the size of the target ellipsoid, but the optimal inclusion polytope cannot in general be computed systematically. This paper shows that use of polytopic invariant sets overcomes this difficulty, allowing larger stabilizable sets without loss of performance. In the interests of online efficiency, consideration is focused on interpolation-based MPC.     

Effect of temperature on the optical and electro-optical properties of poly(methyl methacrylate)/E7 polymer-dispersed liquid crystal composites

Experiments on the effect of temperature on the optical and electro-optical behaviors of polymer-dispersed liquid crystals (PDLCs) are considered. Composite films composed of poly(methyl methacrylate) (PMMA) and the nematic-type liquid crystal (LC) E7 were prepared by solvent casting in chloroform. The PDLC film contained droplets of E7 from 10 to 80 wt % in a PMMA matrix. Morphological studies illustrated the formation of isolated droplets of LC due to phase separation, and their homogeneous distribution increased with increasing E7 content. Thermo-optical studies showed an increase in the nematic–isotropic transition temperature of composites, which indicated preferential solvation during the phase-separation process. The electro-optical characteristics were studied under the conditions of an externally applied square wave electric field with a He–Ne laser (λ = 632.8 nm) as a light source. The responses improved as the E7 content in PMMA increased. Semipermanent memory effects were noticed in composites at higher temperatures. Changes in the transmittance due to thermal variations provided the possibility of using such a device as a temperature sensor. The results obtained indicate that under these experimental conditions, the output can be controlled to the desired level by the selection of a suitable loading of LC to prepare PDLC electro-optically active composite films with a response time on the order of only a few milliseconds. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis of polymeric pour point depressants for Nada crude oil (Gujarat,India) and its impact on oil rheology

Five flow improvers have been synthesized to study rheological properties of Nada crude oil (Gujarat, India). Anhydride copolymers were prepared making use of the copolymerization of acrylates of different alkyls with maleic anhydride and the Poly (n-alkyl acrylates-co-N-hexadecylmaleimide) were prepared by the reaction of copolymer with hexadecylamine. The additives were purified and characterized by FTIR, GPC. The prepared polymeric additives shows dual function both as wax dispersants and flow improvers and all of them acts as good pour point depressants. Yield stress and the viscosity of the crude oil at different temperatures and concentrations of additives were evaluated by zero friction advanced rheometer AR-500 of TA instrument. Comparison of morphologies and structures of wax crystals or aggregates in waxy crude oils beneficiated with and without a PPD was also done by micro photographic studies which show the modification in wax crystal morphology due to additives.     

FMS scheduling with knowledge based genetic algorithm approach

In this paper a complex scheduling problem in flexible manufacturing system (FMS) has been addressed with a novel approach called knowledge based genetic algorithm (KBGA). The literature review indicates that meta-heuristics may be used for combinatorial decision-making problem in FMS and simple genetic algorithm (SGA) is one of the meta-heuristics that has attracted many researchers. This novel approach combines KB (which uses the power of tacit and implicit expert knowledge) and inherent quality of SGA for searching the optima simultaneously. In this novel approach, the knowledge has been used on four different stages of SGA: initialization, selection, crossover, and mutation. Two objective functions known as throughput and mean flow time, have been taken to measure the performance of the FMS. The usefulness of the algorithm has been measured on the basis of number of generations used for achieving better results than SGA. To show the efficacy of the proposed algorithm, a numerical example of scheduling data set has been tested. The KBGA was also tested on 10 different moderate size of data set to show its robustness for large sized problems involving flexibility (that offers multiple options) in FMS.     

Symbolic modular deadlock analysis

Methods in object-oriented concurrent libraries often encapsulate internal synchronization details. As a result of information hiding, clients calling the library methods may cause thread safety violations by invoking methods in an unsafe manner. This is frequently a cause of deadlocks. Given a concurrent library, we present a technique for inferring interface contracts that specify permissible concurrent method calls and patterns of aliasing among method arguments. In this work, we focus on deriving contracts that guarantee deadlock-free execution for the methods in the library. The contracts also help client developers by documenting required assumptions about the library methods. Alternatively, the contracts can be statically enforced in the client code to detect potential deadlocks in the client. Our technique combines static analysis with a symbolic encoding scheme for tracking lock dependencies, allowing us to synthesize contracts using a SMT solver. Additionally, we investigate extensions of our technique to reason about deadlocks in libraries that employ signaling primitives such as wait-notify for cooperative synchronization. Our prototype tool analyzes over a million lines of code for some widely-used Java libraries within an hour, thus demonstrating its scalability and efficiency. Furthermore, the contracts inferred by our approach have been able to pinpoint real deadlocks in clients, i.e. deadlocks that have been a part of bug-reports filed by users and developers of client code.     

Mitigation of ammonia-induced SCC in a cupronickel alloy by additions of MgCl<Subscript>2</Subscript>

The work presented in Part 1 of this article showed that additions of magnesium chloride (MgCl₂) to ammonia solutions reduced the tendency of ammonia-induced stress-corrosion cracking (SCC) initiation in a Cu-5%Ni alloy. The present work was undertaken to study the SCC behavior of the test alloy exposed to ammonia in the presence of varying concentrations of MgCl₂. The exposure to MgCl₂ additions reduced the severity of the ammonia-induced SCC.     

Nano Sized Copper Selenide Thin Film Pre-Cursor by A Liquid Phase Chemical Growth Process

The deposition of copper selenide(CuSe)thin films was carried out using liquid phase chemical bath deposition process at the optimized growth parameters as:60℃deposition temperature,90 minutes deposition time,pH equal to 10.5±0.1 and 72±2 r/min speed of mechanical rotation.The as-grown deposits exhibited excellent uniformity and physical adherency with the substrate surface and are smooth and diffusely reflecting with colour changing from yellowish orange to dark chocolate during deposition.The layer is of the order of 300 nm thick.The EDS analysis technique gave film composition to be nearly stoichiometric(Cu=47.89%,Se=52.11%).An X-ray diffraction analysis showed CuSe to be polycrystalline hexagonal with a good match of d-values and intensities of reflections.The crystallite size is in the nanorange(50-60 nm).The as-deposited CuSe exhibited a high coefficient of absorption(α=105cm-1)with a direct optical band gap of 1.81 eV.Compared to other chalcogenides,CuSe films exhibit low resistance;room temperature electrical resistivity being 1.55×103?cm.The electrical conductivity decreased with increase in temperature up to 473 K;showing totally unusual behaviour from that of the semiconducting property.The thermo probe measurements showed n-type conduction of the samples.