电纺直写制备聚己内酯支架形貌及精度

作为一种新型的微纳制造技术，熔体直写电纺被广泛用于组织工程支架的可控制备,有序的纤维沉积是该领域应用的前提条件。对于支架成型精度的探究，本文使用生物可降解材料聚己内酯（PCL），采用自行设计的熔体电纺三维可控成型设备进行实验，考察了纤维间距对二维并行纤维沉积形貌及成型精度的影响，以及纺丝电压和网格大小对三维网格结构形貌及精度影响。结果表明，随着并行纤维设定距离的增大，纤维的沉积误差减小，并最终趋于平稳。对于三维网格结构，随电压的增加，最大沉积层数量先增大后减小，当纺丝电压为6kV时达到最大沉积层数15层。成型精度误差先减小后增大，当纺丝电压为7kV时，精度最高误差小于5%。随设定网格边长的增大，沉积层数不断增大。成型精度逐渐提高，当网格边长大于等于1.5mm时，沉积误差趋于稳定，并维持在5%左右。     

MPaaS: Mobility prediction as a service in telecom cloud

Mobile applications and services relying on mobility prediction have recently spurred lots of interest. In this paper, we propose mobility prediction based on cellular traces as an infrastructural level service of telecom cloud. Mobility Prediction as a Service (MPaaS) embeds mobility mining and forecasting algorithms into a cloud-based user location tracking framework. By empowering MPaaS, the hosted 3rd-party and value-added services can benefit from online mobility prediction. Particularly we took Mobility-aware Personalization and Predictive Resource Allocation as key features to elaborate how MPaaS drives new fashion of mobile cloud applications. Due to the randomness of human mobility patterns, mobility predicting remains a very challenging task in MPaaS research. Our preliminary study observed collective behavioral patterns (CBP) in mobility of crowds, and proposed a CBP-based mobility predictor. MPaaS system equips a hybrid predictor fusing both CBP-based scheme and Markov-based predictor to provide telecom cloud with large-scale mobility prediction capacity.     

冶金炉窑用高强型煤黏结剂优配的实验研究

以湖南金竹山无烟煤为原料，采用正交实验法对冶金炉窑用型煤复合黏结剂各组分的配比及型煤成型的主要工艺参数进行了实验研究．结果表明，镁基黏结剂和成型压力对型煤的抗碎性能影响显著．型煤黏结剂各组分相对于原料煤粉的最优配比为：镁基黏结剂取4％，生物质纤维取1％，固化剂取0．6％，减水剂取0．12％．型煤成型的最佳工艺参数为：成型压力20kN，成型水分17％，烟煤掺量10%，煤料粒度组成：3mm～2mm颗粒为8％，2mm～1mm为12％，1mm～0．5mm为10％，0．5mm以下为70％．评估了该复合型煤黏结剂的成本，分析了其作用机理．     

中空电极板对狭缝式聚合物熔体微分电纺的影响

研究了电极板中空结构对熔体微分电纺过程的影响,探讨了中空宽度对射流数量、射流间距、纤维直径及均匀性的影响。结果表明:电极板采用中空结构时纺丝模头上所产生的射流数量多于实心电极板,且可有效提高电场击穿电压,验证了中空结构的可行性;电极板采用中空结构后,纤维平均直径及直径均匀性均有明显提高,但随着中空宽度继续增加,射流数量减小,射流间距及纤维平均直径增加且直径均匀性变差,从实验研究结果可知,电极板增加中空结构可提高纺丝效果及质量,但中空宽度不宜过大。     

Stabilization of uncertain networked control systems with actuator saturation and probabilistic cyberattacks

This paper investigates the stabilization of uncertain networked control systems (NCSs) with actuator saturation and cyberattacks. The cyberattacks are governed by a set of independent random variables satisfying Bernoulli distribution. To relieve the network bandwidth load effectively, an event-triggered communication strategy is proposed. By employing Lyapunov stability theory and stochastic analysis techniques, a stability criterion is obtained for the system with actuator saturation and cyberattacks. Moreover, the desired controller gain is derived by solving some matrix inequalities. Finally, the validity and applicability of the criteria are verified through numerical examples.     

高压跌落式熔断器过零延时灭弧结构设计

为开发能带负荷分合闸的高压熔断器,设计具有过零延时灭弧结构的10 kV高压跌落式熔断器,并对其开断过程展开研究。现有的熔断器带载分合闸时,触头间易产生电弧引起触头烧蚀,甚至发生电弧持续燃烧无法分断;串联高压硅堆后,相同条件下有载开断过程可靠性得到大幅上升,有效切断电弧能量注入,使触头间“零休”延长,错过弧后快速上升恢复电压,促进触头间隙介质绝缘恢复,对降低触头间隙击穿概率、改善弧后介质恢复特性十分有利。     

激光与碳纤维相互作用的研究现状及发展趋势

由于高比强度、比模量等优良特性,碳纤维成为轻量化制造业的关键原材料之一,拥有广阔的发展潜力,然而高成本、低产率及工艺缺陷等弊端限制了其发展。激光技术的引入给碳纤维的加工制备提供了新的方向。概述了激光与碳纤维相互作用的最新研究进展,详细介绍了激光在加工、制备碳纤维各工艺过程中的作用机制,总结了激光技术在碳纤维复合材料生产加工领域的研究进展,最后分析和展望了激光辅助加工制备碳纤维过程目前仍存在的一些问题及可能的发展方向、应用前景。     

Three-dimensional macroscale assembly of Pd nanoclusters

Construction of macro-materials with highly oriented microstructures and well-connected interfaces between building blocks is significant for a variety of applications. However, it is still challenging to confine the desired structures. Thus, well-defined building blocks would be crucial to address this issue. Herein, we present a facile process based on 1.8 nm Pd nanoclusters (NCs) to achieve centimeter-size assemblages with aligned honeycomb structures, where the diameter of a single tubular moiety is ～4 μm. Layered and disordered porous assemblages were also obtained by modulating the temperature in this system. The reconciled interactions between the NCs were crucial to the assemblages. As a comparison, 14 nm Pd nanoparticles formed only aggregates. This work highlights the approach of confining the size of the building blocks in order to better control the assembly process and improve the stability of the structures.

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A novel photochromic material based on halophosphate: Remote light-controlled reversible luminescence modulation and fluorescence lifetime regulation

Luminescent material Ca₂Ba₃(PO₄)₃F:Eu²⁺ displays green emitting in the range of 400–700?nm, which is ascribed to the 4f⁶5d¹ →4f⁷ transition of Eu²⁺ ions. Amazingly, the body color of the samples can be changed between colorless and green upon alternative UV and visible light irradiation/heating treatment with robust fatigue resistance due to photochromism. The photochromic effect strongly depends on the Eu²⁺ doping concentration. After remote-controlled short-UV irradiation, the overall Eu²⁺ emission intensity presents a significant decrease, and inversely, exhibits an increase to the initial level after illuminated by longer wavelength light or heat treatment. Moreover, the fluorescence lifetime also can be regulated reversibly, of which the regulation degree depends on the short-UV irradiation and longer wavelength illumination time/heating temperature. A schematic diagram based on energy levels is proposed to illustrate the photochromism mechanism.     

Water filtration properties of novel composite membranes combining solution electrospinning and needleless melt electrospinning methods

New composite polyvinyl alcohol (PVA)/polypropylene (PP) membranes were prepared by combining both solution electrospinning and melt electrospinning methods. Self‐designed and made needleless melt electrospinning device was used to fabricate PP membranes which acted as the support layer. PVA membrane on the surface was fabricated via solution electrospinning. The electrospun PVA/PP composite membranes were characterized by the pore size distribution, pure water flux, and rejection ratio, then compared with general composite membranes. Characterizations revealed that the fiber diameter of solution electrospun PVA membrane and melt electrospun PP membrane were 0.171 ± 0.027 and 2.24 ± 0.33 μm, respectively, and the average pore size was 0.832 μm and 27.29 μm, which was much smaller than the nonwoven membrane. The rejection ratio to the 500 nm particles of the PVA/PP composite membrane could reach more than 96%, which was much larger than that of the PVA/non‐woven substrate of 90%, and the melt electrospun PP membrane of 80%, and still maintained high permeate flux of 32,346 L/m²h under the pressure of 0.24 bar. This approach of compositing the solution electrospun membranes and melt electrospun membranes could be useful in designing novel microfiltration membrane owning both higher flux and higher rejection ratio. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41601.