Noble Metal Ion-Directed Assembly of 2D Materials for Heterostructured Catalysts and Metallic Micro-Texturing

Assembling 2D-material (2DM) nanosheets into micro- and macro-architectures with augmented functionalities requires effective strategies to overcome nanosheet restacking. Conventional assembly approaches involve external binders and/or functionalization, which inevitably sacrifice 2DM's nanoscale properties. Noble metal ions (NMI) are promising ionic crosslinkers, which can simultaneously assemble 2DM nanosheets and induce synergistic properties. Herein, a collection of NMI–2DM complexes are screened and categorized into two sub-groups. Based on the zeta potentials, two assembly approaches are developed to obtain 1) NMI-crosslinked 2DM hydrogels/aerogels for heterostructured catalysts and 2) NMI–2DM inks for templated synthesis. First, tetraammineplatinum(II) nitrate (TPtN) serves as an efficient ionic crosslinker to agglomerate various 2DM dispersions. By utilizing micro-textured assembly platforms, various TPtN–2DM hydrogels are fabricated in a scalable fashion. Afterward, these hydrogels are lyophilized and thermally reduced to synthesize Pt-decorated 2DM aerogels (Pt@2DM). The Pt@2DM heterostructures demonstrate high, substrate-dependent catalytic activities and promote different reaction pathways in the hydrogenation of 3-nitrostyrene. Second, PtCl₄ can be incorporated into 2DM dispersions at high NMI molarities to prepare a series of PtCl₄–2DM inks with high colloidal stability. By adopting the PtCl₄–graphene oxide ink, various Pt micro-structures with replicated topographies are synthesized with accurate control of grain sizes and porosities.     

An extended hesitant fuzzy set using SWARA-MULTIMOORA approach to adapt online education for the control of the pandemic spread of COVID-19 in higher education institutions

The world has been challenged since late 2019 by COVID-19. Higher education institutions have faced various challenges in adapting online education to control the pandemic spread of COVID-19. The present study aims to conduct a survey study through the interview and scrutinizing the literature to find the key challenges. Subsequently, an integrated MCDM framework, including Stepwise Weight Assessment Ratio Analysis (SWARA) and Multiple Objective Optimization based on Ratio Analysis plus Full Multiplicative Form (MULTIMOORA), is developed. The SWARA procedure is applied to the analysis and assesses the challenges to adapt the online education during the COVID-19 outbreak, and the MULTIMOORA approach is utilized to rank the higher education institutions on hesitant fuzzy sets. Further, an illustrative case study is considered to express the proposed idea's feasibility and efficacy in real-world decision-making. Finally, the obtained result is compared with other existing approaches, confirming the proposed framework's strength and steadiness. The identified challenges were systemic, pedagogical, and psychological challenges, while the analysis results found that the pedagogical challenges, including the lack of experience and student engagement, were the main essential challenges to adapting online education in higher education institutions during the COVID-19 outbreak.

     

Ranking alternatives in a preferential voting system using fuzzy concepts and data envelopment analysis

In this paper, a new method for aggregating the opinions of experts in a preferential voting system is proposed. The method, which uses fuzzy concept in handling crisp data, is computationally efficient and is able to completely rank the alternatives. Through this method, the number of votes for certain rank position that each alternative receives are first grouped together to form fuzzy numbers. The nearest point to a fuzzy number concept is then used to introduce an artificial ideal alternative. Data envelopment analysis is next used to find the efficiency scores of the alternatives in a pair-wise comparison with the artificial ideal alternative. Alternatives are rank based on these efficiency scores. If the alternatives are not completely ranked, a weight restriction method also based on fuzzy concept is used on the un-discriminated alternatives until they are completely ranked. Two examples are given for illustration of the method.     

A Puzzle of Quantum Phase Transition on Gd-IMC by Tuning of Conduction Electron Concentration

Based on the critical unstable of both crystal and magnetic structure of Gd-intermetallic compound near the competition of two strongly independent subsystem （＂local 4f7＂ and ＂conduction electron concentration＂）, a new QPT （quantum point transition） is predicted by calculation of： （1） The band structure and density of state by density functional theory where a strong narrowing fluidity of fermions around EF with shifted to negative value ＂-0.8 eV ＂is observable in the Gd-intermetalliccompound system while in the Y-case, it is not dominated. An antiferromagnetic state on the fluidity of conduction band can be investigated; （2） The internal magnetic field due to short range exchange interaction Jij between the nearest neighbor of local magnetic moment of stable s-state of Gd （L = 0） through the mean field approximation and of Eigenvalue-Eigenfunction ~.（k） are calculated. While a strong negative value of Jy is predicted, the eigenvalue L（k） of the system shows a strong antiferromagnetic phase in the reciprocal lattice direction 〈010〉, 〈001〉 in the correlation length 3.38 ~A. Although the antiferromagnetic state at Rc 〈_ 3.38 °A is a puzzle but it is completely dominated at Rc = 9 °A after passing through the competition between ）.λmin（O） and λmin（π） in the ranger of 3.2 °A 〈 Rc 〈 9 °A. Since both of the antiferromagnetic subsystems are sensitive to the predicted KF, the effect of decreasing of conduction electron is proposed to investigate, the change of the antiferromagnetic ordering state to the competition of ferromagnetic state （in direction 〈010〉） and antiferromagnetic state （in direction 〈001 〉 and 〈 100〉） resulted to paramagnetic state in the long range Rc = 9 °A.     

Elimination of inclusions and evaporation control during melting of Ti-48Al-2Cr-2Nb-1B intermetallic alloy

Titanium aluminide intermetallic compounds have an excellent capability for use in engineering structures at high temperatures. In the present work the formation of Nb rich inclusions in microstructure and evaporation of Al during melting of γ-TiAl based alloy (Ti-48Al-2Cr-2Nb-1B (at %)) was studied. The results show that the inclusions cannot be removed even with a four-stage melting process, when elemental Nb is used as raw material. However, by replacing Nb with NbAl₃ and using a three-stage melting process, the inclusions were removed from microstructure and also evaporation of Al was reduced remarkably. Otherwise, with removing elemental Al from raw material by using TiAl compound, evaporation of Al will be very low. Increasing vessel pressure from 400 to 600 mbar will not influence evaporation of Al. The article is published in the original.     

Development of an undergraduate structured laboratory to supportclassical and new base technology experiments in communications

This paper describes an effective method of teaching a communications laboratory course that supports classical as well as new base technology experiments to undergraduate electrical engineering students. Primarily, experiments dealing with the design of the basic building blocks of analog and digital communications systems are targeted, which provides an opportunity for the student to become familiar with various signal processing techniques applied in modern communications systems, to learn how to operate the communication laboratory test equipment, and to obtain exposure to some hardware/software design and implementation of these subsystems. The second level of experimentation involves a small system in which discrete or integrated devices are used to build small systems. Level three involves experimentation with a complete communications system, such as a fiber optics communications system or a simulated satellite link. Four sample experiments are described in some detail     

Preliminary analysis of pore distributions using NMR in natural coral and hydrothermally prepared hydroxyapatite

Pore size distributions in an Australian coral from Goniopora sp have been measured by mercury intrusion, nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM). A significant result is that NMR predicts nanopores which could be seen visibly. The methods give similar results as mercury intrusion for large pores around 100 m but differ for smaller pores. Differences between NMR and mercury intrusion are equated using a non linear sigmoidal regression model. The NMR method was also compared with mercury intrusion methods to measure pore sizes on hydroxyapatite conversion products which have promise as bio-implants. Differences between samples due to errors in the methodology are discussed. Together all three methods are shown to complement each other.     

Optimization of Supercritical Extraction of Linalyl Acetate from Lavender via Box‐Behnken Design

Essential oil was extracted from lavender using supercritical carbon dioxide by means of a newly developed periodic static‐dynamic (PSD) procedure and the conventional semicontinuous (SC) technique. Applying GC‐FID analysis in conjunction with Box‐Behnken design, an optimum overall extraction yield (94.4 %) was obtained via PSD in contrast to 90 % for the SC method. The results indicate that supercritical fluid extraction is a viable technique for separation of constituents such as linalyl acetate, linalool, fenchone, and camphor for pharmaceutical and medicinal applications. Furthermore, a substantial reduction of energy consumption and solvent consumption is achieved with the developed PSD process compared to the conventional SC method.