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1.
Several fatty derivatives with bulky moieties were prepared by treatment of epoxidized isopropyl oleate with a number of alcohols
in the presence of sulfuric acid catalyst to provide a series of α-hydroxy ethers in good yield. The materials were analyzed
for cold flow performance through cloud point and pour point determinations. The most promising α-hydroxy ether produced in
this study, with respect to both low temperature behavior and economic criteria, was isopropyl 9(10)-(2-ethylhexoxy) 10(9)-hydroxystearate,
which has a cloud point of −23°C and pour point of −24°C. 相似文献
2.
New epoxidized soybean oil (ESO)/clay nanocomposites have been prepared with triethylenetetramine (TETA) as a curing agent. The dispersion of the clay layers is investigated by X-ray diffraction (XRD) and transmission electron microscopy (TEM). XRD and TEM data reveal the intercalated structure of ESO/clay nanocomposites has been developed. The thermogravimetric analysis exhibits that the ESO/clay nanocomposites are thermally stable at temperatures lower than 180 °C, with the maximum weight loss rate after 325 °C. The glass transition temperature, Tg, about 7.5 °C measured by differential scanning calorimetry (DSC) and Tg about 20 °C measured by dynamic mechanical study have been obtained. The difference in the Tg between DSC and dynamic measurements may be caused by different heating rate. The nanocomposites with 5-10 wt% clay content possess storage modulus ranging from 2.0×106 to 2.70×106 Pa at 30 °C. The Young's modulus (E) of these materials varies from 1.20 to 3.64 MPa with clay content ranging from 0 to 10 wt%. The ratio of epoxy (ESO) to hydrogen (amino group of TETA) greatly affects dynamic and tensile mechanical properties. At higher amount of TETA, the nanocomposites exhibit stronger tensile and dynamic properties. 相似文献
3.
In this study, polyvinyl alcohol/organically modified montmorillonite (HDA/MMT; organoclay) composite was prepared for the intercalation processes. Firstly, the rheological behavior of aqueous montmorillonite dispersions was investigated as a function of solid content. Hexadecylamine (HDA) was added to the montmorillonite dispersion (2%, w/w) in different concentrations in the range of 5 × 10?4 – 9 × 10?3 mmol/L. The basal spacing of the organoclay (OMMT) was studied by X‐ray diffraction. The FTIR spectra are obtained from the modified montmorillonite products, which revealed the characteristic absorbencies after treatment with HDA. HDA/MMT/PVA composite, which was produced by the reaction of 1 wt % PVA solution with organoclay complex, is characterized by the rheology, electrokinetic, XRD, FTIR, and SEM techniques. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102:2315–2323, 2006 相似文献
4.
Nedim Muzoğlu Ahmet Mesrur Halefoğlu Muhammed Onur Avci Melike Kaya Karaaslan Bekir Sıddık Binboğa Yarman 《Expert Systems》2023,40(1):e13141
Since the first case of COVID-19 was reported in December 2019, many studies have been carried out on artificial intelligence for the rapid diagnosis of the disease to support health services. Therefore, in this study, we present a powerful approach to detect COVID-19 and COVID-19 findings from computed tomography images using pre-trained models using two different datasets. COVID-19, influenza A (H1N1) pneumonia, bacterial pneumonia and healthy lung image classes were used in the first dataset. Consolidation, crazy-paving pattern, ground-glass opacity, ground-glass opacity and consolidation, ground-glass opacity and nodule classes were used in the second dataset. The study consists of four steps. In the first two steps, distinctive features were extracted from the final layers of the pre-trained ShuffleNet, GoogLeNet and MobileNetV2 models trained with the datasets. In the next steps, the most relevant features were selected from the models using the Sine–Cosine optimization algorithm. Then, the hyperparameters of the Support Vector Machines were optimized with the Bayesian optimization algorithm and used to reclassify the feature subset that achieved the highest accuracy in the third step. The overall accuracy obtained for the first and second datasets is 99.46% and 99.82%, respectively. Finally, the performance of the results visualized with Occlusion Sensitivity Maps was compared with Gradient-weighted class activation mapping. The approach proposed in this paper outperformed other methods in detecting COVID-19 from multiclass viral pneumonia. Moreover, detecting the stages of COVID-19 in the lungs was an innovative and successful approach. 相似文献
5.
6.
Murat Yusuf Sav Tansu Sav Elif Senocak Nadide Melike Sav 《Hemodialysis international. International Symposium on Home Hemodialysis》2014,18(4):725-729
Headache is one of the most frequently encountered neurological symptoms during hemodialysis. According to International Classification of Headache criteria dialysis‐related headache was defined as the headache occurring during hemodialysis with no specific characteristic. It resolves spontaneously within 72 hours after the hemodialysis session ends. There are few studies in the literature investigating the clinical features of dialysis headache. The pathophysiology of hemodialysis‐related headache is not known, but various triggering factors have been identified, including changes in blood pressure, serum sodium and magnesium levels during hemodialysis sessions, caffeine deprivation and stress. The aim of this article is to evaluate and analyze features of headache in patients undergoing hemodialysis. 相似文献
7.
8.
Mehmet Aydın Hüseyin Sevgili Bekir Tufan Yilmaz Emre Sevim Köse 《International Journal of Food Science & Technology》2011,46(3):500-508
Proximate composition and fatty acid (FA) profile of three commercial sea cucumbers; Holothuria tubulosa, Holothuria polii and Holothuria mammata caught from Aegean Sea of Turkey were analysed. The effects of regional variation and drying process on FA composition were also investigated. Moisture, protein, fat and ash contents of the species ranged between 81.24% and 85.24%, 7.88% and 8.82%, 0.09% and 0.18%, and 5.13% and 7.85%, respectively, with a significant changes among species (P < 0.05) with some exceptions. Although FA values varied significantly (P < 0.05) among species and regions, the changes for most FA types representing the same region for different species were not significantly different. Total polyunsaturated fatty acids (PUFA) were found to be higher than total saturated (SFA) and monosaturated FAs (MUFA) accounting for 53.0–62.12% for ∑PUFA, 13.28–16.41% for ∑MUFA and 13.99–19.21% for ∑SFA. While some individual SFAs and PUFAs decreased after drying process, various individual FAs of MUFA increased in their amounts (P < 0.05). Among PUFAs, the highest mean value of eicosapentaenoic acid and docosahexaenoic acid for all regions were determined for H. polii as 7.25% and H. tubulosa as 12.37% in fresh samples, respectively. This study represents new information relating to FA contents and drying effect on FA profile for these species. 相似文献
9.
Hong-Sik?Hwang Atanu?Adhvaryu Sevim?Z.?ErhanEmail author 《Journal of the American Oil Chemists' Society》2003,80(8):811-815
Synthetic lubricant basestocks were prepared from epoxidized soybean oil (ESO) and 2-ethylhexanol (2-EH) to be used alone
or with polyalphaolefin (PAO). Sulfuric acid-catalyzed reaction of ESO with 2-EH involves a ring-opening reaction at the epoxy
group followed by transesterification at the ester group. Reaction with other catalysts including p-toluenesulfonic acid, Dowex 50W-8X, boron trifluoride, and sodium methoxide was also examined. Pour points of the products
were observed as lows as −21 and −30°C without and with 1% of pour point depressant, respectively. When the hydroxy groups
in the products were esterified with an acid anhydride, lower pour points were observed. Pour point depression of the product
by adding PAO has been tested. Oxidative stability of the product was examined using pressurized DSC and compared with those
of synthetic lubricant basestocks, PAO, and a synthetic ester. 相似文献
10.
Jingyuan Xu Zengshe Liu Sevim Z. Erhan 《Journal of the American Oil Chemists' Society》2008,85(3):285-290
Hydrogels formed from biopolymers or natural sources have special advantages because they may have biodegradable and biocompatible
properties. The viscoelastic properties of a newly developed biological hydrogel made from epoxidized soybean oil (ESO) were
investigated. The material called HPESO is a hydrolytic product of polymerized ESO (PESO). HPESO exhibited viscoelastic solid
or gel behavior above 2% (wt. %) concentration at room temperature and viscous liquid behavior at 55 °C. The thermal assembly
disassembly reassembly function of the HPESO hydrogel was completely reversible. The viscoelastic properties of HPESO were
dependent on concentration. Analysis of modulus and concentration dependence and stress relaxation measurement indicated that
HPESO was a physical gel where the cross-linkers between the molecules were physical junctions. HPESO hydrogel also exhibited
fast initial recovery of its viscoelastic properties after being subjected to mechanical shear disruption. The function and
behavior of the HPESO hydrogel suggest that this biomaterial may be suitable for applications in drug delivery and scaffolds
of bioengineering and tissue engineering.
Names are necessary to report factually on available data; however, the USDA neither guarantees nor warrants the standard
of the product, and the use of the name by the USDA implies no approval of the product to the exclusion of others that may
also be suitable. 相似文献