Elimination of fictitious penetrating rays from PO and hybridization with AFIM

Physical optics (PO) is an approximation method for high‐frequency scattering and diffraction problems. But PO fields are inaccurate in the shadow region where the source is screened by the scatter. Two key factors of the error for PO are (i) edge diffraction coefficients and (ii) existence of fictitious penetrating rays. The correction with respect to the former has been extensively investigated by many authors using various ray techniques such as GTD, UTD, and UAT. On the other hand, the latter was identified recently by the authors. This paper proposes novel PO‐based calculation procedures termed PO‐AF and PTD‐AF, where PO and Aperture Field Integration Method (AFIM) are merged with the help of special elementary diffraction coefficients. These can uniformly cover the whole angular region and only the error factor (ii) is removed in PO‐AF while both (i) and (ii) are removed in PTD‐AF. The theoretical backgrounds of PO currents are discussed in terms of field equivalence theorem and visualization of EM waves. Next, new methods are proposed and their validity is numerically demonstrated for 2D scattering problems of a strip, a corner reflector, and a cylinder of circular arc. © 2004 Wiley Periodicals, Inc. Electr Eng Jpn, 150(2): 1–10, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20037     

Performance of solvothermally prepared Ga2O3-Al2O3 catalysts for SCR of NO with methane

The solvothermal reaction of mixtures of aluminum isopropoxide (AIP) and gallium acetylacetonate (Ga(acac)₃) directly yielded the mixed oxides of γ-Ga₂O₃-Al₂O₃. In the solvothermal synthesis, the crystal structure of mixed oxides was controlled by the initial formation of γ-Ga₂O₃ nuclei. The mixed oxides prepared in diethylenetriamine have extremely high activities for selective catalytic reduction (SCR) of NO with methane as a reducing agent. With increasing crystallite size of the spinel structure, the catalytic activity increased. The ratio of the amount of methane consumed by combustion to total methane conversion was proportional to the density of acid sites on the surface of the mixed oxides. The mixed oxide catalysts prepared in diethylenetriamine had lower densities of acid sites and showed a higher methane-efficiency for CH₄-SCR than those prepared in other solvents. These catalysts maintained their high activity even when the reaction was carried out under the severe conditions (i.e., high space velocity and low NO concentration).     

Hydrocarbons with a homoconjugated polyene system and their monoepoxy derivatives: Sex attractants of geometrid and noctuid moths distributed in Japan

Although several sex pheromones of the family Geometridae have been characterized, investigations on Japanese species are limited. In order to obtain more information, screening using known sex pheromones and their analogs was carried out. The (Z,Z,Z)-3,6,9-triunsaturated and (Z,Z)-6,9-diunsaturated hydrocarbons with straight C¹⁹-C²¹ chains were synthesized by the Grignard coupling reaction as a key step starting from linolenic and linoleic acids, respectively. Oxidation of the homoconjugated trienes withm-chloroperoxybenzoic acid yielded a 111 mixture of three monoepoxy derivatives that could be separated by silica gel chromatography. The chemical structure of each positional isomer was confirmed using two-dimensional NMR techniques and MS measurements, which enabled characteristic fragment ions from the isomers to be identified. Field tests using lures incorporating only one of the above six hydrocarbons or nine epoxides were carried out in a forest in Tokyo. Consequently, attraction of male moths of 14 geometrid species in addition to four species in another family, the Noctuidae, was observed. It was concluded that hydrocarbons with a homoconjugated polyene system and the monoepoxy derivatives are important components of sex pheromones produced by Japanese lepidopterous insects, particularly the geometrid moths.     

Numerical computation of cross‐coupled algebraic Riccati equations related to H2/H∞ control problem for singularly perturbed systems

In this paper, we present a numerical algorithm to the cross‐coupled algebraic Riccati equations(CARE) related to H₂/H_∞ control problems for singularly perturbed systems (SPS) by means of Newton's method. The resulting algorithm can be widely used to solve Nash game problems and robust control problems because the CARE is solvable even if the quadratic term has an indefinite sign. We prove that the resulting iterative algorithm has the property of the quadratic convergence. Using the solution of the CARE, we construct the high‐order approximate H₂/H_∞ controller. Copyright © 2004 John Wiley & Sons, Ltd.     

Calcium Chloride (CaCl2) as Catalyst for Asymmetric Organic Reactions

Pybox–CaCl₂ was found to be an efficient chiral catalyst for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds with nitroalkenes, affording γ-nitro carbonyl compounds in high yields with high enantioselectivities. The reactions proceeded smoothly even in air, and were successfully applied to a continuous flow system.     

Slow crack growth and acoustic emission characteristics in COD test

Brittle material fractures at a critical value of stress intensity factor or crack opening displacement (COD) without any prior crack growth. In the ductile materials, however unstable fracture initiation may be preceded by a period of slow crack growth from the notch tip. Such slow crack growth may be an essential prelude to unstable fast fracture and thus COD at the start of slow crack growth can also be regarded as a critical value of the fracture characteristics. We have tried to apply the acoustic emission techniques to the COD test. Acoustic emission techniques can be used to detect the onset of slow crack growth and to obtain a relation between COD and AE characteristics in the COD test.     

Ionic conductivity of amorphous mNaFnMF3 thin films (M=Al,Cr)

Evaporated 0.5 to 0.7 μm thick thin films of mNaFnAlF₃ or mNafnCrF₃ were prepared in a 1 mPa vacuum on glass substrates kept at room temperature. Chemical analysis and AC conductivity measurement revealed that in each case studied, a high ionic conductivity plateau existed for the composition range $\text{0.1 <}\text{n}\text{(m+n)}\text{< 0.4}$. The maximum conductivities at room temperature were σ = 1 × 10^?6 S/mm for NaFAlF₃ and σ = 2 × 10^?5 S/m for NaFCrF₃. Those high conductivities were discussed in terms of arrangement of MF₆ octahedra.     

Ice clouds and Asian dust studied with lidar measurements of particle extinction-to-backscatter ratio, particle depolarization, and water-vapor mixing ratio over Tsukuba

The tropospheric particle extinction-to-backscatter ratio, the depolarization ratio, and the water-vapor mixing ratio were measured by use of a Raman lidar and a polarization lidar during the Asian dust seasons in 2001 and 2002 in Tsukuba, Japan. The apparent (not corrected for multiple-scattering effects) extinction-to-backscatter ratios (Sp) showed a dependence on the relative humidity with respect to ice (RHice) obtained from the lidar-derived water-vapor mixing ratio and radiosonde-derived temperature; they were mostly higher than 30 sr in dry air (RHice < 50%), whereas they were mostly lower than 30 sr in ice-supersaturated air (RHice > or = 100%), where the apparent extinction coefficients were larger than 0.036 km(-1). Both regions showed mean particle depolarization ratios of 20%-22%. Comparisons with theoretical calculations and the previous experiments suggest that the observed dependence of Sp on RHice is attributed to the difference in the predominant particles: nonspherical aerosols (mainly the Asian dust) in dry air and cloud particles in ice-supersaturated air.     

The Role of HECT-Type E3 Ligase in the Development of Cardiac Disease

Despite advances in medicine, cardiac disease remains an increasing health problem associated with a high mortality rate. Maladaptive cardiac remodeling, such as cardiac hypertrophy and fibrosis, is a risk factor for heart failure; therefore, it is critical to identify new therapeutic targets. Failing heart is reported to be associated with hyper-ubiquitylation and impairment of the ubiquitin–proteasome system, indicating an importance of ubiquitylation in the development of cardiac disease. Ubiquitylation is a post-translational modification that plays a pivotal role in protein function and degradation. In 1995, homologous to E6AP C-terminus (HECT) type E3 ligases were discovered. E3 ligases are key enzymes in ubiquitylation and are classified into three families: really interesting new genes (RING), HECT, and RING-between-RINGs (RBRs). Moreover, 28 HECT-type E3 ligases have been identified in human beings. It is well conserved in evolution and is characterized by the direct attachment of ubiquitin to substrates. HECT-type E3 ligase is reported to be involved in a wide range of human diseases and health. The role of HECT-type E3 ligases in the development of cardiac diseases has been uncovered in the last decade. There are only a few review articles summarizing recent advancements regarding HECT-type E3 ligase in the field of cardiac disease. This study focused on cardiac remodeling and described the role of HECT-type E3 ligases in the development of cardiac disease. Moreover, this study revealed that the current knowledge could be exploited for the development of new clinical therapies.     

Identification of Sex Pheromones of Anadevidia peponis and Macdunnoughia confusa and Field Tests of Their Role in Reproductive Isolation of Closely Related Plusiinae Moths

Anadevidia peponis and Macdunnoughia confusa are defoliators of plants in the family Cucurbitaceae and Compositae, respectively, in Japan. GC-MS analyses of crude pheromone gland extracts treated with or without dimethyl disulfide indicated that females of A. peponis produced six monoene acetates and two monoene alcohols and that M. confusa females produced five monoene acetates. These components include (Z)-7-dodecenyl acetate as a major common constituent and three other acetates as minor common constituents. The minor constituents are quite different in blend composition. In addition, with (Z)-7-dodecenyl acetate, an indispensable component for male attraction is (Z)-5-decenyl acetate for A. peponis and (Z)-9-tetradecenyl acetate is essential for M. confusa. Field tests with synthetic lures showed synergistic effects of some other minor components and male attraction of three additional Plusiinae species, Macdunnoughia purissima, Ctenoplusia albostriata, and Chrysodeixis eriosoma, suggesting their reproductive isolation is based in part on pheromonal communication.