Ultrafast Electron–Phonon Coupling at Metal-Dielectric Interface

Energy transfer from photo-excited electrons in a metal thin film to the dielectric substrate is important for understanding the ultrafast heat transfer process across the two materials. Substantial research has been conducted to investigate heat transfer in a metal-dielectric structure. In this work, a two-temperature model in metal was used to analyze the interface electron and dielectric substrate coupling. An improved temperature and wavelength-dependent Drude–Lorentz model was implemented to interpret the signals obtained in optical measurements. Ultrafast pump-and-probe measurements on Au-Si samples were carried out, where the probe photon energy was chosen to be close to the interband transition threshold of gold to minimize the influence of non-equilibrium electrons on the optical response and maximize the thermal modulation to the optical reflectance. Electron-substrate interface thermal conductance at different pump laser fluences was obtained, and was found to increase with the interface temperature.     

CATALYTIC CRACKING OF TARS FROM COAL DEVOLATILIZATION

A set of runs were performed on the catalytic and thermal cracking of the tars present fn the gasifier off-gas stream; the cracking referred to here Js essentially hydrocracking, in view of the considerable amount of hydrogen being present in the gas stream. The catalyst evaluated for tar cracking was a commercial cobalt-molybdenum catalyst, suppported on γ-Al₂O₃(Katalco-477). It was observed that there was a decrease in the amount of tar obtained with the cracking unit on-line with the gasifier; the tars were cracked to gaseous products in the presence of catalyst. Furthermore, it appeared that higher ring structures were transformed to less heavier components; thus cracking could become beneficial in downstream processing of the gas stream coming out of a gasifier.     

Dual frequency miniature microstrip antenna

A single-feed dual frequency compact microstrip antenna with a shorting pin is described. This new antenna configuration gives a large variation in frequency ratio of the two operating frequencies, without increasing the overall size of the antenna     

Microstructural effects on the tensile properties and deformation behavior of a Ti-48Al gamma titanium aluminide

The effects of microstructure on the tensile properties and deformation behavior of a binary Ti-48Al gamma titanium aluminide were studied. Tensile-mechanical properties of samples with microstructures ranging from near γ to duplex to fine grained, near- and fully-lamellar were determined at a range of temperatures, and the deformation structures in these characterized by transmission electron microscopy (TEM). Microstructure was observed to exert a strong influence on the tensile properties, with the grain size and lamellar volume fraction playing connected, but complex, roles. Acoustic emission response monitored during the tensile test revealed spikes whose amplitude and frequency increased with an increase in the volume fraction of lamellar grains in the microstructure. Analysis of failed samples suggested that microcracking was the main factor responsible for the spikes, with twinning providing a minor contribution in the near-lamellar materials. The most important factor that controls ductility of these alloys is grain size. The ductility, yield stress, and work-hardening rate of the binary Ti-48Al alloy exhibit maximum values between 0.50 and 0.60 volume fraction of the lamellar constituent. The high work-hardening rate, which is associated with the low mobility of dislocations, is the likely cause of low ductility of these alloys. In the near-γ and duplex structures, slip by motion of 1/2<110] unit dislocations and twinning are the prevalent deformation modes at room temperature (RT), whereas twinning is more common in the near- and fully-lamellar structures. The occurrence of twinning is largely dictated by the Schmid factor. The 1/2<110] unit dislocations are prevalent even for grain orientations for which the Schmid factor is higher for <101] superdislocations, though the latter are observed in favorably oriented grains. The activity of both of these systems is responsible for the higher ductility at ambient temperatures compared with Al-rich single-phase γ alloys. A higher twin density is observed in lamellar grains, but their propagation depends on the orientation and geometry of the individual γ lamellae. The increase in ductility at high temperatures correlates with increased activity of 1/2<110] dislocations (including their climb motion) and twin thickening. The role of microstructural variables on strength, ductility, and fracture are discussed. This article is based on a presentation made in the symposium entitled “Fundamentals of Structural Intermetallics,” presented at the 2002 TMS Annual Meeting, February 21–27, 2002, in Seattle, Washington, under the auspices of the ASM and TMS Joint Committee on Mechanical Behavior of Materials.     

Achieving near-optimum asymptotic efficiency and fading resistanceover the time-varying Rayleigh-faded CDMA channel

We study multiuser receiver design and analysis for synchronous code-division multiple-access (CDMA) channels with time-varying Rayleigh fading. Starting from an error probability criterion, we first derive a near-optimum receiver for this channel that admits a detector-estimator decomposition, has certain asymptotic optimality properties and a complexity which is independent of the length of the observation interval. The performance of this detector is analytically characterized and contrasted with that of the optimal multiuser detector for the time-invariant (or static) CDMA Rayleigh-fading channel when it is implemented over the time-varying channel. Notable among our conclusions is the fact that, unlike the static channel multiuser detector, the time-varying channel detector is able to withstand not only the estimated interference from the other system users, but also, the residual interference (that cannot be estimated) arising out of imperfect estimation of the interferer fading parameters. Using estimation error covariance information, this detector shows flexibility in accommodating a wide range of interferer fading conditions     

An approximate analysis of the effect of micro fractures on the caustic of a dynamically moving crack tip

The optical recording of the conditions at the tips of dynamically moving cracks is often associated with a wave pattern which arises from what we call here radial waves. This observation is prevalent for tough solids, especially when the observation tools involve surface deformations such as the caustic method. These waves can modify the caustic shape and size and thus influence the interpretation of measurements. The quantification of the sources of these waves poses a very difficult problem so that a precise evaluation of that phenomenon is not yet possible. However, in an attempt to better understand the limitation imposed on the method of caustics by this set of waves this paper analyzes primarily the change of shape in the caustic associated with the passage of radial waves over the region of the initial curve of the caustic. The analysis is approximate in that the radial waves are assumed to be insensitive to the presence of the crack surfaces, but otherwise accounts for the three dimensional character of wave propagation in a plate of finite thickness.

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Résumé On associe souvent l'enregistrement optique des conditions présentes à l'extrémité de fissures en cours de propagation spectaculaire, à une disposition ondulée, due à ce que l'on dénomme ici des ondes radiales. L'observation vaut surtout pour les corps à haute ténacité, et en particulier lorsque les méthodes d'observation tiennent compte des déformations de surface, comme la méthode des caustiques. Les ondes radiales peuvent altérer la forme et la dimension d'une caustique, et, de ce fait, influencer l'interprétation des mesures. Une évaluation précise de ce phénomène n'est pas encore possible, car la quantification des sources de ces ondes pose un problème trés délicat. Néanmoins, en vue de mieux comprendre les limites qu'impose à la méthode des caustiques la formation de ces ondes, on a analysé essentiellement le changement de forme de la caustique lorsque se développent des ondes radiales sur la région couverte par la courbe originale de la caustique. On procède à une approximation dans la mesure où on suppose que les ondes radiales sont insensibles à la présence des surfaces de la fissure, mais prennent par ailleurs en considération le caractère tridimensionnel de la propagation d'une fissure dans une plaque d'épaisseur finie.

     

Synergistic Effect of PVDF-Coated PCL-TCP Scaffolds and Pulsed Electromagnetic Field on Osteogenesis

Bone exhibits piezoelectric properties. Thus, electrical stimulations such as pulsed electromagnetic fields (PEMFs) and stimuli-responsive piezoelectric properties of scaffolds have been investigated separately to evaluate their efficacy in supporting osteogenesis. However, current understanding of cells responding under the combined influence of PEMF and piezoelectric properties in scaffolds is still lacking. Therefore, in this study, we fabricated piezoelectric scaffolds by functionalization of polycaprolactone-tricalcium phosphate (PCL-TCP) films with a polyvinylidene fluoride (PVDF) coating that is self-polarized by a modified breath-figure technique. The osteoinductive properties of these PVDF-coated PCL-TCP films on MC3T3-E1 cells were studied under the stimulation of PEMF. Piezoelectric and ferroelectric characterization demonstrated that scaffolds with piezoelectric coefficient d₃₃ = −1.2 pC/N were obtained at a powder dissolution temperature of 100 °C and coating relative humidity (RH) of 56%. DNA quantification showed that cell proliferation was significantly enhanced by PEMF as low as 0.6 mT and 50 Hz. Hydroxyapatite staining showed that cell mineralization was significantly enhanced by incorporation of PVDF coating. Gene expression study showed that the combination of PEMF and PVDF coating promoted late osteogenic gene expression marker most significantly. Collectively, our results suggest that the synergistic effects of PEMF and piezoelectric scaffolds on osteogenesis provide a promising alternative strategy for electrically augmented osteoinduction. The piezoelectric response of PVDF by PEMF, which could provide mechanical strain, is particularly interesting as it could deliver local mechanical stimulation to osteogenic cells using PEMF.     

Silica–alumina-supported transition metal sulphide catalysts for deep hydrodesulphurization

Deep hydrodesulphurization (HDS) of dibenzothiophene (DBT) and gas-oil has been carried out on amorphous-silica–alumina (ASA)-supported transition metal sulphides (TMS) under conditions which approach industrial practice. The activity and selectivity of the binary Ni-, Ru- and Pd-promoted Mo catalysts were compared with the monometallic ones (Ru, Ir, Pd, Ni, Mo on ASA). For both HDS of DBT and gas-oil, the observed activity trends were similar; thus, all catalysts were more active with model feed than with gas-oil, and less active than commercial CoMo/Al₂O₃. The binary catalysts showed larger activity than monometallic ones, with Ni–Mo catalyst being more effective than Ru–Mo or Pd–Mo. For Ni–Mo sample, the X-ray photoelectron and temperature-programmed reduction techniques confirmed that incorporation of Mo minimises metal–support interaction, although the formation of nickel hydrosilicate was not prevented. The consecutive impregnation of calcined Mo/ASA catalyst with precursor solution followed by calcination enhances molybdenum surface exposure in binary samples. As a consequence, the temperature of reduction of MoO₃ to molybdenum suboxides is decreased.     

Characterization of microstructural changes during annealing of cold worked austenitic stainless steel using ultrasonic velocity measurements and correlation with mechanical properties

A technique that is sensitive to change in texture is more reliable than mechanical property measurements for the study of recrystallization behavior in alloys where recrystallization is coupled with precipitation. Hence, ultrasonic velocity measurements have been employed to characterize microstructural changes during annealing of cold worked Ti-modified austenitic stainless steel where precipitation of TiC is known to retard recrystallization. Mechanical property measurements, such as strength and hardness, could not distinguish the recovery and recrystallization regimes, and it was difficult to determine the exact time or temperature for onset of recrystallization. The variation of velocity with annealing time or annealing temperature exhibited a three-stage behavior. The velocity exhibited a slight increase in the recovery region followed by a sharp and continuous decrease in the recrystallization region and reached saturation on completion of recrystallization. Based on the microstructural investigations, the three stages were identified to be recovery, progress of recrystallization, and completion of recrystallization. Velocity measurements could sense the onset, progress, and completion of recrystallization more accurately compared with that of hardness and strength measurements.