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Joo F. Mano Yaming Wang Júlio C. Viana Zlatan Denchev Maria J. Oliveira 《大分子材料与工程》2004,289(10):910-915
Summary: The cold crystallization process of initially amorphous poly(L ‐lactic acid), PLLA, with two different molecular weights, during a heating at 2 °C/min, was investigated by DSC and time‐resolved simultaneous SAXS and WAXS, using synchrotron radiation. Equatorial scans of the isotropic 2D‐SAXS patterns showed that the average Bragg long period (LB) of PLLA samples was approximately constant with the development of cold crystallization up to a temperature that corresponded to a melt/re‐crystallization process that took place before the nominal melting peak seen by DSC. LB values were found to be higher for the high molecular weight material. This was in accordance with the higher melting temperature observed in the high molecular weight PLLA that implied the existence of thicker lamellae. WAXS results showed that the molecular weight did not apparently affect the crystal form and the final degree of crystallinity of PLLA. The Avrami parameters from WAXS and DSC were consistent, showing that the non‐isothermal cold crystallization of the two PLLA samples corresponded mainly to a three‐dimensional growth, although an imperfect crystallization process was involved at early times. The crystallization rate of PLLA, observed both by WAXS and DSC, decreased with increasing molecular weight.
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Polyamide 6 (PA6) isotropic films and oriented cables were prepared by compression molding or by consecutive extrusion and cold‐drawing. These samples were isothermally annealed in the 120–200°C range and were then subjected to tensile tests at room temperature. Synchrotron wide‐angle X‐ray scattering (WAXS) and small‐angle X‐ray scattering (SAXS) patterns were obtained before and after mechanical failure. These data were related with the mechanical properties of the respective PA6 samples. The annealing of isotropic PA6 resulted in an increase in the Young's modulus (E) and yield stress (σy) values, which was attributed to the observed proportional reduction of the d‐spacings of the intersheet distances in both the α‐PA6 and γ‐PA6 polymorphs. Analysis of the WAXS and SAXS patterns of isotropic PA6 after break allowed the supposition of structural changes in the amorphous phase, with these being better pronounced with increasing annealing temperature; this made the samples less ductile. In oriented PA6 samples, annealing resulted in a drastic increase in the E and σy values accompanied by a phase transition from γ‐PA6 to α‐PA6 and a well‐pronounced reduction in the intersheet distances of both polymorphs. The stretching of the oriented samples led to an additional γ‐to‐α transition, whose extent was also related to structural changes in the amorphous phase. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2242–2252, 2007 相似文献
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Preparation and properties of polyamide‐6‐based thermoplastic laminate composites by a novel in‐mold polymerization technique 下载免费PDF全文
Nadya Dencheva Ana S. Sampaio Filipa M. Oliveira António S. Pouzada Antonio M. Brito Zlatan Denchev 《应用聚合物科学杂志》2014,131(8)
In this work, a method for preparation of polyamide‐6 (PA6) based laminates reinforced by glass fiber‐ (GFL) or polyamide‐66 (PA66) textile structures (PL) via reactive injection molding is disclosed. It is based on in‐mold anionic polymerization of ε‐caprolactam carried out at 165°C in the presence of the respective reinforcements performed in newly developed prototype equipment whose design concept and operation are described. Both composite types were produced for reaction times of 20 min, with conversion degrees of 97–99%. Initial mechanical tests in tension of GFL samples displayed almost twofold increase of the Young's modulus and stress at break values when compared with the neat anionic PA6. The improvement was proportional to the volume fraction Vf of glass fiber fabric that was varied in the 0.16–0.25 range. A 300% growth of the impact strength was registered in PL composites with Vf of PA66 textile of 0.1. Removing the surface finish of the latter was found to be a factor for improving the adhesion at the matrix–fiber interface. The mechanical behavior of GFL and PL composites was discussed in conjunction with the morphology of the samples studied by optical and electron microscopy and the matrix crystalline structure as revealed by synchrotron X‐ray diffraction. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40083. 相似文献
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Nadya Dencheva M. Jovita Oliveira Olga S. Carneiro António S. Pouzada Zlatan Denchev 《应用聚合物科学杂志》2010,115(5):2918-2932
The preparation of microfibrillar composites (MFCs) based on oriented blends of polyamide 6 (PA6) and high‐density polyethylene (HDPE) is described. By means of conventional processing techniques, the PA6 phase was transformed in situ into fibrils with diameters in the upper nanometer range embedded in an isotropic HDPE matrix. Three different composite materials were prepared through the variation of the HDPE/PA6 ratio with and without a compatibilizer: MFCs reinforced by long PA6 fibrils arranged as a unidirectional ply; MFCs containing middle‐length, randomly distributed reinforcing PA6 bristles; and a nonoriented PA6‐reinforced material in which the PA6 phase was globular. The evolution of the morphology in the reinforcing phase (e.g., its visible diameter, length, and aspect ratio) was followed during the various processing stages as a function of the blend composition by means of scanning electron microscopy. Synchrotron X‐ray scattering was used to characterize selected unidirectional ply composites. The presence of transcrystalline HDPE was demonstrated in the shell of the reinforcing PA6 fibrils of the final MFCs. The impact of the compatibilizer content on the average diameter and length of the fibrils was assessed. The influence of the reinforcing phase on the tensile strength and Young's modulus of the various composites was also evaluated. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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Semiconductor nanostructures are promising candidates for efficient thermoelectric energy conversion, with applications in solid-state refrigeration and power generation. The design of efficient semiconductor thermocouples requires a thorough understanding of both charge and heat transport; therefore, thermoelectricity in silicon-based nanostructures requires that both electronic and thermal transport be treated on an equal footing. In this paper, we present semiclassical simulation of carrier and phonon transport in ultrathin silicon nanomembranes and gated nanoribbons. We show that the thermoelectric response of Si-membrane-based nanostructures can be improved by employing the anisotropy of the lattice thermal conductivity, revealed in ultrathin Si due to boundary scattering, or by using a gate to provide additional carrier confinement and enhance the thermoelectric power factor. 相似文献
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Joo F. Mano Zlatan Denchev Aurora Nogales Marta Bruix Tiberio A. Ezquerra 《大分子材料与工程》2003,288(10):778-788
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Clara Cano-Raya Nadya V. Dencheva Joana F. Braz Marc Malfois Zlatan Z. Denchev 《应用聚合物科学杂志》2020,137(38):49131
This work presents the preparation, optimization, and testing of an enzyme-based optical biosensor for catechol determination. The sensing area is attached to a glass support and contains: anionic polyamide 6 (PA6) porous microparticles supporting laccase from Trametes Versicolor, embedded in a Pebax® MH1657 polymer binder that contains the optical indicator dye 3-methyl-2-benzothiazolinone hydrazone (MBTH), responsible for the optical transduction. The catechol analyte, after its enzymatic oxidation, forms o-benzoquinone that can be detected by oxidative coupling with MBTH giving rise to a colored product. The latter can be quantified measuring the UV/VIS absorbance at 500 nm. The PA6 microparticles performed as useful laccase carriers reaching high immobilization yields of up to 99.8% and preserving the enzyme catalytic activity. This permitted the preparation of a new biosensor presenting a detection limit of 11 μM and responding linearly to up to 118 μM of catechol. Biosensor applicability was tested in spiked natural water samples from river and spring. The recovery rates observed were in the range of 97–108% that proves the good accuracy of the proposed biosensor. 相似文献
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Aleksandra Gruji Zlatan Stojkovi 《IEEJ Transactions on Electrical and Electronic Engineering》2016,11(Z1):S28-S36
This paper presents the methodology, algorithms, and application of the expanded version of the software tool formed by means of the powerful AutoCAD software and the programming language Visual Basic, enabling both the estimation and visualization of the 3D lightning protection (LP) zone for a high‐voltage substation (HVS) and risk management against lightning. Although HVS is outside the scope of IEC 62305‐2, its methodology is adapted in this paper to the case of HVS. The approximate reasoning algorithm for risk management against lightning is based on the implementation of fuzzy sets that describe the measure of the HVS LP and the corresponding risk. Sensitivity analysis pertaining to the risk from the lightning flash (LF) and the corresponding economic evaluation have been carried out for the actual 220 and 110 kV HVSs in function of the impulse current magnitude and protective measure implementation. The formed software tool application enables the formation of the map of risk in the function of the considered facility and the impulse current of the LF, which will represent the constituent part of the future information system of electric power transmission and distribution organizations intended for risk management. © 2016 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc. 相似文献
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This work examines the generation of heat in silicon MOSFETs using self-consistent Monte Carlo device simulation with full
electron bandstructure and a full phonon dispersion computed from the Adiabatic Bond Charge model. We devise an efficient
algorithm for the inclusion of full phonon dispersion in order to account for anisotropy and details of heat transport with
great accuracy. We compute the density-of-states (DOS) and the lattice thermal energy numerically and use them to generate
maps of local temperatures in a representative small-channel MOSFET device. Our results show that most heat is dissipated
in the form of optical g-type phonons in a small region in the drain, and that the heat flows in a preferred direction aligned with the flow of the
electron current. We also show that the distribution of generated phonons in energy closely follows the phonon DOS. 相似文献