The effect of substrate surface integrity on the surface properties of TiCrN coating applied via the CAE-PVD method

This study aims to investigate how the predeposition machining processes such as magnetic grinding, turning machining, and wire electrical discharge machining can influence the surface properties including electrochemical and tribological behavior of TiCrN nanostructured coating applied on Mo40 steel substrate. A physical vapor deposition technique using cathodic arc evaporation was used to apply the coating. The crystallographic phases and the microstructure of the coating were studied by X-ray diffraction and scanning electron microscope, respectively. Rockwell-C, electrochemical impedance spectroscopy and potentiodynamic polarization, and pin-on-disk wear tests were employed to evaluate the adhesion strength, corrosion behavior, and tribological property of specimens, respectively. The electrochemical results after 24 h of exposure to 3.5 wt% NaCl solution showed that TiCrN coating pretreated with a turning process with polarization resistance of about 3525.32 Ω.cm² had the best corrosion resistance among all specimens. This was because of the improvement of the smoothness, surface quality, and adhesion after the turning process. On the other, the friction coefficient of the grounded sample is less than that of other ones. This is probably due to its higher adhesion strength and higher surface smoothness.     

Synergistic effect of micro- and nano-TiO2 on hydrophobic,mechanical, and electrical properties of hybrid polyurethane composites

Journal of Materials Science: Materials in Electronics - One of the ways to improve the performance of ceramic insulators in polluted climates is to use polymer coatings reinforced with ceramic...     

A simple,low cost,and template-free method for synthesis of boron nitride using different precursors

In this research, hexagonal boron nitride (h-BN) was synthesized using a simple, low cost, and template-free method with urea-boric acid (UB), melamine-boric acid (MB), and melamine-urea and boric acid (MUB) precursors, followed by the pyrolysis and heat treatment in a nitrogen atmosphere at 1050 °C. Samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), Raman Spectroscopy, Fourier transform IR (FT-IR), and Brunauer–Emmett–Teller (BET) techniques. The specific surface areas obtained for h-BN synthesized by UB, MB, and MUB precursors were 87.43, 573.07, and 1005.7 m²/g, respectively. The average diameters of the pores using the Barrett, Joyner, and Halenda (BJH) model were 37.78, 3.68, and 2.13 nm, respectively. A thermogravimetric analysis showed a wider range of decomposition temperatures after using three precursors for synthesizing h-BN. Crumpled, whisker, and flower-like morphologies for UB, MB, and MUB precursors were respectively found using FESEM investigations. The formation of h-BN within the MUB sample was confirmed using the XPS analysis with measured peaks of 398.5 and 190.6 eV belonging to N 1s and B 1s, respectively. Raman spectroscopy revealed a high-intensity peak in 1366 cm^?1 related to the E_2g mode for h-BN synthesized with MUB. Therefore, the results demonstrate that the employed method can increase the potential of using the h-BN porous powder with a high specific surface area as a lubricant, thermal insulation filler, anti-corrosion filler in paint coatings, adsorption of various gas and hydrocarbon molecules as well as its application in drug-delivery nanocarriers.     

Investigation of microstructure,hardness and wear properties of Al–4.5 wt.% Cu–TiC nanocomposites produced by mechanical milling

The present work deals with studies on the manufacturing and investigation of mechanical and wear behavior of aluminum alloy matrix composites (AAMCs), produced using powder metallurgy technique of ball milled mixing in a high energy attritor and using a blend–press–sinter methodology. Matrix of pre-mechanical alloyed Al–4.5 wt.% Cu was used to which different fractions of nano and micron size TiC reinforcing particles (ranging from 0 to 10 wt.%) were added. The powders were mixed using a planetary ball mill. Consolidation was conducted by uniaxial pressing at 650 MPa. Sintering procedure was done at 400 °C for 90 min. The results indicated that as TiC particle size is reduced to nanometre scale and the TiC content is increased up to optimum levels, the hardness and wear resistance of the composite increase significantly, whereas relative density, grain size and distribution homogeneity decrease. Using micron size reinforcing particulates from 5% to 10 wt.%, results in a significant hardness reduction of the composite from 174 to 98 HVN. Microstructural characterization of the as-pressed samples revealed reasonably uniform distribution of TiC reinforcing particulates and presence of minimal porosity. The wear test disclosed that the wear resistance of all specimens increases with the addition of nano and micron size TiC particles (up to 5 wt.%). Scanning electron microscopic observation of the worn surfaces was conducted and the dominant wear mechanism was recognized as abrasive wear accompanied by some delamination wear mechanism.     

The use of poly(amidoamine) dendrimer in modification of jute for improving dyeing properties of reactive dyes

In this study, the poly(amidoamine) (PAMAM) G‐2 dendrimer was applied to the jute yarn. Fourier transform infrared spectrophotometry (FTIR) of the dendrimer‐treated jute yarn indicated that all carbonyl groups of the jute fiber have reacted with amino groups of the PAMAM dendrimer. Jute yarns which had been pretreated with PAMAM dendrimer displayed markedly enhanced color strength with reactive dyes, even when dyeing had been carried out in the absence of electrolyte or alkali. Dendrimer‐treated jute yarn showed much better light‐fastness than that of untreated jute yarn. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Changes in composition,appearance, physical,and dyeing properties of jute yarn after bio-pretreatment with laccase,xylanase, cellulase,and pectinase enzymes

Bio-preparation is a developing and promising method for lowering the consumption of chemicals specially in wet finishing where plenty of these compounds are used. In this study, samples of jute yarns were bio-finished by cellulase, xylanase, pectinase, laccase enzymes, and their mixtures. Then, they were scoured, bleached, and dyed with basic and/or direct dyes in conventional methods. Samples were analyzed by ATR-FTIR spectroscopy, reflective spectrophotometer, mechanical tester, and then compared. FTIR peaks of enzymatic-treated samples showed aldehyde absorption peaks, and also changes in carbonyl groups of hemi-cellulose and aromatic –CH– out of plane vibration in lignin. The whiteness and brightness index values of jute yarns improved before and after bleaching. Pectinase-treated jute yarn enhanced yarn count compare to other enzymatic or NaOH treatment. All enzymatic or NaOH treatments decreased the tenacity of jute yarns. Xylanase and cellulose treatments showed lower tensile strength than others. Pectinase and laccase enzymes increased dye strength of the jute yarn that dyed by direct dye, while cellulase, xylanase, and pectinase did the same for basic dye.     

Effects of alkali and ultraviolet treatment on colour strength and mechanical properties of jute yarn

In this study, jute yarns were treated with an aqueous alkali solution and ultraviolet light to improve dyeability. Ultraviolet light treatments were carried out at an air pressure of 1 atm, under water and vacuum, and all the samples were dyed with reactive dyes. Virgin samples and treated jute yarns were analysed by Fourier Transform–infrared spectroscopy. K/S values were determined by a reflective spectrophotometer and used to establish the fixation values and colour strength of the dyed samples. The tensile mechanical properties of the samples were also measured by a tensile testing apparatus and were compared with the virgin samples. Alkali treatment resulted in a reduction in carbonyl group concentration. However, atmospheric ultraviolet light treatment increased carbonyl group concentration. Dyeability and dye fixation values for atmospheric and underwater ultraviolet light‐treated samples increased. Furthermore, the loss of tensile strength for alkali‐treated samples was much greater than others (up to 50%) in comparison with ultraviolet light‐treated samples.