Preparation and characterization of CeO2–TiO2 support for Ru catalysts: Application in CWAO of p-hydroxybenzoic acid

The catalytic wet air oxidation of aqueous solutions of p-hydroxybenzoic acid has been carried out over CeO₂–TiO₂ supported ruthenium catalysts (Ru/Ce–Ti) at 140 °C and 50 bar of air. High activity of ruthenium supported catalysts was observed. It was found that the decrease of the molar ratio Ce/Ti from 3 to 1/3, improves the activity of Ru catalysts. The activity of the samples decreases in the following order: Ru/Ce–Ti (1/3) > Ru/CeO₂ ≈ Ru/TiO₂ > Ru/TiO₂DT51. Characterization of samples was performed by means of N₂ adsorption–desorption, XRD, UV–visible, TPR, SEM and TEM.     

NUMERICAL STUDY OF FLOW AROUND AN OSCILLATING DIAMOND PRISM AND CIRCULAR CYLINDER AT LOW KEULEGAN-CARPENTER NUMBER

In order to identify the influence of shape corners on the instantaneous forces in the case of oscillating bodies, the simulated flow field is compared for two kinds of cross sections: diamond prism and circular cylinder. For these two flow configurations, the same Reynolds number and a Keulegan-Carpenter are considered. To compute the dynamic flow field surrounding the body, the Navier-Stokes transport equations in a non-inertial reference frame attached to the body are considered. Hence, a source term is added locally to the momentum equation to take into account the body acceleration. The proposed model is solved using the PHOENICS code. For the oscillating circular cylinder, the simulated results are in good agreement with the experimental data available in the litterature. After validation of this proposed model, flow field for diamond prism is determined. For both bodies, the process of the vortex formation is similar, with the formation of a recirculation zone in the near-wake containing a symmetric pair of vortices of equal strength and opposite rotation. The length of recirculation zone varies approximately linearly with time. However, the in-line force coefficient of the oscillating diamond prism is found to be greatest, since the recirculation zone is longer compared with that of the oscillating circular cylinder.     

Multi-scales modelling of dynamic behaviour for discontinuous fibre SMC composites

The requirements of passive security, notably in the transport industry, impose to maximize the dissipation of the energy and to minimize the decelerations undergone by a vehicle and thus passengers due to violent shocks (crash). This paper aims at establishing efficient expected answers towards the preoccupations mainly emanating from transport industry. Currently, the behaviour laws implemented in the dynamic explicit schemes (RADIOSS, PAM-CRASH and LS-DYNA) do not integrate sufficiently the physical aspects in the material degradation, mainly the damage process, their kinetics, the variability and especially the heterogeneity of the composite materials microstructure. This paper deals with the development of a multi-scale predictive model coupling specific experimental methodologies and the micromechanical formulation of damage mechanisms in order to build constitutive laws for discontinuous fibre reinforced composites materials. The developed micromechanical modelling is based on an experimental methodology conducted over a range of strain rates from quasi static to 250 s⁻¹. The latter has enabled identifying local probabilistic damage criterion formulated through the Weibull’s statistical integrating the strain rate effect and describing the progressive interfacial debonding under rapid loading. The developed model has been validated to predict the stiffness reduction and the overall elastic visco-damage behaviour for SMC composite material. The model simulations agree well with high speed tensile tests and confirm that the damage threshold and kinetic in the SMC are mainly strain rate sensitive.     

Combustion with mixed enrichment of oxygen and hydrogen in lean regime

A low global richness of combustion is interesting from an ecological and economic point of view as it helps to limit fuel consumption. In fact, the consequences of the combustion in poor mode are the appearance of local or global flame extinctions, energy loss by radiation and change in flame structure. The flammability limits of the diffusion methane flame can be resolved by the enrichment of the combustion air with oxygen or the use of the pure oxygen as oxidant as well as the addition to hydrogen in natural gas. Moreover, the use of oxygen and hydrogen as previously mentioned allow working in low ranges of richness while maintaining good flame stability. For a constant burner power of 15 kW, the reduction of the richness involves an increase in the oxidizer flow rate injected into the combustion reaction. In this present study, the variation of the richness, the fuel enrichment with hydrogen and the oxidant enrichment with oxygen are shown as major parameters where they have direct influences on the flow dynamic, the flame structure and the pollutant emissions.The Chemiluminescence of OH* radical and the PIV (Particle image velocimetry) are used in this work to characterize the flame structure, the stability and the dynamics of the flame. The measurement of pollutant emissions effected by a gas analyzer. The enrichment in oxygen and hydrogen provides a stable flame, which is well attached to the burner for the following richness values: 0.7, 0.8, 0.9 and 1. The reduction of the richness promotes the mixture quality of the reactants and leads a reduction in CO₂ and CO concentration. By contrast, the decrease of the richness supports the formation of NOx.     

Investigation of dyes degradation intermediates with <Emphasis Type="Italic">Scytalidium thermophilum</Emphasis> laccase

Scytalidium thermophilum laccase was able to successfully decolourise Congo Red, Bromo-Cresol Green, Malachite Green, Phenol Red and Indigo Carmine under optimised conditions. The cited dyes belonging to three different classes were named azo, triarylmethane and indigoid. The decolourisation rates were 100, 95, 76, 57 and 22 mg h⁻¹ U⁻¹ for Indigo Carmine, Malachite Green, Bromo-Cresol Green, Congo Red and Phenol Red, respectively. The degradation products were characterised by UV–vis and FT-IR techniques, and their cytotoxicity was monitored. UV–visible absorption spectra and FT-IR analysis showed a complete degradation of Congo Red, Bromo-Cresol Green and Malachite Green, a partial degradation of Phenol Red and a transformation of Indigo Carmine. Toxicity study revealed that most of the treated dyes were less toxic than those before treatment, especially for Malachite Green. In fact, Scytalidium thermophilum laccase degraded Malachite Green into non-toxic products. Scytalidium thermophilum laccase constitutes a powerful tool for effective bioremediation of rich-dye textile effluents and was, therefore, found worthy of investigation for potential applications in restoration work and other biotechnological uses.     

Screening for anti-listerial bacteriocin-producing lactic acid bacteria from "Gueddid" a traditionally Tunisian fermented meat

Forty eight lactic acid bacteria strains isolated from “Gueddid”, a traditionally Tunisian fermented meat, were screened for bacteriocin production. Four strains named MMZ 04, 09, 13, and 17 showed antimicrobial activity and were identified as Enterococcus faecium by molecular methods based on the 16S-23S rDNA ISR, PCR-RFLP analysis of the 16S-23S rDNA ISR and species-specific primers. The four antimicrobial compounds were heat stable (121 °C for 15 min), active over a wide pH range (3–9) and the antimicrobial activity was lost after treatment with trypsin, -chymotrypsin and proteinase K but not by lysozyme and lipase. The mode of action of enterocin MMZ17 was identified as bactericidal. The MMZ17 bacteriocin was partially purified by ammonium sulphate precipitation and C₁₈ Sep-Pack chromatography. The apparent molecular size of enterocin MMZ17 as indicated by activity detection after SDS-PAGE was lower than 6.5 KDa. According to these assays, enterocin MMZ17 can be classified as a small, heat-stable Listeria-active peptide, presumably belonging to class IIa bacteriocins.     

An improved imperialist competitive algorithm for multi-objective optimization

This article proposes an improved imperialistic competitive algorithm to solve multi-objective optimization problems. The proposed multi-objective imperialistic competitive algorithm (MOICA) uses the elitist strategy, based on the mutation and crossover as in genetic algorithms, and the Pareto concept to store simultaneously optimal solutions of multiple conflicting functions. Three performance metrics are used to evaluate the performance of the new algorithm: convergence to the true Pareto-optimal set, solution diversity and robustness, characterized by the variance over 10 runs. To validate the efficiency of the proposed algorithm, several multi-objective standard test functions with true solutions are used. The obtained results show that the MOICA outperforms most of the methods available in the literature. The proposed algorithm can also handle multi-objective engineering design problems with high dimensions.