应特别重视胶带输送机斜井的防火保护

随着间断－连续工艺在深凹露天矿的广泛应用，在运输机斜井中屡屡发生火灾事故，给企业造成了巨大的经济损失。矿业劳动安全科研所等单位共同调查研究了几个铁矿采选公司斜井胶带火灾事故的原因和后果。通过对胶带结构成分的改进以及对各种防火手段的试验取得了研究成果。提出了一系列防火措施，取得了俄罗斯工业部的批准和国家矿山监督局的认可。     

稀土尾矿强化水泥熟料煅烧

本文论述了尾矿、石膏添加下强化水泥熟料煅烧的效果、作用机理以及水泥性能等。通过含铝相变化、F~-、SO_3分布等基础理论研究,提出了强化熟料煅烧最佳配料及关键技术。一、原材料及实验方法稀土尾矿是选铁、稀土后的工业废渣,细度200目以上,含水率10～15%,主要成分为氟化钙、少量铁、重晶石、氟碳铈矿。     

Redox chemistry of gold(i) phosphine thiolates: sulfur-based oxidation

The redox chemistry of mononuclear and dinuclear gold(I) phosphine arylthiolate complexes was recently investigated by using electrochemical, chemical, and photochemical techniques. We now report the redox chemistry of dinuclear gold(I) phosphine complexes containing aliphatic dithiolate ligands. These molecules differ from previously studied gold(I) phosphine thiolate complexes in that they are cyclic and contain aliphatic thiolates. Cyclic voltammetry experiments of Au(2) (LL)(pdt) [pdt = propanedithiol; LL = 1,2-bis(diphenylphosphino)-ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), 1,4-bis(diphenylphosphino)butane (dppb), 1,5-bis(diphenylphosphino)pentane (dpppn)] in 0.1 M TBAH/CH(3)CN or CH(2)Cl(2) solutions at 50 to 500 mV/sec using glassy carbon or platinum electrodes, show two irreversible anodic processes at ca. +0.6 and +1.1 V (vs. SCE). Bulk electrolyses at +0.9 V and +1.4 V result in n values of 0.95 and 3.7, respectively. Chemical oxidation of Au(2)(dppp)(pdt) using one equivalent of Br(2) (2 oxidizing equivalents) yields 1,2-dithiolane and Au(2)(dppp)Br(2). The reactivity seen upon mild oxidation /= +1.3 V) is consistent with oxidation of gold(I) to gold(III). Structural and electrochemical differences between gold(I) aromatic and aliphatic thiolate oxidation processes are discussed.     

Dietary stearic acid and risk of cardiovascular disease: Intake,sources, digestion,and absorption

Individual FA have diverse biological effects, some of which affect the risk of cardiovascular disease (CVD). In the context of food-based dietary guidance designed to reduce CVD risk, fat and FA recommendations focus on reducing saturated FA (SFA) and trans FA (TFA), and ensuring an adequate intake of unsaturated FA. Because stearic acid shares many physical properties with the other long-chain SFA but has different physiological effects, it is being evaluated as a substitute for TFA in food manufacturing. For stearic acid to become the primary replacement for TFA, it is essential that its physical properties and biological effects be well understood.     

熟料中氟含量对水泥凝结性能的影响

利用包钢稀土精选后的尾矿代替萤石作为煅烧水泥熟料的矿化剂,可以强化水泥熟料煅烧,降低熟料烧成温度100～150℃。所配制的水泥达到525号硅酸盐水泥的国家标准。但是,尾矿掺量必须适当。否则,对水泥性能尤其对水泥的凝结产生很大影响。而影响水泥凝结的因素是很多的。我们着重探讨熟料中氟含量的影响,找出了熟料中氟含量影响水泥凝结的初步规律:当熟料成份及各率值控制在一定范围内,随着氟的增加凝结时间减慢;而且,减慢的趋势又与随氟的增加而使得熟料     

Sex pheromone of tomato fruit borer, Neoleucinodes elegantalis

Five candidate pheromone components were identified by analyzing pheromone gland extracts by gas chromatography (GC), coupled GC-electroantennographic detection (EAD), and coupled GC-mass spectrometry (MS): (E)-11-hexadecenol(E11–16 : OH), (Z)-11-hexadecenol (Z11–16 : OH),(E)-11-hexadecenal, (E)-11-hexadecenyl acetate, and (Z)-3,(Z)-6,(Z)-9-tricosatriene (Z3,Z6,Z9–23 : Hy). In electroantennogram (EAG) recordings, synthetic E11–16 : OH elicited stronger antennal responses at low doses than other candidate pheromone components. Field tests demonstrated that synthetic E11–16 : OH as a trap bait was effective in attracting males, whereas addition of Z11–16 : OH inhibited the males' response. Z3,Z6,Z9–23 : Hy strongly enhanced attractiveness of E11–16 : OH, but was not attractive by itself. A pheromone blend with synergistic behavioral activity of an alcohol (E11–16 : OH) and hydrocarbon (Z3,Z6,Z9–23 : Hy) component is most unusual in the Lepidoptera. The synthetic two-component pheromone is approximately 60 times more attractive than the female-produced blend and might facilitate the control of this pest.     

Ketamine effects on the urogenital system--changes in the urinary bladder and sperm motility

Different doses of ketamine (10 mg/kg, 20 mg/kg, 30 mg/kg, 40 mg/kg, 50 mg/kg, and 60 mg/kg) were injected i.p. (I.P.), respectively, to male ICR mice to determine the optimal dosage for chronic administration. At and above 40 mg/kg I.P. injection, mice had almost no hindlimb movement during swimming test. Subsequently, 30 mg/kg was used as the dose for the study in the toxicity of long-term ketamine administration on urinary bladder and sperm motility. The treatment group were subdivided into two (n = 10 each group); one received daily ketamine treatment i.p. for 3 months and another group for 6 months. Corresponding number of mice in control groups (n = 5 each group) received saline injection instead of ketamine. Terminal dUTP nick and labeling (TUNEL) study and Sirius red staining were carried out on the sectioned slides of the urinary bladders to study the degree of apoptosis in both epithelium and muscular layers of the urinary bladder and the relative thickness of the muscular layers in this organ was also computed. Apoptosis in the bladder epithelium was observed initially in the 3-month ketamine treated mice and the number of apoptotic cells was significantly different (P < 0.05) between the 3-month and 6-month ketamine treated mice and the control. The relative thickness of muscular layers in the bladder wall also decreased significantly (P < 0.05) when the 6-month treated mice and the control were compared. Sirius red staining revealed increase of collagen in the urinary bladder of the treated mice, most evidently 6 months after ketamine treatment. In addition, the sperm motility was studied and there was a statistically significant difference between the control and ketamine treated groups in the percentages of sperms which were motile (P < 0.05). This suggested that the chronic administration of ketamine affected the genital system as well.